Formaldehyde Safety Training. ENVIRONMENTAL Health & Safety and Risk Management Support

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1 Formaldehyde Safety Training ENVIRONMENTAL Health & Safety and Risk Management Support

2 Overview Introduction to OSHA Standard for Formaldehyde Requirements of regulation Permissible exposure limits (PELs) Routes of exposure and health effects Protective measures Handling and storage of formaldehyde Spills and accidents Medical surveillance Waste management

3 29 CFR : Formaldehyde OSHA regulates occupational exposures to Formaldehyde Scope of 29 CFR This standard applies to all occupational exposures to formaldehyde, including exposure to: formaldehyde gas formaldehyde solutions (formalin) materials that release formaldehyde

4 29 CFR : Formaldehyde Requirements: Must have an MSDS available in the lab Written training materials must be available to employees Must establish regulated areas where airborne concentrations of formaldehyde exceed the OSHA permissible exposure limits (PEL) and/or short-term exposure limits (STEL) Medical surveillance must be provided to employees who may be exposed to formaldehyde at concentrations exceeding the PEL or STEL Exposure monitoring will be conducted if formaldehyde concentrations in the workplace exceed the action level of 0.5 ppm (8 hr TWA)

5 Permissible Exposure Levels OSHA requires that regulated areas be established where airborne formaldehyde concentrations exceed the OSHA PEL and/or STEL values OSHA PEL (averaged over 8 hr) OSHA STEL (maximum of 15 min/day) OSHA Action level (averaged over 8 hr) ACGIH STEL (maximum of 15 min/day) Note, this is a ceiling value that must never be exceeded 0.75 ppm 2 ppm 0.5 ppm 0.3 ppm C

6 Regulated Areas Regulated areas shall have danger signs posted at entrances and access ways Only authorized personnel shall enter regulated areas

7 Formaldehyde Use at UAA 10-37% Buffered solutions of Formaldehyde or Formalin 10-37% Non-buffered solutions of Formaldehyde or Formalin Formaldehyde gas in solution is called formalin 10-37% Stabilized solutions of Formaldehyde or Stabilizers: Methanol (0 % > or < 20 %) Even though the solutions are stabilized, formaldehyde (and various adducts) are released from the solution Formaldehyde or Formalin are suspected carcinogens

8 Potential health hazards: acute Exposure Routes Inhalation Sore throat, coughing, shortness of breath Sensitization of respiratory tract ppm: pulmonary edema and pneumonitis Ingestion Severe abdominal pain, violent vomiting, headache, diarrhea, unconsciousness and death Methanol used to stabilize the formaldehyde solution poses additional toxic hazards

9 Potential health hazards: acute Exposure Routes (cont.) Skin contact Irritation and/or burns; cracking, scaling, white discoloration Can be absorbed through skin Eye contact Irritation from vapors, pain, blurred vision May cause irreversible damage if splashed in eyes

10 Report adverse signs and symptoms Know how to report exposures and incidents/injuries that are related to the job Tell your supervisor, complete an Incident / Injury Reports Remember: symptoms develop over time, so adverse effects may not be immediately noticeable The perception of formaldehyde or formalin by odor and eye irritation becomes less sensitive with time as one adapts to formaldehyde or formalin This can lead to overexposure if a worker is relying on formaldehyde's or formalin s warning properties to alert him or her to the potential for exposure

11 Protect Yourself Against Exposures: Primary Methods of Exposure Control Engineering controls: Always use formaldehyde or formalin in a chemical fume hood Check that it is properly functioning Work practices: Badging (exposure monitoring) is required prior to starting any new work with formaldehyde or formalin and when changing experimental protocols. Call EHS/RMS at Have a lab specific SOP covering Formaldehyde or Formalin use Use the smallest amount of formaldehyde or formalin necessary Buy in quantities which can be used up in < 6 months Use non-hazardous alternatives whenever possible Eliminate bench top work with formaldehyde or formalin solutions or specimens

12 Protect Yourself Against Exposures: Secondary Methods of Exposure Control Personal Protective Equipment (PPE): For working with formalin at any concentration greater than 1%, splashproof goggles are required Formaldehyde contact with the eye can range from transient discomfort to severe, permanent corneal clouding and loss of vision

13 Protect Yourself Against Exposures: Secondary Methods of Exposure Control Personal Protective Equipment (PPE): For working with formaldehyde or formalin 10 % > or < 37%: Protective clothing: lab coats, aprons, suits Gloves: Tychem CPF2, SL, CPF3, F, CPF 4, BR, LV, Responder, TK, or Reflector (all have breakthrough times > 480 min) For working with formaldehyde or formalin 1 % > or < 10%: Protective clothing: lab coats (recommended) Gloves : Nitrile (>360 min), Neoprene (105 min), PVC (100 min) Rubber or Neoprene/rubber (10-15 min), PVA gloves are not recommended

