Lewis Structures. The least electronegative element is nitrogen which will be the central atom.

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Priscilla May
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1 Lewis Structures Lewis structures are used to help visualize what molecules look like. They are 2- dimansional representations of molecular structures, based on the arrangement of valence electrons in the formation of chemical bonds. It is assumed that most elements require an octet of valence electrons, to attain a noble gas configuration. There are exceptions to this rule, which we will discuss. An important exception is hydrogen, which fills its valence shell (1s) with only 2 electrons. There is a series of steps that can be followed to simplify the determination of a Lewis Structure. 1. Examine the atoms in the molecule and determine how many valence electrons they each contribute. or polyatomic anions, add enough extra electrons to account for the negative charge. or polyatomic cations, remove enough electrons to account for the positive charge. 2. Place the least electronegative element in the center of the molecule (never hydrogen). 3. Using pair of electrons, make bonds between the central atom and each surrounding atom. 4. Complete the octets of electrons for the atoms bonded to the central atom. Show all lone pairs. 5. Place all remaining electrons on the central atom. If the octet rule is not met for the central atom, move lone pairs of electrons to make multiple bonds to the central atom. This sounds more confusing than it is. What is the structure of nitrogen trifluoride, N 3? N = group 5 = 5 valence electrons = group 7 = 7 valence electrons Total electrons = 5 + (3x7) = 26 electrons The least electronegative element is nitrogen which will be the central atom. Now, make bonds between N and three. N This uses up 6 of the 26 electrons. Now, add an octet of valence electrons around each of the fluorine atoms. N We have now used 24 of the 26 electrons. Add the remaining 2 electrons to complete the octet on N.

2 N This accounts for all 26 electrons and gives every atom in the molecule a share in 8 valence electrons, an octet. There are 3 bonding pairs of electrons and 10 lone pairs of electrons. What is the Lewis Structure for nitric acid, N 3? N = Group 5 = 5 valence electrons = Group 6 = 6 valence electrons = Group 1 = 1 valence electron Total electrons = 5 + (3x6) + 1 = 24 electrons The least electronegative element is nitrogen, the central atom. ydrogen is always at the edge of a molecule, since it can only form one bond. Make bonds between N and three. The hydrogen should be bonded to one of the oxygens. Nitric acid is one of the "xoy-acids", like sulfuric, phosphoric and choric acids. The acidic hydrogen, which forms + in aqueous solutions, is always bonded to an oxygen in these acids. N This uses up 8 of the 24 electrons. Now, create octets of electrons around the oxygens. N This uses up all 24 electrons. Each oxygen is surrounded by 8electrons and the hydrogen has 2 electrons. owever, nitrogen only has a share in 6 electrons. To give nitrogen a chare in 8 electrons, move one of the lone pairs of electrons from an oxygen, and make a second bonding pair between the oxygen and nitrogen. N N This now gives N and all of the a share in 8 electrons. With two pairs of bonding electrons, the nitrogen and oxygen are joined by a double bond, which would be represented as N=. What is the Lewis Structure of the carbonate ion, C 3 2-? irst, decide on the number of electrons involved.

3 C = Group 4 = 4 valence electrons = Group 6 = 6 valence electrons Total electrons = 4 + (3x6) = 22 electrons, but the ion carries a charge of -2. This indicates that the ion has gained 2 additional electrons, so add 2 more electrons to the total. We have 24 electrons to work with. The least electronegative atom is carbon, so it will be the central atom. Draw bonds between the central C and the three atoms. C This uses up 6 of the 24 electrons. Next, complete the octets of electrons around the oxygen atoms. C This brings the electrons used to 24. But, there is a problem. The C has a share in only 6 electrons. Again, move a lone pair from oxygen to make a double bond with the carbons. This gives both atoms a share in a complete octet. C C The double bond could be between the carbon and any one of the equivalent oxygen atoms. C or C or C A C= bond will be stronger and shorter than a C- bond. There is more electron density between the nuclei. owever, it has been shown that all three carbon-oxygen bonds are identical. This can be explained if we use all three configurations to explain the structure. When two or more Lewis Structures can be used to describe the same molecule, each is called a resonance structure. Each has an identical atomic structure, only the position of the electrons has been changed. A double arrow is used to represent resonance structures. C C C Another way of representing these structures is:

