Isopropyl Alcohol 90-10%

Transcription

1 Material Safety Data Sheet Isopropyl Alcohol 90-10% 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Isopropyl Alcohol 90% Synonyms/Generic Names: IPA, Isopropanol, 2-propanol Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Columbus, WI For More Information Call: IN CASE OF EMERGENCY CALL: CHEMTREC (Monday Friday 8:00-4:30) (24 Hours/Day, 7 Days/Week) COMPOSITION/INFORMATION ON INGREDIENTS Weight % Component CAS # EINECS# / ELINCS# Classification* 90% Isopropyl Alcohol F; R11; Xi; R36,R67 Balance Water N/A N/A *Symbol and R phrase according to EC Annex1 ** Subject to the reporting requirements of SARA Title III Section HAZARDS IDENTIFICATION Clear, colorless solution with alcohol odor. R11 Highly flammable. R36 Irritating to eyes R37 Vapors may cause drowsiness and dizziness. S2, S7, S16 Routes of Entry: Eyes, Skin, absorption, Inhalation and ingestion. Revised on 5/27/2010 Page 1 of 7

2 Ingredients found on carcinogen lists: INGREDIENT NAME NTP STATUS IARC STATUS OSHA LIST ACGIH Isopropyl Alcohol Not Listed Not Listed Not Listed Not Listed 4. FIRST AID INFORMATION Inhalation: Inhalation can cause irritation of mucous membranes and central nervous system depression. Symptoms include coughing, wheezing, headache, disorientation, blurred vision, dizziness, fatigue or nausea. Move casualty to fresh air and keep at rest. Get medical attention if symptoms persist. Eyes: Skin: Causes irritation. Symptoms include redness, excessive blinking and watering eyes. In case of eye contact, rinse with plenty of water and seek medical attention if irritation continues. Contact may cause irritation. Symptoms include burning, itching, redness, may be harmful if absorbed through skin. Wash with soap and water. Get medical attention if symptoms persist. Ingestion: May be harmful if swallowed. Symptoms include nausea vomiting and central nervous system depression. Wash out mouth with water and give 1-2 glasses of water or milk. Do Not induce vomiting, aspiration hazard! Get medical attention immediately. 5. FIRE-FIGHTING MEASURES FLAMMABLE PROPERTIES: Flash Point: 22 C (74 F) Flash Point method: Closed Cup Autoignition Temperature: Upper Flame Limit (volume % in air): 12% Lower Flame Limit (volume % in air): 2.5% Extinguishing Media: Class 1B Flammable liquid. Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. Cool containers with water. Special fire-fighting procedures: Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. Use water spray to cool fire-exposed containers and disperse vapors. Containers may rupture in the heat of the fire. Do not use direct water stream, may spread the fire. Hazardous combustion products: Emits toxic fumes under fire conditions. Carbon Oxides. (See also Stability and Reactivity section). Unusual fire and explosion hazards: Vapors can travel to a source of ignition and flash back. Containers may explode in a fire. Cool containers from a distance using water spray. Flames may be invisible. Revised on 5/27/2010 Page 2 of 7

3 6. ACCIDENTAL RELEASE MEASURES Personal precautions: See section 8 for recommendations on the use of personal protective equipment. Environmental precautions: Prevent spillage from entering drains. Absorb spill with sand or other noncombustible absorbent material, then place in a suitable container for disposal. Clean surfaces thoroughly with water to remove residual contamination. Any release to the environment may be subject to federal/national or local reporting requirements. Dispose of all waste or cleanup materials in accordance with local regulations. 7. HANDLING AND STORAGE Normal handling: Use with adequate ventilation and grounding. Wash thoroughly after using. Keep container closed when not in use. Storage: Store in tightly closed, original containers in a cool, dry, well ventilated area. Do not store with strong oxidizing agents, strong acids, peroxides, aldehydes, halogens, ammonia, acid anhydrides or alkali metals. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure controls: Ventilation and appropriate grounding of containers. Chemical name Regulatory List Value and type Isopropyl Alcohol USA OSHA PEL 980 mg/m 3 USA ACGIH TLV 492 mg/m 3 USA NIOSH REL 980 mg/m 3 OSHA IDLH 2000 ppm TWA: Time Weighted Average over 8 hours of work. TLV: Threshold Limit Value over 8 hours of work. REL: Recommended Exposure Limit STEL: Short Term Exposure Limit during x minutes. IDLH: Immediately Dangerous to Life or Health Ventilation: Provide local exhaust, preferably mechanical. Respiratory protection: Full or half face respirators with organic cartridges if exposure levels exceed PELs. Eye protection: Wear chemical safety glasses or goggles. Skin and body protection: Wear nitrile or rubber gloves, apron or lab coat. Other Recommendations: Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. Revised on 5/27/2010 Page 3 of 7

