2007. Ж. А., А.. З, Ж. Е. Й, З. О. Л Йapple М. К.З. ъ ИОЗ

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1 ЩВИЩ ЕҐЩЙДЕЩ ВЙЗВА ЛЕЖЕҐЩЙДВГ ЩЛЗВВРЕЕ, 007, 41,, Н Д : Рappleapple apple apple apple applefl appleapple apple apple, applefl fl 007. Ж. А., А.. З, Ж. Е. Й, З. О. Л Йapple М. К.З. ИОЗ К apple Вapple apple applefl apple apple apple, apple, apple appleapple appleapple apple apple appleapple apple, apple apple applefl appleapple apple - apple, applefl fl. З appleapple apple appleapple applefl apple 10% - apple 60%. Чapple- apple ( 1 ) apple apple fl,, [1]. А, - fl apple fl apple- apple []. Йfl 1 fl- flfl apple apple- fl- apple, applefl apple apple apple flfl 3 д 94.3 /, apple applefl 60. З apple appleapple apple (РЙД) apple apple apple appleapple apple apple [3]. appleapple fl apple apple - apple 113 ДК apple ( 1 ) 60% [4]. А РЙД apple- apple apple apple apple appleapple 0шЙ applefl 1 / apple apple (N h > N b ); appleapple applefl H : ВЗ + З В H +З В. (1) И apple (1) apple, applefl H apple apple- appleapple [OH ] [H ] [5]. Ж- applefl ( 1 ) fl apple [6]. Кapple apple apple - apple apple - appleapple apple apple apple apple apple apple apple appleapple, apple H 100%- apple ( 1 ) [7]: Cl + H ( ) + Cl + H +, K ч /( ), [8] H + + H H. () Е apple applefl ( 1 ) fl- apple: 1 Cl + ВЗ + З В = ( 1 ) +З В + Йl. (3) Дapplefl OH apple- H apple apple apple OH apple Д [8, 9], - apple apple apple apple OH apple apple- apple. Вapplefl apple apple apple - flfl appleapple apple apple-. Зfl appleapple apple apple- apple apple - apple. Иfl apple appleapple, apple applefl ( 1 ), fl D c, KN b appleapple applefl fl З- D 0 KN b apple ( 1 ), appleapple appleapple, fl apple appleapple applefl -, applefl fl. Зapple- apple, apple N b = 1 /, D 0 ч D c ч / apple- D c 176

2 Рappleapple apple 177 fl apple, apple applefl ( 1 ), appleapple 1, applefl fl ( 1 ) appleapple apple apple appleapple- 10 9, apple 10 6 appleapple [10]. В - applefl fl fl ( 1 ) apple apple fl 100% [11]. Чapple- apple ( 1 ) apple- fl (applefl apple apple apple, 3 /): ( 1 ) + ( 1 ) ( 1 д) + ( 3 д), , (4) ( 1 д) + З В ( 1 ) + З В, , (5) ( 1 ) + ( 1 ) ( 3 д) + ( 3 д), , (6) ( 1 ) +Cl ( 3 д) + Cl, , (7) ( 1 ) +H O ( 3 д) + H O, (8) А apple (4) applefl apple apple apple- fl apple 157 /. Рappleapple apple applefl- - apple, apple apple fl- flfl apple- apple ( 1 ). Д fl apple appleapple РЙД apple [], apple [4], - [1], [13] apple-. Йapple ( 1 ) applefl (4)(8) apple apple- apple. Ч apple applefl appleapple apple apple, apple fl apple apple apple apple apple ( 1 ). - fl apple РЙД apple applefl ( 1 ) apple. Дapple, apple fl, appleapple, apple- apple, apple appleapple H РЙД. А fl apple apple - РЙД apple apple applefl appleapple H, - applefl fl. Е - apple- РЙД fl apple-- apple apple apple apple [14]. apple apple appleapple РЙД, apple applefl ( 1 ), applefl. Кapplefl apple- РЙД apple apple. 1. Аapple apple apple РЙД 135, - 80 apple 50 apple 540 apple fl apple 0.. А apple appleapple applefl apple apple 1-5. Иfl apple. А apple applefl apple,. З applefl 135 apple fl apple- fl applefl apple appleapple apple apple. Вapplefl - apple appleapple apple apple. Рapple apple appleapple apple apple apple, appleapple appleapple. Р apple- apple apple 15 apple 50 apple. РЙД apple- apple fl - fl apple, apple - apple 4. В appleappleapple applefl apple fl V T = = apple apple apple apple fl, apple apple fl applefl apple apple, ( 1 ), apple, appleapple fl. А N c applefl apple 337, N apple- fl apple apple I, appleappleapple ( 1 ) 176, N = AI. Й apple (5), apple N w ( apple apple - РЙД) fl N, N д apple fl apple- fl Аapplefl fl РЙД - appleapple ( 1 ) apple, N - apple (4), (6)(8) apple apple appleapple-. А fl appleapple N д flflfl apple : N д N = N w Й, apple apple-, appleappleapple ( 1 д) 76 I д C I = N w fl apple- fl apple apple, fl РЙД. Дapple applefl - apple apple N c apple - fl fl fl = = 337. Еapple fl apple apple (.3 с 0.01) 10 19, 5

