SECTION 1: Identification of the substance/mixture and of the company/undertaking

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1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Commercial Product Name Ceramill ZI 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses 1.3 Details of the supplier of the safety data sheet Company designation Marketer 1.4 Emergency telephone number Resources for dental technology Amann Girrbach AG Herrschaftswiesen 1 A-6842 Koblach Telephone: FAX: Internet: Amann Girrbach GmbH Duerrenweg 40 D Pforzheim Telephone: FAX: Internet: Emergency telephone number +49 (0) Only available during office hours. SECTION 2: Hazards identification 2.1 Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 This product is classified as not hazardous according to regulation (EC) 1272/2008 [CLP]. 2.2 Label elements P-statement(s) Labelling according to Regulation (EC) No. 1272/2008 [CLP] 2.3 Other hazards Hazard precautions P260: Do not breathe dust/fume/gas/mist/vapours/spray. P273: Avoid release to the environment. The product does not have to be labelled according to Regulation (EC) No. 1272/2008 [CLP]. Restricted to professional users. SECTION 3: Composition/information on ingredients Chemical characterization Other data Pre-sintered, porose ZrO2 bloc with synthetic frame. The safety guidelines in chapters 4-8 as well as in chapters do not refer to the product itself but to the dust released during the working process. SECTION 4: First aid measures 4.1 Description of first aid measures General advice 1 / 5

2 If inhaled In case of skin contact In case of eye contact If swallowed Notes to physician Provide fresh air. Seek medical attention if problems persist. Wash with plenty of soap and water. Seek medical attention if problems persist. In the case of the formation of dust: In case of contact with eyes, rinse immediately with plenty of flowing water for 10 to 15 minutes holding eyelids apart. In case of eye irritation consult an ophthalmologist. Rinse mouth. Seek medical attention if problems persist. SECTION 5: Firefighting measures 5.1 Extinguishing media Suitable extinguishing media Co-ordinate fire-fighting measures to the fire surroundings. The product itself does not burn. 5.2 Special hazards arising from the substance or mixture Special exposure hazards arising from the substance or preparation itself, its combustion products, or released gases 5.3 Advice for firefighters Special protective equipment for firefighting Additional information on firefighting Brandrückstände und kontaminiertes Löschwasser müssen entsprechend den behördlichen Vorschriften entsorgt werden SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions Wear suitable protective clothing. Wear respiratory protection. Dust should be exhausted directly at the point of origin. Keep away from unprotected people. 6.2 Environmental precautions Environmental precautions Do not allow to enter into surface water or drains. 6.3 Methods and material for containment and cleaning up Methods for cleaning up SECTION 7: Handling and storage Take up mechanically. Staubbildung vermeiden 7.1 Precautions for safe handling Advice on safe handling Advice on protection against fire and explosion Refer to operating instructions. Provide fresh air. Dust should be exhausted directly at the point of origin. Do not breathe dust. 2 / 5

3 7.2 Conditions for safe storage, including any incompatibilities Storage space and container requirements Hints on storage assembly Do not store together with: Food and fodder 7.3 Specific end use(s) Specific use(s) Material to manufacture dental prosthesis. SECTION 8: Exposure controls/personal protection 8.1 Control parameters The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. 8.2 Exposure controls Respiratory protection Hand protection Suitable material: Evaluation: Remarks: Reference substance: Eye protection Skin and body protection General protective and hygiene measures Dust should be exhausted directly at the point of origin. In case of inadequate ventilation wear respiratory protection. Das Handschuhmaterial muss undurchlässig und beständig gegen das Produkt / den Stoff / die Zubereitung sein NBR (Nitrile rubber). Breakthrough times and swelling properties of the material must be taken into consideration. Aufgrund fehlender Tests kann keine Empfehlung zum Handschuhmaterial für das Produkt / die Zubereitung / da Chemikaliengemisch abgegeben werden Die Auswahl eines geeigneten Handschuhs ist nicht nur vom Material sondern auch vin weiteren Qualitätsmerkmalen abhängig und von Hersteller zu Hersteller unterschiedlich Da das Produkt eine Zubereitung aus mehreren Stoffen darstellt ist die Beständigkeit von Handschuhmaterialien nicht vorausberechenbar und muss deshalb vor dem Einsatz überprüft werden Tightly sealed safety glasses. Protective clothing. Avoid contact with skin, eyes and clothes. Wash hands before breaks and after work. After cleaning apply high-fat content skin care cream. When using do not eat, drink or smoke. Keep away from food, drink and animal feedingstuffs. SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Form solid Colour white Odour odourless Odour threshold Boiling point [ C] ca C Flash point [ C] Evaporation rate [kg/(s*m²)] Flammability (solid, gas) 3 / 5

4 Explosion limits [Vol-% ] Lower limit: Upper limit: Vapour density Density [g/cm³] Relative density Water solubility [g/l] Partition coefficient n-octanol /water (log P O/W) Autoinflammability Decomposition temperature [ C] Viscosity, dynamic [kg/(m*s)] Viscosity, kinematic [mm²/s] Risk of explosion. ca. 3 g/cm³ insoluble The product is not: Spontaneously flammable. The product is: not explosive. 9.2 Other information Melting range [ C] ca C Solvent content [%] organic: 0,0 % Solid content [%] 100 % Other data SECTION 10: Stability and reactivity 10.2 Chemical stability Chemical stability None, if used in accordance to instructions Possibility of hazardous reactions Hazardous reactions 10.4 Conditions to avoid Conditions to avoid 10.5 Incompatible materials Materials to avoid 10.6 Hazardous decomposition products Hazardous decomposition products SECTION 11: Toxicological information 11.1 Information on toxicological effects Irritant effect on skin Irritant effect on eyes Irritant effect on the respiratory tract Sensitization Frequently or prolonged contact with skin may cause dermal irritation. Inhalation of dust may cause irritation of the respiratory system. 4 / 5

5 11.2 Additional information Other information (chapter 11.) No evidence of harmful effects from available information if used properly. Das Produkt ist nicht kennzeichnungspflichtig auf Grund des Berechnungsverfahrens der "Allgemeinen Einstufungsrichtlinie für Zubereitungen der EG" in der letztgültigen Fassung SECTION 12: Ecological information 12.1 Toxicity Aquatic toxicity [mg/l] 12.2 Persistence and degradability Biodegradability 12.6 Other adverse effects Further information on ecology Product is not easily biodegradable. Wassergefährdungsklasse: schwach wassergefährdend (WGK 1) Selbsteinstufung Nicht unverdünnt bzw. in größeren Mengen in das Grundwasser, in Gewässer oder in die Kanalisation gelangen lassen. SECTION 13: Disposal considerations 13.1 Waste treatment methods Disposal considerations Waste Code Uncleaned empty packaging Kleinere Mengen können gemeinsam mit Hausmüll deponiert werden. Darf nicht zusammen mit Hausmüll entsorgt werden Do not empty into drains. Packing which cannot be properly cleaned must be thrown away. Dispose of waste according to applicable legislation. SECTION 14: Transport information 14.8 Additional information Other information (chapter 14.) No dangerous good in sense of these transport regulations. SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Water hazard class (self-classification) Chemical safety assessment Safety assessment For this substance a chemical safety assessment has not been carried out. SECTION 16: Other information Leerzeile These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. 5 / 5

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