SCOPE. Benzene Some common halogenated hydrocarbons Metals Lead Chromium Corrosive materials Acids and acid anhydride Alkalis Asbestos Silica

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1 COMMON CHEMICALS

2 SCOPE Benzene Some common halogenated hydrocarbons Metals Lead Chromium Corrosive materials Acids and acid anhydride Alkalis Asbestos Silica

3 BENZENE Colourless, flammable liquid Used as a solvent in rubber and shoe manufacturing Used in production of styrene, phenol and cyclohexane; Essential in manufacture of detergents, pesticides, solvents and paint removers Present in gasoline-up to 5%

4 BENZENE: HEALTH EFFECTS Enters body by inhalation or through skin Dizziness, lightheadedness, headache, loss of appetite, upset stomach, irritation of nose & throat High exposures can cause irregularities in heart beat which can lead to death Repeated exposure can damage bone marrow leading to aplastic anaemia Can cause leukemia

5 BENZENE: CONTROLS Substitution-e.g. using toluene, white spirit, xylene Enclosure and/or exhaust ventilation Isolation PPE- respirator with organic solvent cartridge or PAPR Viton or PVA gloves Eating, smoking or drinking not allowed

6 HALOGENATED HYDROCARBON From natural processes (e.g. chloroform) or man-made (e.g. methylene chloride, 1,2-dichloroethane and trichloroethylene) Some can deplete ozone layer (carbon tetrachloride and 1,1,1-trichloroethane) Exposure to these solvents in agriculture; rubber and plastics industry; chemical industry; mfg of pharmaceuticals and hygiene products; metal works; assembling of instruments and equipment; and dry cleaning

7 HALOGENATED HYDROCARBON: HEALTH EFFECTS Most have narcotic effects May affect heart and damage liver Ethylene dibromide, vinyl bromide and epichlorohydrin are classified by IARC as probably carcinogenic to humans Bromodichloromethane, carbon tetrachloride, chloroform, 1,2- dichloroethane, 1,3-dichloropropene, methylene chloride and tetrachloroethylene are possibly carcinogenic Halogenated hydrocarbon solvents decompose producing toxic and corrosive gases when brought in contact with open flames or hot surfaces

8 HALOGENATED HYDROCARBONS: PREVENTIVE MEASURES Select solvent with least serious health effects Prevent contact with solvent and vapour using closed systems, isolated working areas, ventilation at source, protective clothing and respiratory equipment Monitoring of exposure Safe work practice Labelling of containers Training of users

9 METALS: LEAD Bluish grey, heavy metal, soft and very resistant to corrosion Melting point is 327 C and evaporates above 500 C-these temperatures are reached in welding, grinding or soldering Tetraethyl lead and tetramethyl lead, used as fuel additives, are flammable liquids which evaporate easily at room temperature

10 LEAD: HEALTH EFFECTS Can be absorbed through the respiratory tract or from stomach, lead tetraethyl can be absorbed through skin It combines with red blood cells causing anaemia It affects the nervous system, including the brain Lead may pass through the placenta from mother to unborn baby, and also present in milk if the mother has been exposed

11 LEAD: CONTROL Preventive engineering solutions such as use of local exhaust ventilation system to trap lead dusts and fumes Substitution may be possible such as using tin-silver instead of tin-lead solder Banning use of lead in paints or restricting use of organic lead in petrol Monitoring of lead exposure among workers Medical surveillance on exposed workers Maintain adequate hygienic level by good personal hygiene, separate clothing for work that should not be brought back home, adequate washing facilities

12 METAL: CHROMIUM & CHROMIUM COMPOUNDS Steel grey metal when in a clean, metallic state 75% of chromium consumption is for metallurgical purposes; 10% goes to refractory industry and 10% goes into chemical compounds Chromium content in stainless steel ranged from 3% to 27% Compounds of chromium have very different roles in nature and different effects on human health depending on their oxidation state

13 CHROMIUM & CHROMIUM COMPOUND: HEALTH EFFECTS Low levels of chromium are ubiquitous and essential Chromium salts, particularly in hexavalent state, are irritant, corrosive, sensitizing and potential or proven carcinogens (lung cancer) Inhalation is primary route of exposure Hexavalent chromium compounds can cause ulceration on the hands, forearm or the feet; or can occur in the nose if dust containing it is inhaled Chronic inhalation or skin contact to trivalent chromium compounds may lead to allergic reactions such as asthma Acute exposure due to ingestion may lead to toxic effects on GI tract and may damage kidneys

