Safety data sheet according to 1907/2006/EC, Article 31

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1 Page 1/7 * 1 Identification of the substance/mixture and of the company/undertaking Product identifier CAS Number: EINECS Number: Index number: X Registration number Relevant identified uses of the substance or mixture and uses advised against not determined. Application of the substance / the preparation Food Details of the supplier of the safety data sheet Manufacturer/Supplier: Chemische Fabrik WIBARCO GmbH Postfach D Ibbenbüren Tel.: +49-(0) Further information obtainable from: Product safety Tel.: +49 (0) juergen.mueller@hansagroup.de Emergency telephone number: GIZ-Nord, Göttingen, Germany Member of EPECS Network * 2 Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 GHS05 corrosion Met. Corr.1 H290 May be corrosive to metals. Skin Corr. 1B H314 Causes severe skin burns and eye damage. GHS07 STOT SE 3 H335 May cause respiratory irritation. Classification according to Directive 67/548/EEC or Directive 1999/45/EC C; Corrosive R34: Causes burns. Xi; Irritant R37: Irritating to respiratory system. Label elements Labelling according to Regulation (EC) No 1272/2008 The substance is classified and labelled according to the CLP regulation. (Contd. on page 2)

2 Page 2/7 Hazard pictograms (Contd. of page 1) GHS05 GHS07 Signal word Danger Hazard statements H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. Precautionary statements P234 Keep only in original container. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P309+P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. Other hazards Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. * 3 Composition/information on ingredients Chemical characterization: Substances CAS No. Description hydrochloric acid Identification number(s) EINECS Number: Index number: X Dangerous components: CAS: EINECS: hydrochloric acid C R34; Xi R37 Met. Corr.1, H290; Skin Corr. 1B, H314; STOT SE 3, H % * 4 First aid measures Description of first aid measures General information: Personal protection for the First Aider. Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air. Call a doctor immediately. In case of unconsciousness place patient stably in side position for transportation. After skin contact: Immediately rinse with water. Cover wound with a sterile dressing. Call a doctor immediately. After eye contact: Protect unharmed eye. (Contd. on page 3)

3 Page 3/7 (Contd. of page 2) Rinse opened eye for several minutes under running water. Then consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting - aspiration hazard. Call in a physician immediately and show him the Safety Data Sheet. Never give anything by mouth to an unconscious person. Information for doctor: Indication of any immediate medical attention and special treatment needed Treat symptomatically No specific antidote known. * 5 Firefighting measures Extinguishing media Suitable extinguishing agents: Water Special hazards arising from the substance or mixture Hydrogen chloride (HCl) Advice for firefighters Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. Additional information Cool endangered receptacles with water spray. Collect contaminated fire fighting water separately. It must not enter the sewage system. Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. * 6 Accidental release measures Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear protective equipment. Keep unprotected persons away. Mount respiratory protective device. Environmental precautions: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. Methods and material for containment and cleaning up: Use neutralizing agent. Send for recovery or disposal in suitable receptacles. Ensure adequate ventilation. Reference to other sections See Section 8 for information on personal protection equipment. See Section 13 for disposal information. * 7 Handling and storage Handling: Precautions for safe handling The usual precautionary measures are to be adhered to when handling chemicals. Avoid contact with skin, eyes and clothing. Do not breathe vapour. Carry out filling operations only at sites with extractors available. Ensure good ventilation/exhaustion at the workplace. Information about fire - and explosion protection: Product itself is non-combustible (Contd. on page 4)

4 Page 4/7 Conditions for safe storage, including any incompatibilities Storage: Requirements to be met by storerooms and receptacles: Keep container tightly sealed. Unsuitable material: metal Information about storage in one common storage facility: Not required. Further information about storage conditions: Store receptacle in a well ventilated area. Protect from heat and direct sunlight. (Contd. of page 3) * 8 Exposure controls/personal protection Additional information about design of technical facilities: No further data; see item 7. Control parameters Ingredients with limit values that require monitoring at the workplace: hydrochloric acid WEL Short-term value: 8 mg/m³, 5 ppm Long-term value: 2 mg/m³, 1 ppm (gas and aerosol mists) Additional information: The lists valid during the making were used as basis. Exposure controls Personal protective equipment: General protective and hygienic measures: Avoid contact with the eyes and skin. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Clean skin thoroughly immediately after handling the product. Do not inhale gases / fumes / aerosols. Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device. Short term filter device: Filter E Protection of hands: Protective gloves Material of gloves PVC gloves Recommended thickness of the material: approx. 0.7 mm Penetration time of glove material Time for permeation > 480 min Eye protection: Gauze goggles Face protection Body protection: Acid resistant protective clothing Protective clothing should be selected specifically for the working place, depending on concentration and quantity of the hazardous substances handled. The resistance of the protective clothing to chemicals should be ascertained with the respective supplier. (Contd. on page 5)