4 C C C r, more compactly as C which shows the partial double bond character of all three bonds. What is the Lewis Structure of formaldehyde, C 2? Carbon - 4 valence electrons xygen = 6 valence electrons ydrogen = 1 valence electron Total = (2x1) = 12 valence electrons The atoms can be arranged 2 different ways: C or C This leaves 6 more electrons to complete the octets around C and. C or C Again, we have to move lone pair electrons to create double bonds. C or C Which of these two structures represents formaldehyde? To determine this, we need to look at the concept of formal charge. This is a comparison of the number of valence electrons on an isolated atom versus the number of electrons assigned to an atom in a given Lewis Structure. The number of electrons in an isolated atom is simply the Group number of the element. The number of electrons assigned by a Lewis Structure is the number of lone pair electrons (unshared) plus one-half of the shared, bonding electrons.

5 In the figure below, the electrons "belonging" to carbon are shown in red, and the electrons "belonging" to oxygen are shown in blue. C or C or the structure on the left, the formal charges will be: element valence e - - lone pair e - - ½ shared e - = formal charge C or the structure on the right, the formal charges will be: element valence e - - lone pair e - - ½ shared e - = formal charge C or a neutral molecule, a Lewis Structure with no formal charges is preferred. Small formal charges are preferable to large formal charges. Like charges on adjacent atoms are undesirable. A more negative formal charge should reside on a more electronegative element. The structure on the left puts a positive formal charge on oxygen, an electronegative element. The structure on the right has no formal charges and is the best structure for formaldehyde. The Lewis dot structures of the individual, non-metal atoms give a good indication of the bonding possibilities for the atoms. C N Carbon tends to form 4 bonds and have no lone pairs. Nitrogen tends to form three bonds and have on e lone pair. xygen tends to form two bonds and have two lone pairs. luorine (and all halogens) tends to form one bond and have 3 lone pairs. With these electron configurations, none of these atoms will have any formal charge. This is how they are most stable. In the correct (right) structure for formaldehyde, C 2, carbon has four bonds and no lone pairs, and oxygen has two bonds and two lone pairs.

6 In the incorrect (left) structure, carbon has three bonds an a lone pair, and oxygen has three bonds and a lone pair, leading to non-zero formal charges. Exceptions to the octet rule 1. Molecules with an odd number of electrons. These species are called free radicals because they contain an unpaired electron. An example would be nitrogen monoxide, N. Because of the odd number of electrons, Lewis structures can not really be used to describe it. What is the structure of nitrogen monoxide, N? N = Group 5 = 5 valence electrons = Group 6 = 6 valence electrons Total electrons = = 11 electrons Add another electron in order to come up with possible Lewis structures. So, assume there are 12 electrons. Bond the and N. N Next, create an octet on the oxygen, and place remaining electrons on the nitrogen. N To complete the octet on N, move a lone pair from to give N a share in 8 electrons. N To make a free radical, with only 11 electrons, we can remove an electron from either N or. The two resulting structures are shown below, with their formal charges. N N The first has no formal charge and is the correct representation for N.

7 2. Incomplete ctets (fewer than 8 electrons on central atom) These compounds involve Be (2 valence e - ), B and sometimes Al (3 valence e - ). or example, B forms compounds with halogens with the formula, BX 3, like B 3. What is the structure of boron trifluoride, B 3? B = Group 3 = 3 valence electrons = Group 7 = 7 valence electrons Total electrons = 3 + (3x7) = 24 electrons B A resonance structure could be drawn with a double bond between a and B. But, this would put a formal positive charge on, the most electronegative element. 3. Expanded ctet (more than 8 valence electrons on the central atom) This can occur in atoms that possess d orbitals, in the 3 rd period and beyond. An example of this would be phosphorus pentafluoride, P 5. What is the structure of phosphorus pentafluoride? P = Group 5 = 5 valence electrons = Group 7 = 7 valence electrons Total = 5 + (5x7) = 40 electrons Bond the 5 to a central P, and complete the octets on the surrounding atoms. P This uses all 40 electrons, and P, the central atom, has a share in 10 valence electrons.

Worksheet 14 - Lewis structures. 1. Complete the Lewis dot symbols for the oxygen atoms below

Worksheet 14 - Lewis structures Determine the Lewis structure of 2 oxygen gas. 1. omplete the Lewis dot symbols for the oxygen atoms below 2. Determine the number of valence electrons available in the