MATERIAL SAFETY DATA SHEET

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1 MATERIAL SAFETY DATA SHEET Product Trade Name: Revision Date: 02-Jan CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Trade Name: Synonyms: Chemical Family: Application: Manufacturer/Supplier Prepared By Carbonate Solvent Halliburton Energy Services P.O. Box 1431 Duncan, Oklahoma Emergency Telephone: (281) Chemical Compliance Telephone: COMPOSITION/INFORMATION ON INGREDIENTS SUBSTANCE CAS Number PERCENT ACGIH TLV-TWA OSHA PEL-TWA Sodium carbonate % 3. HAZARDS IDENTIFICATION Hazard Overview May cause eye, skin, and respiratory irritation. 4. FIRST AID MEASURES Inhalation Skin Eyes Ingestion Notes to Physician If inhaled, remove from area to fresh air. Get medical attention if respiratory irritation develops or if breathing becomes difficult. Wash with soap and water. Get medical attention if irritation persists. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. Do not induce vomiting. Slowly dilute with 1-2 glasses of water or milk and seek medical attention. Never give anything by mouth to an unconscious person. Not Applicable Page 1 of 5

2 5. FIRE FIGHTING MEASURES Flash Point/Range (F): Flash Point/Range (C): Flash Point Method: Autoignition Temperature (F): Autoignition Temperature (C): Flammability Limits in Air - Lower (%): Flammability Limits in Air - Upper (%): Fire Extinguishing Media Special Exposure Hazards Water fog, carbon dioxide, foam, dry chemical. Decomposition in fire may produce toxic gases. Special Protective Equipment for Fire-Fighters Full protective clothing and approved self-contained breathing apparatus required for fire fighting personnel. NFPA Ratings: Health 1, Flammability 0, Reactivity 0 HMIS Ratings: Flammability 0, Reactivity 0, Health 1 6. ACCIDENTAL RELEASE MEASURES Personal Precautionary Measures Use appropriate protective equipment. Environmental Precautionary Measures Procedure for Cleaning / Absorption Prevent from entering sewers, waterways, or low areas. Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove. 7. HANDLING AND STORAGE Handling Precautions Storage Information Avoid contact with eyes, skin, or clothing. Avoid breathing vapors. Store away from acids. Store in a cool well ventilated area. Keep container closed when not in use. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Engineering Controls Respiratory Protection Use in a well ventilated area. Not normally necessary. Hand Protection Skin Protection Eye Protection Other Precautions Normal work gloves. Normal work coveralls. Wear safety glasses or goggles to protect against exposure. Eyewash fountains and safety showers must be easily accessible. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State: Liquid Color: Clear Odor: Odorless ph: 11.4 Specific 20 C (Water=1): C (lbs./gallon): 9.08 Page 2 of 5

3 9. PHYSICAL AND CHEMICAL PROPERTIES Bulk 20 C (lbs/ft3): Boiling Point/Range (F): Boiling Point/Range (C): Freezing Point/Range (F): Freezing Point/Range (C): Vapor 20 C (mmhg): Vapor Density (Air=1): Percent Volatiles: Evaporation Rate (Butyl Acetate=1): Solubility in Water (g/100ml): Solubility in Solvents (g/100ml): VOCs (lbs./gallon): Viscosity, 20 C (centipoise): Viscosity, 20 C (centistrokes): Partition Coefficient/n-Octanol/Water: Molecular Weight (g/mole): Soluble 10. STABILITY AND REACTIVITY Stability Data: Hazardous Polymerization: Conditions to Avoid Incompatibility (Materials to Avoid) Hazardous Decomposition Products Additional Guidelines Stable Will Not Occur anticipated Strong acids. Carbon monoxide and carbon dioxide. Not Applicable 11. TOXICOLOGICAL INFORMATION Principle Route of Exposure Inhalation Eye or skin contact, inhalation. May cause respiratory irritation. Skin Contact Eye Contact Ingestion Aggravated Medical Conditions Chronic Effects/Carcinogenicity Other Information May cause mild skin irritation. May cause eye irritation. known known. No data available to indicate product or components present at greater than 1% are chronic health hazards. known. Toxicity Tests Oral Toxicity: Dermal Toxicity: Inhalation Toxicity: Page 3 of 5

4 Primary Irritation Effect: Carcinogenicity Genotoxicity: Reproductive / Developmental Toxicity: 12. ECOLOGICAL INFORMATION Mobility (Water/Soil/Air) Persistence/Degradability Bio-accumulation Ecotoxicological Information Acute Fish Toxicity: Acute Crustaceans Toxicity: Acute Algae Toxicity: Chemical Fate Information Other Information 13. DISPOSAL CONSIDERATIONS Disposal Method Contaminated Packaging Disposal should be made in accordance with federal, state, and local regulations. Follow all applicable national or local regulations. 14. TRANSPORT INFORMATION Land Transportation DOT Not restricted Canadian TDG Not restricted ADR Not restricted Air Transportation ICAO/IATA Not restricted Sea Transportation IMDG Not restricted Other Shipping Information Labels: Page 4 of 5

5 15. REGULATORY INFORMATION US Regulations US TSCA Inventory EPA SARA Title III Extremely Hazardous Substances EPA SARA (311,312) Hazard Class EPA SARA (313) Chemicals All components listed on inventory. This product does not contain a toxic chemical for routine annual "Toxic Chemical Release Reporting" under Section 313 (40 CFR 372). EPA CERCLA/Superfund. Reportable Spill Quantity For This Product EPA RCRA Hazardous Waste Classification California Proposition 65 MA Right-to-Know Law NJ Right-to-Know Law PA Right-to-Know Law If product becomes a waste, it does NOT meet the criteria of a hazardous waste as defined by the US EPA. All components listed do not apply to the California Proposition 65 Regulation. Canadian Regulations Canadian DSL Inventory WHMIS Hazard Class All components listed on inventory. Un-Controlled 16. OTHER INFORMATION The following sections have been revised since the last issue of this MSDS Additional Information For additional information on the use of this product, contact your local Halliburton representative. For questions about the Material Safety Data Sheet for this or other Halliburton products, contact Chemical Compliance at Disclaimer Statement This information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtained from various sources including the manufacturer and other third party sources. The information may not be valid under all conditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of any material is the sole responsibility of the user. ***END OF MSDS*** Page 5 of 5

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