5 Page 5/7 (Contd. of page 4) * 9 Physical and chemical properties Information on basic physical and chemical properties General Information Appearance: Form: Solution Colour: colourless to slightly yellow Odour: Pungent ph-value: <1 Change in condition Melting point/melting range: C Boiling point/boiling range: C Flash point: Not applicable. Flammability (solid, gaseous): Product is not flammable. Danger of explosion: Product does not present an explosion hazard. Vapour pressure at 20 C: mbar Density at 20 C: 1.15 g/cm³ Solubility in / Miscibility with water: 90% Segregation coefficient (n-octanol/water): log POW Viscosity: Dynamic at 20 C: ca.2 mpas * 10 Stability and reactivity Reactivity Chemical stability Thermal decomposition / conditions to be avoided: To avoid: heat Possibility of hazardous reactions Reacts with alkali (lyes). Incompatible materials: alkali (lyes). Hazardous decomposition products: Hydrogen chloride (HCl) * 11 Toxicological information Information on toxicological effects Acute toxicity: LD/LC50 values relevant for classification: Oral LD mg/kg (rat) Dermal LD50 >5.000 mg/kg (rabbit) Inhalative LC50/1 h 1.68 mg/l (rat) Specific symptoms in biological assay: Inhalation may lead to irritation of the respiratory tract. Primary irritant effect: on the skin: Caustic effect on skin and mucous membranes. on the eye: Caustic Sensitization: No sensitizing effects known. Additional toxicological information: After inhalation: may lead to strong irritation or burns of the respiratory system. (Contd. on page 6)

6 Page 6/7 (Contd. of page 5) Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach. * 12 Ecological information Toxicity Acquatic toxicity: EC80/72 h 56 mg/l (daphnia) LC50/96 h 282 mg/l (Gambusia affinis) Persistence and degradability Anorganic product, is not removable from water by biological cleaning process Behaviour in environmental systems: Bioaccumulative potential Due to the distribution coefficient n-octanol/water an accumulation in organisms is not expected. Additional ecological information: General notes: Water hazard class 1(VwVwS): slightly hazardous for water Do not allow product to reach ground water, water course or sewage system. Results of PBT and vpvb assessment PBT: Not applicable. vpvb: Not applicable. * 13 Disposal considerations Waste treatment methods Recommendation Must not be disposed together with household garbage. Do not allow product to reach sewage system. Disposal must be made according to official regulations. Uncleaned packaging: Recommendation: Disposal must be made according to official regulations. * 14 Transport information ADR/RID class: 8 Corrosive substances. Danger code (Kemler): 80 UN-Number: 1789 Packaging group: II Hazard label: 8 UN proper shipping name: HYDROCHLORIC ACID Tunnel restriction code E Inland shipping ADN/ADNR: 1789 ADN/R Class: 8 Maritime transport IMDG: IMDG Class: 8 UN Number: 1789 Label 8 Packaging group: II EMS Number: F-A,S-B (Contd. on page 7)

7 Page 7/7 Proper shipping name: HYDROCHLORIC ACID Air transport ICAO-TI and IATA-DGR: (Contd. of page 6) ICAO/IATA Class: 8 UN/ID Number: 1789 Label 8 Packaging group: II Proper shipping name: HYDROCHLORIC ACID UN "Model Regulation": UN1789, HYDROCHLORIC ACID, 8, II Special precautions for user Warning: Corrosive substances. * 15 Regulatory information Chemical safety assessment: A Chemical Safety Assessment has not been carried out. * 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. Relevant phrases H290 May be corrosive to metals. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. R34 R37 Causes burns. Irritating to respiratory system. Department issuing MSDS: Product safety Contact: Dr. Müller Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals EINECS: European Inventory of Existing Commercial Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Sources Literature value * Data compared to the previous version altered.

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