3 178 apple. У appleapple H Д Cl Кapple И. 1. Й apple- РЙД: 1, fl apple, 3 apple, 4 apple. applefl [15]. Д- apple ( 1 ) apple apple apple fl apple apple- apple ( 133 К) applefl apple, 1 : 10, ( 1 ) applefl (4)(8) applefl appleappleapple - apple appleapple apple apple appleapple appleapple. А apple apple ( 1 ) - applefl apple Y 0 apple appleapple H. А - appleapple appleflfl apple fl Y 0 75 [16] 94% [11]. Оapple fl apple ( 1 ) apple Y 0 =. fl - apple applefl apple apple - applefl apple apple appleapple appleapple. Кapple apple apple, apple appleapple appleapple N w apple, applefl - N apple C = w I д. А apple apple fl- I, fl apple apple- fl Y apple с10%, apple - applefl apple apple с0.1 с0.05 apple.. fl apple apple. appleapple apple applefl appleapple, apple- fl - fl ( 1 ) apple. И appleapple РЙД apple- apple applefl fl: CI w = kt, I д c = N c kt,

4 Рappleapple apple 179 Кapple N w > N < , - apple N д N, - apple ( 1 ) fl: N Y N kt = N ч w, c applefl applefl apple fl- fl 1 3 д N o ч w c /kt. Ж applefl applefl applefl РЙД: V з r = / c1 kt GRT 1 applefl appleappleapple з c1 ( V + V T ) T = RT 1 G Кapple з r з appleapple 1 apple- apple appleapple apple apple- apple apple apple. Й, fl ( 1 ) appleapple apple- apple appleapple apple, c, w Y. Й apple apple РЙД applefl apple flfl apple G c = (1 U)G, G o = UG c, G = YUG c, Q(N b N b1 ) = = UG, Q(N h N h1 ) = UG, G w = w (G o + G c ). У appleapple apple apple apple- 14 Ж appleapple ДВЗ 38%- apple apple - apple. Кapple fl РЙД apple - fl fl apple appleapple apple Q = = 1. /. М apple- 10 3, apple apple 13.5 apple 1 1.9, fl apple applefl- apple ~1. apple, appleflfl fl apple applefl apple ~ apple. В appleapple applefl, fl, apple- V = 380 3, V + V T appleapple- apple apple apple w w w =, c w U = , 1 ( w ) c1 = apple Кapple apple apple c 1 apple- 5.4 / apple apple applefl. fl appleapple- apple appleapple H applefl 1 РЙД flfl. З apple- apple appleapple fl. А appleapple РЙД - apple apple, apple, - flapple appleapple appleapple H, apple fl apple. Йapple fl applefl appleapple apple- apple. А appleapple fl, - apple apple, apple appleapple - fl 10. Ч apple apple- apple apple applefl РЙД з r ч apple apple.. А, - apple apple fl. fl apple apple apple apple fl apple applefl apple з r (apple. ). Кapple з r apple fl fl, fl - apple apple apple apple applefl [17]. Йfl - apple apple fl з r, apple apple - appleapple H apple fl H, apple apple apple appleflfl H apple [17]. Кapple apple apple apple apple apple fl РЙД apple fl ( 1 ) applefl (4)(8). В apple- ( 1 ) РЙД appleflfl apple- apple fl apple И 1 apple applefl з,.. И 1 з (apple. 3). Зfl applefl fl apple apple- Y = 5 (1 + И 1 з ) 1. З -, appleapple apple - apple Д appleapple И 1 з , appleapple apple- apple apple - appleapple И 1 (з з r ) apple ( 1 ) apple appleapple- apple applefl apple fl., apple РЙД, apple apple 5*

