MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET SECTION 1 COMPANY AND PRODUCT IDENTIFICATION Golden Artist Colors, Inc. Date Revised: 3/19/ Bell Road Phone: (607) New Berlin, NY Prepared by: Ben Gavett WILLIAMSBURG OIL COLORS HAZARDOUS COMPONENTS (See Sec. 3) Item # Description Alizarin Crimson Alizarin Orange Alizarin Yellow Bohemian Green Earth 19,24,33, Brilliant Yellow Extra Pale Brilliant Yellow Pale 33, Brown Ochre 3,20,24, Brown Pink Brown Umber 13,20, Burnt Sienna 7,20, Burnt Umber 20, Cadmium Green 12, Cadmium Green Light 12, Cadmium Lemon Cadmium Orange Cadmium Purple Cadmium Red Deep Cadmium Red Light Cadmium Red Medium Cadmium Red Purple Cadmium Red Vermilion Cadmium Yellow Deep Cadmium Yellow Extra Deep Cadmium Yellow Light Cadmium Yellow Medium Cadmium Purple Canton Rose 24,33,34 1

2 Carl's Crimson (Permanent) Cerulean Blue (Genuine) 3,14,18, Cerulean Blue French 14, Chromium Oxide Cinnabar Green Light Cobalt Blue Cobalt Blue Deep Cobalt Green Cobalt Teal Cobalt Teal Deep Cobalt Turquoise Bluish Cobalt Turquoise Greenish 14, Cobalt Violet Deep Cobalt Violet Light Cobalt Yellow Cold Black 3, Courbet Green 20, Cyprus Orange 20, Davy's Grey Deep Dianthus Pink Dutch Brown (Transparent) Earth Green 20, Eqyptian Violet Fanchon Red Flake White SEE WILLIAMSBURG LEAD MSDS German Earth 20, Graphite Grey 20, Green Gold Indanthrone Blue Indian Yellow Indigo 20, Italian Pink Ivory Black Jaune Brilliant 24,33, King's Blue 3,33, Lamp Black Manganese Violet Mars Black Mars Orange Mars Orange Deep Mars Red 7, Mars Red Light Mars Violet Mars Yellow Deep 11, Mars Yellow Light 24 2

3 Montserrat Orange 33, Naples Yellow 24,33, Naples Yellow Italian Naples Yellow Reddish 24,33, Neutral Gray N2 7,13,24, Neutral Gray N4 7,11,13,24, Neutral Gray N6 7,11,13,24, Neutral Gray N8 7,11,13, Nickel Yellow Olive Green 19, Payne's Grey 3, Payne's Grey (Violet) 3, Permanent Crimson Permanent Green Permanent Green Light Permanent Lemon Permanent Orange Permanent Red-Orange Permanent Yellow Deep Permanent Yellow Light 7, Permanent Yellow Medium Persian Rose 33, Perylene Crimson Phthalo Blue Phthalo Green Phthalo Green-Yellowish Phthalo Turquoise Provence Violet Bluish 33, Provence Violet Reddish 33, Prussian Blue Quinacridone Gold Brown Quinacridone Magenta Quinacridone Red Quinacridone Violet Raw Sienna 20, Raw Umber 13,20, Red Ochre 3,20,24, Red Umber 20, Sap Green Sevres Blue 33, Silver White SEE WILLIAMSBURG LEAD MSDS Slate Black Spanish Earth 3,20,24, Stil De Grain Titanium - Zinc White 3,33,34 3