14 CHROMIUM: CONTROL Control of aerosols (dusts and mists) by closed processes, effective ventilation at source, protective clothing and respirators Immediate clean-up of spills to prevent dispersion as airborne dust Wet cleaning methods used wherever possible Vacuuming rather than sweeping Using less hazardous process, e.g. use of MIG (Metal Inert Gas) and TIG (Tungsten Inert Gas) welding instead of manual metal arc welding Use of fully impermeable, chemically resistant PPE in electroplating Air monitoring Medical surveillance

15 CORROSIVE MATERIALS Acids and anhydrides E.g. Acetic acid and acetic anhydride; phosphoric acid and phosphorus trioxide Alkalis E.g. sodium hydroxide; organic amines-ethanolamine Halogens and acid halides E.g. chlorine gas; chlorite solutions Other compounds E.g. mercury, ammonium polysulphide, hydrazine, peroxides Note: acid anhydrides are compounds having similar properties to acids, they react with water forming the corresponding acids

16 CORROSIVE MATERIALS: HEALTH EFFECTS Irritation, ulceration Chemical burns (due to heat) Affect skin, eyes and respiratory tract Most susceptible to rapid, severe and often irreversible damage are those of the eyes Acid fumes can corrode teeth Effects depend on the properties of the material, its concentration, and duration and frequency of contact Irritation effect is reversible inflammatory effect Corrosion effect is irreversible effect where tissue is permanently damaged Exposure may increase risk of cancer such in pickling operation in metal industry where risk of larynx and lung cancer was elevated

17 CORROSIVE MATERIALS: CONTROL Organizing storage to prevent contact with incompatibles Limiting quantity stored Choice of material and equipment Minimizing hazard to workers and surrounding Monitoring and alarm systems Use of dykes and reservoirs to collect spillage Good ventilation Exclusion area and entry control Fire-fighting equipment, safety equipment such eye wash & emergency shower Personal protective equipment

18 ASBESTOS Two types of asbestos, i.e. amphibole and serpentine Amphiboles are straight, sharp, almost needle-shape fibres used commercially, which include amosite (brown asbestos) and crocidolite (blue asbestos), as well as less common types (tremolite, actinolite and anthophyllite). Amphiboles are extremely hazardous. crocidolite amosite

19 ASBESTOS Serpentines are so named because of their curved, snake-like shape. Chrysotile (white asbestos), the most common serpentine fibre, is considerably less hazardous than the amphibole varieties. chrysotile

20 HEALTH EFFECTS OF ASBESTOS Risk of developing 3 severe, debilitating respiratory diseases: asbestosis; lung cancer; and mesothelioma. It can cause gastrointestinal and laryngeal cancers in humans, but to a far lesser extent than lung cancer. ILO estimated 100,000 death due to asbestos annually

21 CONTROL OF ASBESTOS Ban Substitution Engineering control Wet methods Local exhaust ventilation Safe work procedures and practices Vacuuming rather than sweeping Change rooms & lockers Air monitoring Medical surveillance Use of personal protective equipment

22 INDUSTRIAL DUST METALLIC (lead) INORGANIC NON- METALLIC ORGANIC (cotton, grain) coal CONTAINING SILICA COMBINED SILICA (talc) FREE SILICA CRYSTALLINE (quartz) AMORPHOUS (diatomaceous earth)

23 CRYSTALLINE SILICA HEXAGONAL CUBIC / TETRAGONAL RHOMBIC 867 o C 1470 o C quartz cristobalite tridymite

24 SILICA HEALTH EFFECTS Silicosis Lung cancer

25 A former tunneling worker suffered from silicosis Lung changes 54 y.o. 61 y.o. Tunneling from18 to 38 years old

26 CONTROL OF SILICA EXPOSURE Ban Substitution Engineering control Wet methods Local exhaust ventilation Safe work procedures and practices Vacuuming rather than sweeping Change rooms & lockers Air monitoring Medical surveillance Use of suitable personal protective equipment

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