* * *Section 1 Identification* * * * * *Section 2 Hazard(s) Identification. Silicomanganese Safety Data Sheet SDS ID: DJJFA012

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1 * * *Section 1 Identification* * * Product Identifier: Silicomanganese Chemical Family: Alloy Recommended Use: Metal Alloys and Steel Manufacture Restriction on Use: None identified Manufacturer Information The David J. Joseph Company Non-Emergency Contact: Safety Department 300 Pike Street Non-Emergency Phone: Cincinnati, OH Emergency Contact: DJJ Emergency Phone: * * *Section 2 Hazard(s) Identification Classification Not classified according to Commission Regulation (EC) No. 1272/2008. GHS Label Elements Symbol(s) Signal Word Hazards Statement(s) Precautionary Statements Prevention Response Storage Disposal Hazard(s) Not Otherwise Classified This substance does not meet the requirement for a PBT or vpvb substance. Page 1 of 5 Issue Date 11/23/2015 Revision 1.00

2 * * *Section 3 Composition / Information on Ingredients* * * CAS Component Percent Manganese >60% Silicon 10%-20% Iron 10%-20% Carbon <3% Phosphorus <1% * * *Section 4 Fist Aid Measures* * * Inhalation If dust is inhaled, remove from contaminated area. Apply artificial respiration if not breathing. Skin Contact If skin contact occurs, remove contaminated clothing and flush skin with running water. Eye Contact If eyes come in contact with dust, flush eyes with running water. Continue flushing until advised to stop by a doctor, or for at least 15 minutes. Ingestion Rinse mouth thoroughly if dust is ingested. Seek medical advice. If swallowed, do not induce vomiting. * * *Section 5 Fire Fighting Measures* * * Extinguishing Media Dry agent. Unsuitable Extinguishing Media Do not use water or halogenated extinguishing media. Specific Hazards Arising from the Chemical May evolve manganese, carbon, silicon and iron oxides when strongly heated. Special Protective Equipment and Precautions for Firefighters Wear full protective equipment including self-contained breathing apparatus when combating fire. Flood with water to cool intact containers and nearby storage areas. * * *Section 6 Accidental Release Measures* * * Personal Precautions, Protective Equipment and Emergency Procedures Protective equipment as described in section 8. Keep unnecessary personnel away. Avoid release into the environment. Prevent contamination of drains or waterways. Page 2 of 5 Issue Date 11/23/2015 Revision 1.00

3 Methods and Materials for Containment and Cleaning Up Collect for reuse if possible. Collect in suitable container for disposal. * * *Section 7 Handling and Storage* * * Precautions for Safe Handling Avoid feeding wet or dusty alloy to steelmaking and alloy making furnaces. Avoid generation and spreading of dust. Provide adequate ventilation. Conditions for Safe Storage Store in a cool, dry, well ventilated area removed from oxidizing agents, acids and foodstuffs. Incompatibilities Oxidizing agents, acids and alkalis. * * *Section 8 Exposure Controls / Personal Protection* * * Exposure Limits Ingredient Reference TWA mg/m3 STEL mg/m3 General dust limit alveolar fraction Germany, TRGS General dust limit Germany, TRGS Manganese and its inorganic compounds, Germany, TRGS General dust limit value, alveolar fraction France, INRS VLEP 5 General dust limit value, France, INRS VLEP 10 Manganese containing exhaust gases France, INRS VLEP 1 General dust limit value, alveolar fraction UK, WEL 4 Silicon General dust limit value, UK, WEL 10 Silicon, Manganese and its inorganic compounds, UK, WEL 0.5 Phosphorus, UK, WEL General dust limit value, alveolar fraction Austria, GKV General dust limit value, Austria, GKV Manganese and its inorganic compounds, Austria, GKV including manganese tetraoxide Phosphorus, Austria, GKV Manganese and its inorganic compounds, Spain, LEPAQE Carbon (powder) Spain, LEPAQE Silicon, alveolar fraction Spain, LEPAQE Silicon, Spain, LEPAQE Phosphorus, respirable gas Spain, LEPAQE (0.02 ppm) Appropriate Engineering controls Ensure adequate ventilation. Individual Protection Measures Eyes/Face Protection Wear dust resistant safety goggles where there is danger of eye contact. Page 3 of 5 Issue Date 11/23/2015 Revision 1.00

4 Skin Protection Wear suitable protective gloves to prevent cuts and abrasions. Respiration Respiratory equipment should be used in case of risk of inhalation of dust. Appearance: Silver/grey metallic lumps * * *Section 9 Physical and Chemical Properties* * * Physical state: Solid Melting/freezing Point: 1350 C Flash Point: UFL: Vapor Pressure: Specific Gravity: Auto Ignition: ph: Boiling Point: OSHA Flammability Class: Non flammable LFL: Vapor Density: Solubility (H20): Insoluble * * *Section 10 Chemical Stability & Reactivity* * * Reactivity Non-reactive under normal conditions of use, storage and transport. Chemical Stability Stable. Conditions to Avoid Dust generation, avoid heat, sparks, open flames or other ignition sources. Incompatible Materials Oxidizing agents, acids, alkalis Hazardous Decomposition Products May evolve manganese, carbon and silicon oxides when heated to decomposition. * * *Section 11 Toxicological Information* * * The mixture does not contain any hazardous ingredients classified according to (EC) 1278/2008 (CLP) and/or 67/584/EEC (DSD). No toxicity to organisms is anticipated. * * *Section 12 Ecological Information* * * Persistence & Degradability Not relevant for inorganic substances. Bioaccumulation Not relevant for inorganic substances. Mobility Low solubility in water and low mobility in the environment. Page 4 of 5 Issue Date 11/23/2015 Revision 1.00

5 PBT and vpvb Assessment This material does not meet the criteria for PBT or vpvb assessment under GHS guidelines. * * *Section 13 Disposal Considerations* * * Disposal Methods Return to the manufacturer or supplier. Contact the manufacturer for additional information. US EPA Waste Number & Descriptions Waste codes should be assigned by the user based on the application for which the product was used. * * *Section 14 Transportation Information* * * US DOT Information Not regulated by the DOT. * * *Section 15 Regulatory Information* * * U.S. Federal Regulations None identified. * * *Section 16 Other Information* * * Reasonable care has been taken in the preparation of this information, but the manufacturer makes no warranty of merchantability or any other warranty, expressed or implied, with respect to this information. The manufacturer makes no representations and assumes no liability for any direct, incidental or consequential damages resulting from its use. The data on this sheet applies only to products sold by corporate subsidiaries of The David J. Joseph Company and may not apply to products sold by others. Page 5 of 5 Issue Date 11/23/2015 Revision 1.00

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