Material Safety Data Sheet

Transcription

1 Number : W106A Revision : 1.02 Date : 16/02/2004 Replace : 14/10/2003 Xi - Irritant 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING Type of product and use: Fuel Additive. Company identification: WYNN'S BELGIUM N.V. Industriepark West 46 B-9100 Sint-Niklaas tel: INT fax: INT Emergency phone Nr.: BIG 32.(0)14/ COMPOSITION/INFORMATION ON INGREDIENTS Composition: Mixture to prevent bacterial contamination of fuels Hazardous component(s): 4-methylpentan-2-ol (CAS / EINECS ) wt%: Symb: Xi R: 10, 37 3,3'-methylenebis(5-methyloxazolidine) (CAS / EINECS ) wt%: <25% Symb: Xn R: 22,31,37/38,41,43 kerosine (petroleum) (CAS / EINECS ) wt%: <10% Symb: Xn,N R: 10,38,51/53,65 3. HAZARDS IDENTIFICATION Important hazards-fire: Important hazards-toxicity: Important hazards-chemical reactions: Flammable. Gas/vapour explosive with air within explosion limits. May be ignited by sparks. May cause irritation. Vapours may cause drowsiness and dizziness. Contact with strong acids causes violent reaction. 4. FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Remove to fresh air. In case of loss of consciousness, give artificial respiration. Seek medical advice. Wash immediately with plenty of water. Wash thoroughly with soap and water. If inflammation or irritation persists, seek medical advice. If irritation persists, seek medical advice. Wash immediately with plenty of water. If swallowed, DO NOT induce vomiting. Keep at rest. Get prompt medical attention. Rinse mouth. Give water to drink. Publication Date : Number : W106A Page : 1 / 5 Pollux6

2 5. FIRE-FIGHTING MEASURES Material Safety Data Sheet Give capsules of active carbon. Seek medical attention. Extinguishing media: - Suitable: Carbon dioxide, dry chemicals, foam (AFFF/ATC), water spray (fog). - Not to be used: None. Firefighting instructions: The vapours are heavier than air, spreads along the ground. If a leak or spill has not ignited, use water spray to disperse the vapors and to protect men attempting to stop a leak. Move product away from danger area. Special exposure hazards: Fumes, smoke, carbon dioxide (CO2), carbon monoxide (CO) (Toxic). Special protective equipment for fire Heat/fire exposure: compressed oxygen apparatus. fighters: Appropriate protective clothing. 6. ACCIDENTAL RELEASE MEASURES Personal precautions: Personal Protective Equipment must be worn, see section 8 (Personal Protection). Appropriate protective clothing. Protective gloves (Plastic, impervious). Safety goggles/visor. Methods for cleaning up: - On soil: Take measures to minimize the effect on the ground water. Consult an expert on disposal of recovered material and ensure conformity to local disposal regulations. Recover small spills with a suitable absorbent. Shovel into suitable and closed container for disposal. Remove sources of ignition. Prevent product from entering drains / surface water / ground water. 7. HANDLING AND STORAGE Handling: When using, do not eat, drink or smoke. Ensure good ventilation. Prolonged or repeated contact may cause transcient irritation. Keep containers closed when not in use. Launder contaminated clothing before reuse. Keep away from all sources of ignition. Storage: Keep away from all sources of ignition. Keep container tightly closed. Store in dry, cool, well ventilated area. Keep away from heat. Store at temperatures below 50 C Packaging: - General: Keep preferably in the original packaging; if not, copy all indications of the labelling on the new packaging. - Suitable: Carbon Steel, Stainless steel, Publication Date : Number : W106A Page : 2 / 5

