Cadmium Yellow No. 6, medium

Transcription

1 Revised edition: Version: 1 Identification of the Substance/Mixture and of the Company/Undertaking Product Identifier Page 1 Product Name: Cadmium Yellow No. 6, medium Article No.: Relevant identified Uses of the Substance or Mixture and Uses advised against Identified uses: To dye plastics, varnishes and cement. Production of ceramic coating suited for firing and decor preparation for glass and ceramic Uses advised against: Details of the Supplier of the Safety Data Sheet (Producer/Importer) Company: Address: Kremer Pigmente GmbH & Co. KG Hauptstr , Aichstetten, Germany Tel./Fax.: Tel , Fax Internet: info@kremer-pigmente.de Importer: -- Emergency No. Emergency No.: (Mon-Fri 8:00-17:00) Hazards Identification Classification of the Substance or Mixture Classification according to EC Regulation 1272/2008 Classification according to EC Regulation No. 67/548 or No. 1999/45 This product does not require classification and labelling as hazardous according to CLP/GHS. The material is not subject to classification according to EC lists. Safety Phrases: Possible Environmental Effects: Label Elements Classification according to EC Regulation 1272/2008 This product does not require classification and labelling as hazardous according to CLP/GHS. Hazard designation: Signal word: Hazard designation: Safety designation: Hazardous components for labelling: 2

2 2. 3. Other Hazards 3. Composition/Information on Ingredients Substance Mixture Page 2 Chemical Characterization: Inorganic salt. Pigment Yellow 35, C.I CAS No , EINECS Cadmium zinc sulphide yellow Hazardous Ingredients: Does not contain any hazardous components according to EC Guidelines 1272/2008 and 67/548/EEC Additional information: First Aid Measures Description of the First Aid Measures General information: After inhalation: After skin contact: After eye contact: Do not leave affected persons unattended. In case of unconsciousness place patient stable in side position for transportation. Get medical help. Consult physician if symptoms persist. Wash with soap and rinse with plenty of water. Remove contaminated clothing. Rinse open eye for several minutes under running water. Should irritation continue, seek medical advice. Remove contact lens. Protect unharmed eye After ingestion: Most important Symptoms and Effects, both Acute and Delayed Rinse mouth thoroughly with plenty of water and drink plenty of water. Consult a physician. Never give anything by mouth to an unconscious person. Do not give milk or alcohol to drink. Symptoms: No further information available Effects: No further information available. Indication of any Immediate Medical Attention and special Treatment needed Treatment: First-aid measures must be specified together with the responsible physician for industrial medicine. 3

3 5. Fire-Fighting Measures Extinguishing Media Page 3 Suitable extinguishing media: Use extinguishing media for surrounding fire Unsuitable extinguishing media: Special Hazards arising from the Substance or Mixture None known Special hazards: Advice for Firefighters Protective equipment: Do not let extinguishing water enter the sewerage system or water courses. Wear self-contained respiratory protective device Further information: Accidential Release Measures Personal Precautions, Protective Equipment and Emergency Procedures Collect contaminated extinguishing water and debris separately; avoid contamination of sewage system. Contaminated extinguishing water and debris should be disposed of according to local regulations Personal precautions: Environmental Precautions Wear appropriate protective equipment. Keep spectators away. Avoid formation of dust. Ensure adequate ventilation Environmental precautions: Methods and Material for Containment and Cleaning Up Prevent contamination of soils, drains and surface water. Contact local authorities if product pollutes soil or vegetation Methods and material: Reference to other Sections Handling and Storage Precautions for Safe Handling Instructions on safe handling: Take up mechanically and collect in suitable containers for disposal. Avoid formation of dust and static discharges. Wear protective gear and self-contained breathing apparatus. Protective clothing, see Section 8. Avoid formation of dust. Do not inhale dust. Wear adequate protective clothing (see para. 8). Hygienic measures: Do not eat or drink during work. Do not smoke. 4

4 7. 2. Conditions for Safe Storage, including any Incompatibilities Page Storage conditions: Requirements for storage areas and containers: Information on fire and explosion protection: Storage class (VCI): Further Information: Specific End Use(s) Store in tightly sealed containers in a dry and well ventilated location. Do not store together with strong acids and oxidants. Electrical installation/working materials must comply with the technological safety standards. Avoid dust formation. Provide adequate exhaust ventilation at places where dust is formed. 13; Non combustible solids Store in a dry place. No decomposition if used and stored according to specifications Further information: Exposure Controls/Personal Protection Parameters to be Controlled The technical guidelines for the application of this product/mixture should be followed. Does not contain substances with occupational exposure limits. Parameters to be controlled (DE): Parameters to be controlled (EC): Derived No-Effect Level (DNEL): Predicted No-Effect Concentration (PNEC): Additional Information: Exposure Controls Technical protective measures: Technical protective measures have priority to personal protective measures. Personal Protection General protective measures: Wear adequate protective clothing. Wash hands and face at the end of work. Carry out work under a fume hood. Do inhale product. Respiratory protection: None required under normal operating conditions. 5

