Aluminum Chloride, Hexahydrate Crystal Reagent

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1 Safety Data Sheet Aluminum Chloride, Hexahydrate Crystal Reagent 1. PRODUCT AND COMPANY IDENTIFICATION Product Name: Aluminum Chloride, Hexahydrate Crystal Reagent Synonyms/Generic Names: None Product Number: 0227 Product Use: Industrial, Manufacturing or Laboratory use Manufacturer: Columbus Chemical Industries, Inc. N4335 Temkin Rd. Columbus, WI For More Information Call: (Monday-Friday 8:00-4:30) In Case of Emergency Call: CHEMTREC or (24 Hours/Day, 7 Days/Week) 2. HAZARDS IDENTIFICATION OSHA Hazards: Irritant Target Organs: None Signal Words: Warning Pictograms: GHS Classification: irritation Category 2 Eye irritation Category 2A Specific target organ toxicity single exposure Category 3 Acute aquatic toxicity Category 3 GHS Label Elements, including precautionary statements: Hazard Statements: H315 Causes skin irritation. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H402 Harmful to aquatic life. Precautionary Statements: P261 Avoid breathing dust/fume/gas/mist/vapors/spray. P264 Wash hands thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. Revised on 07/14/2016 Page 1 of 6

2 P273 P280 P302+P352 P304+P340 P305+P351+P338 P312 P332+P313 P337+P313 P362+P364 P403+P233 P405 P501 Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of water. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER/doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Dispose of contents/container in accordance with local regulations. Potential Health Effects Causes eye irritation. Inhalation May be harmful if inhaled. Causes respiratory tract irritation. May be harmful if absorbed through skin. Causes skin irritation. Ingestion May be harmful if swallowed. NFPA Ratings Health 2 Flammability 0 Reactivity 0 Specific hazard HMIS Ratings Health 1 Fire 0 Reactivity 0 Personal 3. COMPOSITION/INFORMATION ON INGREDIENTS Component Weight % CAS # Aluminum Chloride, Hexahydrate EINECS# / ELINCS# Formula Molecular Weight > AlCl 3* 6H 2 O g/mol 4. FIRST-AID MEASURES Inhalation Ingestion Rinse with plenty of water for at least 15 minutes and seek medical attention. Move casualty to fresh air and keep at rest. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Get medical attention. Flush with plenty of water for at least 15 minutes while removing contaminated clothing and wash using soap. Get medical attention if necessary. Do Not Induce Vomiting! Never give anything by mouth to an unconscious person. If conscious, wash out mouth with water. Get medical attention if necessary. 5. FIRE-FIGHTING MEASURES Suitable (and unsuitable) extinguishing media Special protective equipment and precautions for firefighters Specific hazards arising from the chemical Product is not flammable. Use appropriate media for adjacent fire. Cool unopened containers with water. Wear self-contained, approved breathing apparatus and full protective clothing, including eye protection and boots. Emits toxic fumes (hydrogen chloride, aluminum oxide) under fire conditions. (See also Stability and Reactivity section). Revised on 07/14/2016 Page 2 of 6

3 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Environmental precautions Methods and materials for containment and cleaning up See section 8 for recommendations on the use of personal protective equipment. Prevent spillage from entering drains. Any release to the environment may be subject to federal/national or local reporting requirements. Pick up and arrange disposal without creating dust. Sweep up and place in suitable containers for disposal. Clean surfaces thoroughly with water to remove residual contamination. Dispose of all waste and cleanup materials in accordance with regulations. 7. HANDLING AND STORAGE Precautions for safe handling See section 8 for recommendations on the use of personal protective equipment. Use with adequate ventilation. Wash thoroughly after using. Keep container closed when not in use. Avoid formation of dusts. Conditions for safe storage, including any incompatibilities Store in a cool, dry, well ventilated area. Moisture sensitive. Keep away from incompatible materials (see section 10 for incompatibilities). 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure controls: Contains no substances with occupational exposure limit values. Personal Protection Wear chemical safety glasses or goggles. Inhalation Provide local exhaust, preferably mechanical. If exposure levels are excessive, use an approved respirator. Wear nitrile or rubber gloves, apron or lab coat. Other Other Recommendations Provide eyewash stations, quick-drench showers and washing facilities accessible to areas of use and handling. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance (physical state, color, etc.) Odor Odor threshold ph Melting point/freezing point Initial boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limit Vapor pressure Vapor density Relative density White crystalline solid. 20 C (68 F) 100 C (212 F) 182 C (360 F) Not Flammable Not Flammable Not Explosive 1 hpa (1 100 C (212 F) Revised on 07/14/2016 Page 3 of 6

