HAZARD CLASSIFICATIONS, APPROVALS AND CONTROLS HSNO APPROVALS HOW SUBSTANCES ARE CLASSIFIED CONTROLS (RULES) FOR MANAGING HAZARDOUS SUBSTANCES

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1 HAZARD CLASSIFICATIONS, APPROVALS AND CONTROLS HSNO APPROVALS HOW SUBSTANCES ARE CLASSIFIED CONTROLS (RULES) FOR MANAGING HAZARDOUS SUBSTANCES 7

2 8 HAZARD CLASSIFICATIONS, APPROVALS AND CONTROLS HAZARD CLASSIFICATIONS, APPROVALS AND CONTROLS HSNO APPROVALS Most products used by small industrial businesses will be approved under a group standard approval. A group standard is an approval for a group of similar substances or products that have a similar use. The manufacturer or importer can assign a product to a group standard by making sure that the product has only the classifications that are allowable within the scope of the group standard. If the product meets the scope of the standard, the product is considered to be approved. A HSNO approval sets out the rules (also called controls) for managing the risks of a hazardous substance. THE HSNO APPROVAL NUMBER IS ON THE SAFETY DATA SHEET HSNO approval numbers are usually found in Section 15: Regulatory Information of your safety data sheet and look like the following example: HSR If you can t find the approval number on your safety data sheet, contact your supplier. HOW SUBSTANCES ARE CLASSIFIED Hazardous substances can be classified under one of several similar systems. In New Zealand, the HSNO system is used. Substances manufactured overseas may use another system. The HSNO system is based on the United Nations (UN) dangerous goods classification system for transport and the Globally Harmonised System of Classification and Labelling of Chemicals (GHS). HAZARD CLASSIFICATION The classification for your product should be listed in the Hazards Identification section of the safety data sheet, usually found in Section 2. Section 15 of the safety data sheet may also have information specific to HSNO.

3 HAZARD CLASSIFICATIONS, APPROVALS AND CONTROLS 9 HSNO CLASSIFICATION SYSTEM 6. 3 A CLASS SUBCLASS DEGREE OF HAZARD The HSNO system uses numbered classes and subclasses to indicate the hazardous properties of a substance. For example, for a substance classified as 6.3A: 6 is the class, which indicates the substance is toxic to people 3 is the subclass, which indicates the type of toxicity, for example, irritating to the skin, and the letter A indicates the degree of hazard, with A being the highest hazard. Therefore a hazardous substance classified as 6.3A is highly irritating to the skin. The HSNO classes are: Class 1 explosives (note that this booklet does not provide information about explosives) Class 2 flammable gases Class 3 flammable liquids Class 4 flammable solids Class 5 oxidising substances Class 6 substances toxic to people Class 8 corrosive substances Class 9 substances that are toxic to the environment. Dangerous goods class 6.2 (infectious substances) and class 7, radioactive materials, are not regulated under HSNO but must be managed under the HSE Act when used and stored in the workplace. Most hazardous substances have more than one classification Most hazardous substances will have more than one hazardous property and therefore more than one classification. For example, petrol is classified as a 3.1A (highly flammable liquid), 6.1E (acutely toxic may be harmful, aspiration hazard), 6.3B (mildly irritating to the skin), 6.7B (suspected human carcinogen) and 9.1B (toxic to the aquatic environment).

4 10 HAZARD CLASSIFICATIONS, APPROVALS AND CONTROLS UNITED NATIONS TRANSPORT CLASSES AND PACKING GROUPS If you don t have the HSNO classifications for products approved under group standards you can use the United Nations (UN) classification and packing groups in the HSNO Calculator. Most safety data sheets will include the UN classes and packing groups because these are used internationally when transporting dangerous goods. The UN classes and packing groups are found in the Transport Information section of your safety data sheet. In a 16 header safety data sheet, this is section 14. The packing group determines the standard of packaging to be used depending on how dangerous a hazardous substance is. There are three packing groups, I II and III (high, medium or low danger). Packing group I is used for the most dangerous substances. An example of what to look for in section 14 is shown below (toluene is used as an example): UN NUMBER 1294 PROPER SHIPPING NAME CLASS 3 PACKING GROUP TOLUENE II If you don t have the HSNO classification for your products approved under group standards you need to include the UN class and the packing group in the HSNO Calculator. CONTROLS (RULES) FOR MANAGING HAZARDOUS SUBSTANCES Controls are rules put in place to prevent or manage the adverse effects of hazardous substances. The controls for substances differ depending on their hazard classification and their particular approval. CONTROLS THAT ARE ALWAYS NEEDED A list of all of the hazardous substances you use and store To safely manage your hazardous substances you need to know what you ve got. Make a list of all of the hazardous substances used and stored at your workplace. See your Workbook. An assessment of the hazards followed by elimination, isolation, minimisation of hazards Hazardous substances can be harmful to people s health. Learn about the hazards of each hazardous substance, and assess who will be exposed and in what way. You then need to either get rid of the hazardous substance or isolate the use of the substance away from people. If you can t eliminate or isolate the substance you