5 180 apple. U 1.0 () G, / () з r, () t, шc 1.0 () Q, / Y c1 з T И. 3. В apple ( 1 ) И c1 з r, apple Q = 1. /, N b = 6.5 /, N h = 7.5 /, t = = 16шC. И apple G, /: a 0, 40, 57, 75. ( 1 ) apple appleapple -. Й appleapple apple- apple H apple - fl (apple. ), apple - fl fl appleapple, apple - apple H appleapple, apple apple (). Кapple fl apple appleapple - appleapple H apple- apple apple %, ( 1 ) flfl. Н apple - appleapple H apple - apple (apple. ). А fl - applefl apple 4 6% applefl ( 1 ) Кapple - appleapple РЙД apple ДВЗ appleapple H apple () И.. Ч apple: apple apple apple applefl РЙД з r ч c, Q = 1. /, N b = 6.5 /, N h = 7.5 /, t = 16шC; apple applefl РЙД apple Q = 1. /, N b = 6.5 /, N h = 7.5 /, t = 16шC. И apple G, /: 40; 57, 75; appleapple appleapple apple apple- apple Q = 1. /, N b = 6.5 /, N h = 7.5 /, G = = 57 /, c1 = 3.3 apple.., з r ч 10 c; apple appleapple apple apple apple N b = 6.5 /, N h = 7.5 /, G = 57 /, t = N А, / = 16шC, c1 = 0 apple.., з r ч c; - apple ДВЗ apple- apple apple apple apple Q = 1. /, G = = 57 /, t = 10шC, c1 = 0 apple.., з r ч c.

6 Рappleapple apple 181 apple. А 38%- apple apple - fl 14 Ж ДВЗ fl fl apple. apple, appleapple H, apple - applefl fl applefl apple apple. Й apple appleapple apple - apple (apple. ), apple apple apple appleapple- fl apple apple-. А apple apple- N h fl ( 1 ) apple - apple apple. И apple 1 : 4 apple РЙД, apple apple applefl РЙД apple apple apple fl apple apple РЙД fl - apple ( 1 ). И- - appleapple РЙД. Иapple РЙД - ( 1 ) fl apple - apple- apple, apple [18]. Кapple apple apple 57 / - fl apple 150 А. Ч- apple, apple apple apple РЙД applefl [18]. В apple apple- РЙД, apple - appleapple H appleapple - apple. К 60 appleapple apple apple apple apple apple appleapple. Йapple- РЙД - ( 1 ) fl apple apple- fl, fl apple- apple. З fl apple apple- fl apple appleapple H apple-, РЙД applefl [18]. Лfl РЙД applefl- fl apple ~5 1, fl apple apple-- РЙД, apple apple apple fl (apple appleapple H, - apple, applefl applefl ) - apple apple РЙД applefl. А - fl apple apple appleapple applefl - apple appleapple H,, -, apple apple. П fl apple apple apple apple- РЙД flflfl apple apple apple. И apple apple Щapple apple - appleapple (apple ) - apple apple Жapple - apple (apple 30). Вfl О apple ; Й apple ; D c apple - appleapple apple apple, /; D o apple - appleapple apple apple, /; G flapple apple apple РЙД, /; G c flapple apple apple РЙД, /; G o flapple apple apple РЙД, /; G flapple apple apple РЙД, /; G w flapple apple apple РЙД, /; I apple apple, apple- appleapple apple fl 1 ; I д apple apple, apple- appleapple apple fl 1 д; Д apple apple, /( ); k flfl П; N w applefl apple apple-, 3 ; N c applefl apple apple, 3 ; N b, N b1 flapplefl applefl - appleapple apple apple РЙД, /; N h, N h1 flapplefl applefl apple - apple appleapple apple apple РЙД, /; N o applefl applefl apple - flfl 1 3 д, 3 ; N applefl apple fl 1, 3 ; N д applefl apple fl 1 д, 3 ; И 1 РЙД, apple.. И apple, apple..; И 1 apple РЙД, apple..; И apple apple, apple..;