4 Solubility (ies) Partition coefficient: n-octanol/water Auto-ignition temperature Decomposition temperature Completely soluble in water. 10. STABILITY AND REACTIVITY Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Incompatible Materials Hazardous Decomposition Products Stable Will not occur. Moisture. Alkalis, nitrobenzene, strong acids. Aluminum oxides, hydrogen chloride gas. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Respiratory Ingestion Carcinogenicity IARC ACGIH NTP OSHA LD50 Oral Rat 3,311 mg/kg as probable, possible or confirmed human carcinogen by IARC. as a carcinogen or potential carcinogen by ACGIH. as a known or anticipated carcinogen by NTP. as a carcinogen or potential carcinogen by OSHA. Signs & Symptoms of Exposure Burning, itching, redness. Burning, itching, redness. Respiratory Coughing, sneezing. Ingestion Nausea, vomiting, diarrhea. Chronic Toxicity Teratogenicity Mutagenicity Embryotoxicity Specific Target Organ Toxicity Reproductive Toxicity Respiratory/ Sensitization Development Toxicity Mouse Intravenous Specific Developmental Abnormalities: Musculoskeletal system Genotoxicity in vitro Mammal lymphocyte DNA damage Inhalation May cause respiratory irritation. 12. ECOLOGICAL INFORMATION Ecotoxicity Aquatic Vertebrate Aquatic Invertebrate Terrestrial LC50 other fish 27.1 mg/l 96 hours EC50 Daphnia magna (Water flea) 27.3 mg/l 48 hours Revised on 07/14/2016 Page 4 of 6

5 Persistence and Degradability Bioaccumulative Potential Mobility in Soil PBT and vpvb Assessment Other Adverse Effects Harmful to aquatic life. May be harmful to aquatic organisms due to the shift of the ph. Avoid release to the environment. 13. DISPOSAL CONSIDERATIONS Waste Residues Product Containers Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product or residue. Users should review their operations in terms of the applicable federal/national or local regulations and consult with appropriate regulatory agencies if necessary before disposing of waste product container. The information offered in section 13 is for the product as shipped. Use and/or alterations to the product may significantly change the characteristics of the material and alter the waste classification and proper disposal methods. 14. TRANSPORTATION INFORMATION US DOT TDG IMDG Marine Pollutant IATA/ICAO No 15. REGULATORY INFORMATION TSCA Inventory Status DSCL (EEC) California Proposition 65 SARA 302 SARA 304 SARA 311 SARA 312 SARA 313 WHMIS Canada All ingredients are listed on the TSCA inventory. All ingredients are listed on the DSCL inventory. Not Listed No SARA Hazard No SARA Hazard Acute Health Hazard Acute Health Hazard No SARA Hazard Class E: Corrosive material. Revised on 07/14/2016 Page 5 of 6

6 16. OTHER INFORMATION Revision Date Revision 1 01/07/2013 Revision 2 07/14/2016 Disclaimer: Columbus Chemical Industries, Inc. ( Columbus ) believes that the information herein is factual but is not intended to be all inclusive. The information relates only to the specific material designated and does not relate to its use in combination with other materials or its use as to any particular process. Because safety standards and regulations are subject to change and because Columbus has no continuing control over the material, those handling, storing or using the material should satisfy themselves that they have current information regarding the particular way the material is handled, stored or used and that the same is done in accordance with federal, state and local law. COLUMBUS MAKES NO WARRANTY, EXPRESS OR IMPLIED, INCLUDING (WITHOUT LIMITATION) WARRANTIES WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN OR WITH RESPECT TO FITNESS FOR ANY PARTICULAR USE. Revised on 07/14/2016 Page 6 of 6

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