4 Titanium White 3, Turkey Umber 19, Turquoise 19,33, Ultramarine Blue Ultramarine Blue French Ultramarine Pink Ultramarine Violet Unbleached Titanium 24, Unbleached Titanium Pale Van Dyke Brown Veronese Green 19, Viridian Yellow Ochre (Domestic) 20,24,27, Yellow Ochre Burnt 20, Zinc Buff 33, Zinc Buff Yellowish Zinc Buff Yellow 7,11,28, Zinc White 34 French Earth Colors French Ardoise Gray 11,24, French Brown Ochre 3,20, French Burnt Umber 3,20, French Cassel Earth 3,20, French Noir Indien 3,20, French Rouge Indien French Burnt Ochre 3,20, French Ochre Havane 3,20, French Raw Sienna 3,20, French Raw Umber 3,20, French Light Sienna 3,20, French Terre Verte 3,20,24, French Yellow Ochre Deep 3,20,24 Native Italian Earth Colors Italian Black Roman Earth 13,20, Italian Burnt Sienna 20, Italian Green Ochre 20, Italian Lemon Ochre 20, Italian Orange Ochre 20, Italian Pompeii Red 20, Italian Pozzuoli Earth 20, Italian Raw Sienna 20, Italian Raw Umber 20,24 4

5 Italian Rosso Veneto 20, Italian Terra Rosa 20, Italian Terra Verte 20, Italian Yellow Ochre 20,24 Iridescent and Interference Interference Blue 27, Interference Green 27, Interference Red 27, Interference Violet 27, Iridescent Bronze 24, 27, Iridescent Copper 24, 27, Iridescent Pale Gold 24, 27, Iridescent Pearl White 27, Iridescent Pewter 24, 27, Iridescent Silver 24, 27,33 SECTION 2 - HAZARD IDENTIFICATION INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: None known. EYE CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE: irritating. Contact may be mildly SKIN CONTACT HEALTH RISKS AND SYMPTOMS OF EXPOSURE: None generally expected. Contact with some pigments may cause allergic reaction in sensitized individuals. See pigment-specific information below. INGESTION HEALTH RISKS AND SYMPTOMS OF EXPOSURE: May cause irritation to gastrointestinal system. Chronic ingestion of some pigments may be harmful. See pigment-specific information below. MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: Pre-existing skin, eye, or respiratory conditions may be aggravated by exposure. ADDITIONAL HAZARDS ASS0CIATED WITH SPECIFIED PIGMENTS OR THEIR COMPONENTS IDENTIFIED IN SECTION 3: CADMIUM PIGMENT- Cadmium Compounds are classified by IARC as probably carcinogenic in humans. OSHA also classifies such compounds as causing lung and kidney disease. WARNING: This product contains a chemical known to the State of California to cause cancer by means of inhalation. CARBON BLACK- IARC classification as Group 2B, possibly carcinogenic to humans CRYSTALLINE SILICA- Considered a carcinogen through particulate inhalation 5

6 COBALT COMPOUNDS- Individuals hypersensitive to Cobalt may develop asthma, bronchitis, or shortness of breath. May cause skin sensitization. IARC classification as Group 2B, possibly carcinogenic to humans. WARNING: This product contains a chemical known to the State of California to cause cancer. CHROMIUM III Compounds- Some chromium compounds are considered carcinogenic, evidence of Chromium (III) compound carcinogenicity is inconclusive. MANGANESE- Overexposure may affect the Central Nervous System and lungs, resulting in transitory psychosis, tiredness, weakness and pneumonitis. May aggravate preexisting neuralgic conditions. NICKEL, METAL AND COMPOUNDS- IARC and NTP also state there is sufficient evidence of carcinogenicity in experimental animals and humans. Ingestion may result in damage to the testes. WARNING: This product contains a chemical known to the State of California to cause cancer. TITANIUM DIOXIDE- Listed by IARC under category 2B, possibly carcinogenic to humans. VIRIDIAN- WARNING: This products contains ppm hexavalent chromium, a chemical known to the State of California to cause cancer. ZINC WHITE- Overexposure may result in fever, chills, muscular pain or nausea. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. SECTION 3 - HAZARDOUS COMPONENT INFORMATION OSHA PERMISSIBLE EXPOSURE LIMITS CODE CAS NUMBER TWA STEL CEILING 3 Aluminum Compounds NE 6 Antimony and Compounds various.5 mg/m 3 7 Barium Sulfate mg/m 3 11 Calcium Carbonate mg/m 3 12 Cadmium Pigment various 5 g/m 3 (as Cadmium) 13 Carbon Black mg/m 3 14 Chromium (III) Compounds various.5 mg/m 3 18 Cobalt Compounds various.5 mg/m 3 19 Copper Compounds various 1 mg/m 3 20 Crystalline Silica mg/m 3 23 Graphite(natural) mg/m 3 24 Iron Oxide mg/m Magnesium Silicate mg/m 3 25 Manganese compounds NE 5 mg/m 3 27 Mica mg/m 3 28 Nickel compounds various.1 mg/m Tin compounds various NE 33 Titanium Dioxide mg/m 3 34 Zinc Oxide mg/m 3 6