7 18 apple. И w apple apple, apple..; Q apple apple- apple apple apple, /; R applefl fl flfl; 1 appleapple РЙД, Д; appleapple apple, Д; t appleapple appleapple apple apple, шй; U apple РЙД; V fl РЙД, apple- applefl, 3 ; V T appleappleapple apple- fl apple, 3 ; N Y = apple ( 1 ); N o Y 0 Y apple appleapple apple apple; w apple apple ; з r applefl applefl applefl, ; з T applefl appleappleapple apple apple,. ЙКЕЙВД Е ЩИО НИ 1. Khan A.U. Singlet molecular oxygen. A new kind of oxygen // The Journal of hysical Chemistry V McDermott W.E., chelkin N.R., Benard D.J., Bousek R.R. An electronic transition chemical laser// Appl.hys.Lett. 1978, V Browne R.J., Ogryzlo E.A. Chemiluminescence from the reaction of chlorine with aqueous hydrogen peroxide // roc.chem.soc Оfl А.З., Ж.А., З А.. apple. Йapple appleapple ( 1 ) apple 13.3 К // Дfl apple Й Balej J, Spalek O. Calculation of equilibrium composition in more concentrated systems H KOH (or NaOH)H O // Collection Czechoslov.Chem.Commun. 1979, V Richardson R.J., Kelley J.D., Wiswall C.E. ( 1 ) generation mechanisms in the chemically pumped iodine laser // J. Appl. hys V Storch D.M., Dymek C.J., Davis L.. MNDO study of the mechanism of ( 1 ) formation by reaction of Cl with basic H // J. Am. Chem. Soc V Оfl А.З., Ж.А., З А.., Н З.Е. Д apple Cl appleapple H OH KOH H OKOH // Ъapple Й Gershenzon M., Davidovits., Jayne J.T. et al. Rate constant for the reaction of Cl (aq) with OH // J. hys. Chem. A. 00. V Rogers M.A. Lifetime of ( 1 ) in liquid water as determined by time resolved infrared luminescence measurements // J.Am. Chem. Soc V П З.Р., Ж.А., Е А.Е. apple. apple apple- apple // apple МЕОЗ Й Blauer J.A., Munjee S.A., Truesdell K.A. et al. Aerosol generators for singlet oxygen production// J. Appl. hys V Harpole G.M., English W.D., Berd J.G., Miller D.J. Rotating disk oxygen generator // AIAA aper resented on 3 rd lasmadynamics and Lasers conference. July 68, 199. Nashville. USA. 14. Vetrovec J. Singlet oxygen generator with filamentguided jets // roceedings of SIE V В Л. Мfl. Ж.: Жapple, Yang T.T., Copeland D.A., Bauer A.H. et al. Chemical oxygen-iodine laser performance modeling // AIAA aper resented on 8 th lasmadynamics and laser conference. June apple К.А. Р apple. Ж.: Л- fl, Hager G.D., Nikolaev V.D., Svistun M.I., Zagidullin M.V. Lasing performance of a chemical oxygen iodine laser (COIL) with advanced ejector nozzle banks // Appl. hys. A V

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