5 HAZARD CLASSIFICATIONS, APPROVALS AND CONTROLS 11 need to minimise your staff s exposure to it using controls, such as ventilation, safer work practices, and personal protective equipment. See Keep safe with hazardous substances, page 13. Staff training to use and store substances safely Staff need to be trained to use and store hazardous substances safely. See Keep safe with hazardous substances, page 13 and Store hazardous substances safely, page 35. Preparing for an emergency Make sure that your staff and workplace are prepared for an emergency. See Emergency preparation, page 43. ADDITIONAL CONTROLS THAT MAY BE NEEDED If you have particular types or amounts of hazardous substances, you may have to comply with aitional controls. The HSNO Calculator will help you work out what key HSNO controls apply to you. Fire extinguishers Signs If you have flammable or oxidising substances, you may need a specific type and number of fire extinguishers. However, even if it s not legally required, it s best practice to always have fire extinguishers at your workplace. Fire extinguishers are used to put out fires before they reach the hazardous substances used and stored at your workplace. See Emergency preparation, page 43. Depending on the types and amounts of hazardous substances you use or store, you may need signs to warn people that hazardous substances are present. Although signs are only required when you have certain amounts of hazardous substances, it s best practice to always have them. See Hazardous substance information, page 23. Approved handlers If you have very toxic substances or amounts of flammable or oxidising substances over certain limits, one or more of your staff may need to be trained and certified as an approved handler. This is someone who has specific knowledge and experience about how to handle particular hazardous substances and has received a test certificate from a test certifier. See Test certificates, page 51. A location test certificate If you have flammable or oxidising substances at your workplace, you may need a location test certificate. This certifies that you are managing your flammable or oxidising substances in accordance with the rules. Test certificates are issued by test certifiers. See Test certificates, page 51.

6 12 HAZARD CLASSIFICATIONS, APPROVALS AND CONTROLS Hazardous atmosphere zones A hazardous atmosphere zone surrounds a place where flammable substances are used or stored and flammable vapours may be present. Within these zones, special precautions must be taken to prevent unintended ignition so that a fire or explosion does not occur. See Store hazardous substances safely, page 35. Emergency response plan An emergency response plan is a written document that covers what will be done and who is responsible for doing each task if an emergency were to occur involving your hazardous substances. See Emergency preparation, page 43. Secondary containment (bunding) A secondary containment system ensures that liquid substances can be contained if they leak or spill from the container or vessel they are stored in. See Emergency preparation, page 43. CONTROLS THAT MAY BE NEEDED NOT COVERED BY THE CALCULATOR The controls below are not covered by the HSNO Calculator but guidance about what to do is provided in this booklet. An approved filler test certificate Everyone at your business who fills compressed gas containers must have an approved filler test certificate. An approved filler is someone who has the necessary training, knowledge and skills to fill compressed gas containers safely, and has obtained an approved filler test certificate from a test certifier. See Test certificates, page 51. A stationary container system test certificate A stationary container system is a fixed tank or process container and its associated equipment, pipe work and fittings. If you have a stationary tank containing a gas or liquid hazardous substance you may need a stationary container system test certificate. This certifies that your tank is safe and complies with the rules. See Test certificates, page 51. Controlled zones A controlled zone is an area around a flammable or oxidising substance. Within that area, ignition sources must be controlled and access must be limited to authorised personnel to protect the general public. See Store hazardous substances safely, page 35. Tracking Tracking is a record of what happens to a substance and who is responsible for it. The employer must keep records and track very hazardous substances from import or manufacture, to distribution and transport, through to use or disposal. See Tracking very hazardous substances, page 57.

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