14 Protect Yourself Against Exposures: Secondary Methods of Exposure Control Personal Protective Equipment (PPE): Inspect all PPE prior to use Check all PPE for cracks, degradation, discoloration, or holes Change gloves frequently Just because the breakthrough time is >360 min doesn t mean you should use one pair of gloves for 6 hours. Double glove if necessary DO NOT REUSE disposable gloves Storage of PPE Store away from sources of formaldehyde or formalin Formaldehyde vapors can permeate the lab coat or glove material, reducing its barrier-properties

15 Protect Yourself Against Exposures: Secondary Methods of Exposure Control Personal Protective Equipment (PPE): Respirator use follows the requirements given in 29 CFR : Employees must wear respirators if they are required to do so If required to wear a respirator, employees must have a medical exam (once) and be fit tested (annually) Respirators are required During periods necessary to implement engineering and work practice controls In operations where engineering controls and work practices are not feasible In operations where engineering controls and work practices do not prevent exposure below the PEL In emergencies (spill response) If you use formalin in a fume hood, you should not need to wear a respirator NO EMPLOYEE IS AUTHORIZED OR PERMITTED TO USE A RESPIRATOR HERE AT UAA

16 Storage and handling Formaldehyde or Formalin Concentration 10 % > or < 37%: Storage code is RED (flammable) It is also a health hazard, but flammable rating takes precedence Store in secondary containment Formaldehyde or Formalin Concentration 1 % > or < 10%: Storage code is BLUE (health hazard) At this concentration, it is no longer flammable Store in secondary containment

17 Labeling All containers of formaldehyde or formalin must be labeled with the following: The word Formaldehyde or Formalin and the concentration Name and address of the responsible party The words Potential cancer hazard and Respiratory sensitizer This includes: Stock solutions whose concentrations are 10 % > and < 37 % Working solutions Specimens preserved in formalin

18 Spill Response / Clean-up All employees not involved directly with spill response and cleanup must leave the spill area. Do not clean up a spill if you are untrained and are uncomfortable about doing so. DO NOT RISK A CHEMICAL EXPOSURE INORDER TO CLEAN UP ANY SPILL! Small spills (< 400 ml) outside of a fume hood: Contain the spill and cap any opened bottles Use the green labeled Spill-X-FP Formaldehyde polymerizer as outlined in the directions. (Maker is Ansul Inc.) Evacuate all non essential personnel and notify the PI, Director of CAS Facility Support, CHO, and UAA EHS / RMS of the spill. Call 911 if there are immediate threats to life, health or injuries.

19 Spill Response / Clean-up Large spills (> 400 ml) outside of a fume hood: Contain the spill and cap any open bottles. Use the green labeled Spill-X-FP Formaldehyde polymerizer as outlined in the directions. (Maker is Ansul Inc.) Evacuate the area and notify the PI, Director of CAS Facility Support, CHO, and UAA EHS / RMS of the spill. Call 911 if there are immediate threats to life, health or injuries. All spills inside of a fume hood can be swept into the cup sink using a sponge or squeegee and diluted 3 to 1 with water at the cup sink. Clean up and disposal spill related materials must follow all UAA Hazardous Waste Guidelines and any other State and Federal disposal requirements. Call hazardous waste manager at or EHS / RMS at

20 Medical Surveillance Medical surveillance is required: prior to assignments to areas where exposure may be above STEL at least annually where exposure may be at or above the STEL whenever an employee shows signs/symptoms of toxic levels of exposure Exposure levels are determined without regard to respirator use

21 Medical Surveillance Medical surveillance includes: Administration of medical disease questionnaire Determination if a medical examination is necessary Examinations for employees who are at increased risk for exposure to formaldehyde Medical examinations include: a physical exam laboratory examinations any other necessary tests counseling of employees

22 Medical Surveillance Written physician opinions include: Physician s opinion about employee s medical condition Recommended limitations Statement of medical conditions Employees get copies of the written opinions within 15 working days Records are retained for the duration of employment plus 30 years

23 Formaldehyde / Formalin Waste Management Place formaldehyde waste solutions in (10 L or 20 L) carboys label with: Formaldehyde Waste Danger: Toxic, Potential Cancer Hazard Keep the carboy sealed at all times when not adding wastes to it Keep the carboy in a chemical fume hood at all times Log the concentration and volume on the log sheet provided with the waste carboy Fill out the chemical waste form: Link to Chemical Waste Disposal Form Contact the hazardous waste manager at or EHS/RMS for pickup and or assistance All disposed formaldehyde must be entered into the EHS/RMS waste log for regulatory requirements Link to FORMALDEHYDE STANDARD & UAA FORMALDEHYDE SOP

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