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1 Kamel Makhlouf NTCE: Materials Design (DKN) Tel: europe.co.uk

2 Agenda 1. What is VOC 2. VOC Regulation Trend 3. JAMA Requirement for Vehicle Cabin VOC 4. Nissan Action Plan for Cabin VOC 5. Cabin VOC Specification 6. Parts VOC Specification 7. Parts VOC Test Method 8. VOC Counter-measure Examples

3 1. What are VOCs? Definition: General term of Volatile Organic Compounds Classification SVOC Semi The boiling point( ( ) Representative substances DOP n-hexadecane General Origins: materials such as Adhesives, Paints, solvents, Plasticiser, insecticide etc VOC VVOC Very Xylene Toluene n-hexane Acetaldehyde Formaldehyde Classification by WHO definition

4 2. VOC Regulation Trend Background Sick house syndrome = social problem in Japan, hence Housing VOC regulation was established in Japan. Some vehicle cabin VOCV lawsuits started in Japan.. Through JAMA (Japanese Automobile Manufacturers Association), a voluntary VOC specification was agreed. Similarly, the Chinese government decided to introduce a vehicle cabin VOC regulation from Jul (The Chinese regulation includes not only PV but also trucks and buses) In Europe: growing customer awareness of cabin VOC emission. (Several German OEMs have set themselves VOC targets based on VDA test methods. Others OEMs are considering how to proceed.)

5 2. VOC Regulation Trend WHO guideline & Japanese regulation for VOC Substances Formaldehyde Toluene Xylene p-dichlorobenzene Ethylbenzene Styrene Chlorpyrifos Di-n-butyl phthalate Tetradecane Di-(2 (2-ethylhexyl)phthalate Diazinone Acetaldehyde Fenobucarb TVOC Guideline of WHO (mg/m3) Guideline of the Ministry of Health and Welfare of Japan (mg/m3)

6 3. JAMA Requirement for Vehicle Cabin VOC 13 substances requirement for Vehicle cabin Substances Formaldehyde Acetaldehyde Toluene Ethylbenzene Xylene Styrene p-dichlorobenzene Tetradecane Chlorpyrifos Di-n-butyl phthalate Di-2-ethylhexyl phthalate Diazinon Fenobucard Vehicle cabin requirement ( µ g/m3) Currently these substances are not included in vehicle parts.

7 4. Nissan Action Plan for Cabin VOC Nissan Global policy regarding cabin VOC Applied from new launch vehicles after July, Interior parts must meet the requirements of NES M0403. Note: For all new models destined to the Chinese market, the VOC regulation applies from April 07. The VOC regulation only applies to current models from Jul 08. Nissan VOC Global policy Global Japan '06 '07 '08 '09 '10 '15 Vehicle Indoor VOC Regulations Applied After 07/7 new launch vehicle ( New model) Applied from April. 05,, for New launched vehicle & m/c Chinese regulation Study of Criteria Euro III New model after Apr. 07 Current model by Jul. 08

8 5.1 Cabin VOC Specification Based on the JAMA recommendation, Nissan has developed vehicle cabin VOC test specification KM

9 5.2 Cabin VOC Specification

10 5.3 Cabin VOC Specification

11 5.4 Cabin VOC Specification VOC pump and Tenax tube: Aldehydes pump and Sep-Pak cartridge:

12 6.1 Parts VOC Specification NES M0403

13 6.2 Parts VOC Specification No Components Parts

14 7.11 Parts Test Method NES M0402

15 7.22 Parts Test Method NES M0402

16 8.1 VOC Counter-measure Examples Various VOC sources & c/measures: Paint, Adhesive, Solvent, Some fabrics etc.. Substance Formaldehyde Acetaldehyde VOC substance source Felt/Yarn Leather Fabric( Cloth Backing) Purpose/ Function Binder Tanning agent <Example> Cloth backing Counter-measure example Binder backing material change Aldehyde free tanning agent Aldehyde free cloth backing adoption Issue/ concern Durability reduction Toluene Xylene Adhesives Adhesion promoter Paint for trim parts Top coatings Solvent Solvent Solvent Solvent Solvent change addition of drying process Solvent change addition of drying process Solvent change, drying process addition drying process addition Adhesion loss Adhesion, Productivity Adhesion, Productivity Productivity Urethane pad Solvent Solvent change, drying process addition As above Mold release agent Solvent Solvent change Cleaners Solvent Solvent change

17 8.2 VOC Counter-measure Examples Adhesive Primer Paint Mat. Change ( Low VOC Urethane) Cushion mold release agent Leather tanning agent Artificial leather surface treatment Absorbent Backing material Inst Door trim Wood grain effect Seat Headlining Carpet Bodyside trim Rr P/shelf Sunroof sunshade Lug trim

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