3 Polyamide - Not to be used: Polypropylene, Polyethylene, 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Recommended engineering controls: When using, do not eat, drink or smoke. Ensure good ventilation in case of possible formation of vapour, mist or aerosol. Avoid contact with skin and eyes. Personal protection: Handle in accordance with good industrial hygiene and safety procedures. - Respiratory protection: In case of insufficient ventilation wear suitable respiratory equipment. - Skin and hand protection: Appropriate protective clothing and gloves Nitrile, Neoprene, - Not to be used: polyvinylchloride (PVC), Natural rubber, Butyl rubber, - Eye protection: Safety goggles/visor. 9. PHYSICAL AND CHEMICAL PROPERTIES These are indicative values only. Please refer also to the product specification sheet. Appearance: Liquid. Colourless to pale yellow. Clear. Odour: Characteristic. ph : ~9 Boiling point: >100 C Melting point: Not yet determined. Flash point: 41.5 C Explosion limits: 1-7 % Vapour pressure at 20 C: <1 hpa Solubility in water: Negligible. refractive index at 20 C (ASTM D-1747): Density at 15 C: 858,7 kg/m³ 10. STABILITY AND REACTIVITY Stability: Stable in normal conditions of use. Conditions to avoid: Store at temperatures below 50 C Store away from direct sunlight. Keep away from heat. Avoid contact with strong acids Materials to avoid: None known. Hazardous decomposition products: None known. 11. TOXICOLOGICAL INFORMATION Publication Date : Number : W106A Page : 3 / 5

4 Oral LD50 (rat): Dermal LD50 (Rabbit): Inhalation LC50 (Rat/4h): Skin contact: Eye contact: Skin sensitization test: >2500 mg/kg No information available. No information available. Irritating. Irritating. Data not available. 12. ECOLOGICAL INFORMATION Mobility: Low, due to low water solubility. Degradability: This substance is expected to biodegrade rapidly. Ecotoxicity and bioaccumulation: No information available. WGK class (Germany): DISPOSAL CONSIDERATIONS Disposal of product: Disposal of packaging: This product is not suitable for disposal by either landfill or via municipal sewers, drains, natural streams or rivers. Dispose of in a safe manner, in accordance with local regulations. Dispose of in a safe manner, in accordance with local regulations. 14. TRANSPORT INFORMATION UN 1993 Proper shipping name: Flammable liquid, n.o.s. (methylisobutylcarbinol) --ADR/RID: LQ7 Class: 3, III Hazard code: 30 Label: 3 --MARITIME TRANSPORT (IMO-IMDG): LQ=5L Klasse: 3 Packing group: III EMS: F-E, S-E Marine Pollutant: / --AIR TRANSPORT (CAO/IATA): Class: 3 Packing group: III Packing instructions: 309/ REGULATORY INFORMATION EEC labelling information: Classification and labelling according to the directives 67/548/EEG and 1999/45/EG. - Symbol(s): Irritant: Xi. - Contains: 3,3'-methylenebis(5-methyloxazolidine) (CAS / EINECS ) - R Phrase(s): R 10: Flammable. R 31: Contact with acids liberates toxic gas. R 37/38: Irritating to respiratory system and skin. R 41: Risk of serious damage to eyes. R 43: May cause sensitization by skin contact. Publication Date : Number : W106A Page : 4 / 5

5 R 52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. - S Phrase(s): S (2): Keep out of reach of children. S 23.2: Do not breathe vapour. S 24: Avoid contact with skin. S 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S 36/37/39: Wear suitable protective clothing, gloves and eye/face protection. S (46): If swallowed seek medical advice immediately and show this container or label. S 61: Avoid release to the environment. Refer to special instructions/safety data sheets. 16. OTHER INFORMATION Sources of key data used: Raw material suppliers'data sheets were used as key data sources in the preparation of this safety data sheet. Nature of revision: New data in Section: 14,15 Text of R phrases mentioned in Section 2 R 10: Flammable. R 22: Harmful if swallowed. R 31: Contact with acids liberates toxic gas. R 37: Irritating to respiratory system. R 38: Irritating to skin. R 37/38: Irritating to respiratory system and skin. R 41: Risk of serious damage to eyes. R 43: May cause sensitization by skin contact. R 51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R 65: Harmful, may cause lung damage if swallowed. This safety data sheet has been made in accordance with the directives 91/155/EEG, 93/112/EEG and 2001/58/EG. It completes the technical directions for use, but does not replace it. The data mentioned on these documents are to our knowledge correct on the date of publication and are provided on the assumption that the product will be used as indicated by the manufacturer/supplier. The indication of these safety data, without being considered as complete, helps the user to fulfil his obligations with regard to dangerous substances. The user is obliged to evaluate the product and use it in a safe way in compliance with the effective laws and stipulations. The user has to make sure that all regulations as to human and environmental protection during handling, storage and use of the products are observed. Publication Date : Number : W106A Page : 5 / 5