5 Hand protection: In case of prolonged contact: Recommended Page 5 Protective glove material: Eye protection: Body protection: Safety glasses (EN 166) Protective clothing Environmental precautions: Physical and Chemical Properties Information on Basic Physical and Chemical Properties Avoid contamination of sewage system, open water ways and ground water. Form: Color: Odor: Odor threshold: ph-value: Melting temperature: Boiling temperature: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Vapor density: Density: Solubility in water: powder yellow odorless 7 (5% suspension) not available not available no information available no information available not determined g/cm3 No data available Coefficient of variation (n- 6

6 Octanol/Water): Page 6 Auto-ignition temperature: Decomposition temperature: > 300 C Viscosity, dynamic: Explosive properties: Oxidizing properties: Bulk density: Further Information Solubility in solvents: Viscosity, kinematic Burning class: Solvent content: Solid content: Particle size: Other information: Stability and Reactivity Reactivity Chemical Stability Possibility of Hazardous Reactions Conditions to Avoid Conditions to avoid: not available no information available not determined Stable if used according to specifications. No decomposition if used according to specifications. Reacts with acids: development of hydrogen sulfide. Reacts with strong oxidants. Thermal decomposition: Imcompatible Materials Strong acids and strong oxidizing agents Hazardous Decomposition Products None if handled according to specifications. 7

7 10.7. Further Information 11. Toxicological Information Information on Toxicological Effects Page 7 Acute Toxicity LD50, oral: LD50, dermal: LC50, inhalation: > 5000 mg/kg Primary effects Irritant effect on skin: Irritant effect on eyes: Non irritating Non-irritating to eyes Inhalation: Ingestion: Sensitization: Mutagenicity: Reproductive toxicity: Cancerogenity: Teratogenicity: Specific target organ toxicity (STOT): Additional toxicological information: Ecological Information Aquatic Toxicity Fish toxicity: Daphnia toxicity: Bacteria toxicity: No negative effects. No negative effects. No negative effects. Algae toxicity: 8

8 Persistency and Degradability Bioaccumulation Mobility Results of PBT- und vpvp Assessment Other Adverse Effects Water hazard class: Behaviour in sewage systems: No negative effects. Page 8 Inorganic substance. Biological degradability is not affected. No bioaccumulation expected. This product is neither a PBT or vpvb substance nor does it contain a PBT or vpvb substance. Further ecological effects: No ecological data available AOX Value: Disposal Considerations Waste Treatment Methods Product: Dispose of according to official national and local regulations. European Waste Code (EWC): Uncleaned packaging: Empty containers can be landfilled after cleaning, when in compliance with the Environmental Protection (Duty of Care) Regulations Waste Code No.: Transport Information UN Number ADR, IMDG, IATA UN Proper Shipping Name ADR/RID: IMDG/IATA: Transport Hazard Classes ADR Class: Hazard no.: Classification code: No hazardous goods according to ADR (land transportation). No hazardous goods according to IMDG. Tunnel no.: 9

9 IMDG Class (sea): Page 9 Hazard no.: EmS No.: IATA Class: Hazard no.: Packaging Group ADR/RID: IMDG: IATA: Environmental Hazards None Special Precautions for User Not classified as a dangerous good under transport regulations. Transportation in Bulk according to Annex II of MARPOL 73/78 and IBC-Code Further Information Regulatory Information Safety, Health and Environmental Regulations/Legislation specific for the Substance or Mixture Water hazard class: Local regulations on chemical accidents: 1, slightly hazardous for water EC-Regulation 96/82 does not apply (2003). Employment restrictions: Restriction and prohibition of application: EC. REACH, Section XVII, Restrictions on the Manufacture, Placing on the Market and Use of Certain Dangerous Substances, Preparations and Articles, Registered no. 23 The use of cadmium in pigments in certain polymers, as well as in aqueous- and non-aqueous based paints is restricted Technical instructions on air quality: Chemical Safety Assessment Further Information Other Information EC SVHC-List: This product does not contain a substance in the candidate list for substances of very high concern (REACH Regulation (EC) 1907/2006, Article 57) This product is not a ozone-depleting substance (EC Reg. 2037/2000) and not a persistent organic pollutant (POP) (EC Reg. 850/2004). This product should be stored, handled and used in accordance with good hygiene practices and in conformity with any legal 10

10 Page 10 regulations. This information contained herein is based on the present state of knowledge and is intended to describe our product from the point of view of safety requirements. It should be therefore not be construed as guaranteeing specific properties.