4 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear, colorless Physical state: liquid Odor: mild alcohol Odor Threshold: Specific Gravity: 0.81 ph: Melting Point/Freezing Point: Boiling Point/Range: Flammability: Flammable (See section 5) Flash point: (See section 5) Evaporation Rate (Butyl Acetate =1): Explosive Limits: (See section 5) Vapor Pressure (at 20ºC): Vapor Density (air =1): Solubility: Completely soluble in water Partition coefficient/n-octanol/water: % Volatile: 100% Autoignition Temperature: See section STABILITY AND REACTIVITY Stability: Stable Conditions to avoid: Keep away from heat, flame and sparks. Incompatibility: Acids, Alkali metals, Oxidizing agents, iron salts, potassium, aluminum. May attack plastics, rubber Hazardous decomposition products: Carbon oxides. Hazardous polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Acute Effects: See section 4 for symptoms of exposure and effects. Likely routes of exposure are Ingestion and inhalation. Target organs: Gastrointestinal tract, Liver, Cardiovascular system., Kidney, Nerves, Kidney Acute Toxicity Data: LD50 Oral - rat mg/kg LC50 Inhalation - rat - 8 h ppm LD50 Dermal - rabbit mg/kg Chronic Effects: Ingestion may cause blindness. Teratogenicity: Mutagenicity: Embryotoxicity: Pre-and Post-implant mortality. Revised on 5/27/2010 Page 4 of 7

5 Synergistic Products/Effects: 12. ECOLOGICAL INFORMATION Ecotoxicity (aquatic and terrestrial): LC 50 - Pimephales promelas (fathead minnow) 9,640 mg/l - 96 h EC 50 - Daphnia magna (Water flea) - 5,102 mg/l - 24 h Persistence and Degradability: Bioaccumulative Potential: Mobility in Soil: Other Adverse Effects: 13. DISPOSAL CONSIDERATIONS RCRA: Hazardous waste? Yes RCRA ID number: DOO1 Waste Residues: Absorb on non-combustible material and hold for disposal through a licensed contractor. Users should review their operations in terms of the applicable federal/nation or local regulations and consult with appropriate regulatory agencies before discharging or disposing of waste material. Product containers: Empty containers will retain residues which may be flammable. Do not cut, weld or expose to heat or flames. Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies before discharging or disposing of waste material. The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may significantly change the characteristics of the material and alter the waste classification and proper disposal methods. 14. TRANSPORTATION INFORMATION DOT: UN1219, Isopropanol, 3, pg II TDG: UN1219, Isopropanol, 3, pg II PIN: IDMG: UN1219, Isopropanol, 3, pg II Marine Pollutant: No IATA/ICAO: UN1219, Isopropanol, 3, pg II RID/ADR: Class 3 Revised on 5/27/2010 Page 5 of 7

6 15. REGULATORY INFORMATION TSCA Inventory Status: All ingredients are listed on the TSCA inventory. Federal and State Regulations: Connecticut hazardous material survey: Isopropyl Alcohol Illinois toxic substances disclosure to employee act: Isopropyl Alcohol Rhode Island RTK hazardous substances: Isopropyl Alcohol Pennsylvania RTK: Isopropyl Alcohol Minnesota: Isopropyl Alcohol Massachusetts RTK: Isopropyl Alcohol Massachusetts spill list: Isopropyl Alcohol New Jersey: Isopropyl Alcohol Louisiana RTK reporting list: Isopropyl Alcohol California Director's List of Hazardous Substances: Isopropyl Alcohol SARA 302/304/311/312 extremely hazardous substances: Not Listed SARA 313 toxic chemical notification and release reporting: Isopropyl Alcohol CERCLA: Hazardous Substances: Not Applicable California Proposition 65: WHMIS Canada: DSCL (EEC): Not Listed Class B-2 - Flammable liquid R11 Highly Flammable. HMIS (U.S.A.) Health Hazard 1 Fire Hazard 3 Reactivity 0 National Fire Protection Association (U.S.A.) Flammability 3 Health 1 0 Reactivity Specific hazard Revised on 5/27/2010 Page 6 of 7

7 Protective Equipment: ADR (Europe): TDG (Canada): DSCL (Europe): 16. OTHER INFORMATION Current Issue Date: May 27, 2010 Prepared by: Sherry Brock Disclaimer: Columbus Chemical Industries, Inc. ( Columbus ) believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Columbus has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. COLUMBUS MAKES NO WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION) WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE. Revised on 5/27/2010 Page 7 of 7