7 TWA= Time Weighted Average (ave. airborne exposure in 8 hr work shift work week) STEL= Short Term Exposure Limit (15 minute time weighted average exposure) CEILING = exposure not to be exceeded during any part of the work day NE = None established mg/m 3 = approximate milligrams of substance per cubic meter of air SECTION 4 - FIRST AID MEASURES EYE CONTACT: Flush with water for 15 minutes. SEE DOCTOR if any symptoms persist. SKIN CONTACT: Wash with soap and water. SEE DOCTOR if skin irritation occurs. INHALATION: Remove subject to fresh air. SEE DOCTOR if symptoms persist INGESTION: If swallowed, dilute by giving 2 or more glasses of water to drink ONLY IF CONSCIOUS! SEE DOCTOR. SECTION 5 - FIRE FIGHTING MEASURES FLASH POINT: None METHOD USED: N/A FLAMMABLE LIMITS IN AIR BY VOLUME: LOWER: N/A UPPER: N/A EXTINGUISHING MEDIA: Carbon dioxide, water spray, foam or dry chemical. SPECIAL FIRE FIGHTING PROCEDURES: Use self-contained breathing apparatus and full protective clothing. UNUSUAL FIRE AND EXPLOSION HAZARDS: Decomposition and combustion products may be toxic. SECTION 6 ACCIDENTAL RELEASE MEASURES Contain spill. Recover material for use or proper disposal. Clean reside with detergent and wet mopping. SECTION 7 - HANDLING AND STORAGE Ensure good industrial hygiene when storing and using pigments by keeping containers closed and avoiding contamination of work space through excessive dust generation. Clean work space thoroughly after use. SECTION 8 - EXPOSURE CONTROL/PERSONAL PROTECTION RESPIRATORY PROTECTION: None applicable VENTILATION: General dilution ventilation as desired PROTECTIVE GLOVES: Latex gloves are recommended. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None required under normal use. WORK/HYGIENIC PRACTICES: Use in accordance with safe handling practices, including: do not eat, drink or smoke when working with materials, avoid excessive skin contact, wash after working with materials. 7

8 SECTION 9 - PHYSICAL/CHEMICAL PROPERTIES BOILING POINT: NA SPECIFIC GRAVITY (H 2 0=1): >1 VAPOR DENSITY: NA ph: NA SOLUBILITY IN WATER: negligible VOC: 0 g/l APPEARANCE AND ODOR: Viscous pastes of assorted colors SECTION 10 - STABILITY AND REACTIVITY STABILITY: Stable INCOMPATIBILITY: May react with strong oxidizers HAZARDOUS DECOMPOSITION OR BYPRODUCTS: None known Oral LD50 - rat: >5000 mg/kg Dermal LD50 - rabbit: >5000 mg/kg Eye Irritation rabbit: minimal Skin Irritation rabbit: slight SECTION 11 TOXICOLOGICAL INFORMATION SECTION 12 ECOLOGICAL INFORMATION Not readily biodegradable. No other data available. SECTION 13 DISPOSAL CONSIDERATIONS Allow to dry and dispose of as solid waste. US TCLP (metals solubility) data available upon request. SECTION 14 -TRANSPORT INFORMATION Not hazardous for shipping via any mode SECTION 15 REGULATORY INFORMATION Consumer Product Labeling: Products are labeled in compliance with 67/548/EEC (EU), FHSA/LHAMA (USA), CCCR (Canada). 4/30/2012 Added 18 new colors 2/8/2013 Added Neutral Grays 3/19/2013 Added Zinc Buff Yellow SECTION 16 OTHER INFORMATION 8