ION EXCHANGE RESINS Rohm and Haas Company IER1

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1 ION EXCHANGE RESINS Boiler feed water Drinking water: removal of contaminants Radioactive waste cleaning Ultra-pure water for semiconductors Waste treatment: recovery of metals Food and beverage processing Pharmaceuticals 2007 Rohm and Haas Company IER1

2 Resins Uniform particle size Amberjet Standard particle size Amberlite Various polymers Styrenic Acrylic Phenolic Different matrices Gel type Macroporous Amberjet 4400 Amberlite IRA Rohm and Haas Company IER2

3 Applications Water treatment Industrial water treatment Boiler feed water Nuclear power Condensate Radioactive waste Ultra-pure water Drinking water Household softening Waste water Special applications Catalysts Separations Purifications Nutrition Pharmacy Biotechnologies 2007 Rohm and Haas Company IER3

4 Industrial water treatment Softening Demineralisation Mixed bed polishing ADI standard plant 2007 Rohm and Haas Company IER4

5 Demineralisation Boiler feed water with Amberjet resins Quality 0.1 to 1 µs/cm before polishing to 0.1 µs/cm after polishing 2007 Rohm and Haas Company IER5

6 Amberpack Reverse flow regeneration technology Compact system Easy regeneration Very little waste 98 % water recovery % salt rejection Hundreds of plants in service 2007 Rohm and Haas Company IER6

7 Advanced Amberpack With fractal distribution ADI 60: 60 m 3 /h demineralisation ADN for nitrate removal Compact and modular ADI Rohm and Haas Company IER7

8 Polishing After RO After primary demin Treated water After flash evaporation Condensate polishing Resin 2 Mixed bed technology Amberjet resins Freeboard Collector Amberpack Sandwich No mixing, no backwash Resin 1 Feed water Amberpack Sandwich 2007 Rohm and Haas Company IER8

9 Demineralisation Mixed bed for electro-erosion machines Special resin for this application only Ready for use Amberlite MB9L 2007 Rohm and Haas Company IER9

10 Power Nuclear and fossil-fuelled stations (EdF etc.) Boiler make-up water Condensate polishing Primary circuit Secondary circuit Radioactive waste treatment Fuel storage pond 2007 Rohm and Haas Company IER10

11 Condensate polishing Unique resin combination: Amberjet Ambersep 900 Stable Clean High ammonia capacity Excellent separability 2007 Rohm and Haas Company IER11

12 Household softening Large and small producers of softeners use Amberlite SR1LNa Imac HP1110Na Approved by French Health Authority and many other authorities In Europe, all dishwashers are equipped with a small softener using a resin like Amberlite IR120FF Na 2007 Rohm and Haas Company IER12

13 Drinking water Point of use A growing market with Imac HP333 Hardness removal cartridges Imac HP555 Selective nitrate removal 2007 Rohm and Haas Company IER13

14 Drinking water Municipal Amberlite PWA5 Nitrate removal Amberlite PWA10 Boron removal Amberlite PWA2 Perchlorate removal Advanced Amberpack ADN in the UK 2007 Rohm and Haas Company IER14

15 Desalination Boron removal after RO Amberlite PWA10 Totally selective resin Removes B only 0.1 mg/l residual B 99% + water recovery Boron removal in Kziot 2007 Rohm and Haas Company IER15

16 Ultra-pure water Amberjet UP and Amberlite UP developed specifically for the semiconductor industry Minor impurities in the water used for the production of wafers can create short-circuits and make the product unusable Amberjet UP6040 used in the final mixed bed polisher It brings the last impurities down to ng/l (ppt) levels Rohm and Haas Company IER16

17 Waste water solutions Soil reclamation Heavy metals removal (Hg, Cd) Ambersep GT74 Amberlite IRC748 Removal of phenol Amberlite XAD4 Ammonium nitrate recovery Fertilizer plants 2007 Rohm and Haas Company IER17

18 Catalysis using ion exchange resins Amberlyst 31, 131 & 121 main catalysts used for Bisphenol A, one of the components of polycarbonate and epoxy resins. Amberlyst 15Dry & 36Dry For the production of alkylphenols used in detergent formulations Amberlyst 35 catalyst used in the synthesis of octane improvers (petrol additives) such as MTBE, ETBE, TAME & iso-octane 2007 Rohm and Haas Company IER18

19 Chemical separations Uranium mining Amberjet 4400 & Ambersep 920U Soil reclamation Heavy metals removal (Hg, Cd) Ambersep GT74 Amberlite IRC748 Removal of phenol Amberlite XAD4 Ammonium nitrate recovery Fertilizer plants Purifications Phenol Glycol Formaldehyde 2007 Rohm and Haas Company IER19

20 Chemical separations (2) Boron removal From magnesium brine Amberlite IRA743 Calcium removal from brine Chlor-alkali industry Amberlite IRC747 Biodiesel purification Removal of potassium and sodium Amberlite BD10Dry 2007 Rohm and Haas Company IER20

21 Metals Many applications Rinse water from plating baths Recovery of metal catalysts Chromic acid recycling Pickling baths recycling Removal of iron from chromic acid Metal catalyst recovery in plastics production Recovery of gold from plating solutions Recovery of silver 2007 Rohm and Haas Company IER21

22 Sugar & sweeteners Calcium removal from beet juice Amberlite FPC14 Na De-ashing of liquid sugar Amberlite FPC22 H and FPA53 Colour removal from cane juice Amberlite FPA98 Cl and FPA90 Cl Purification of sweeteners Glucose, fructose, maltose Polyols Chromatographic separations Amberlite CR1310 & CR1320 High fructose syrup 2007 Rohm and Haas Company IER22

23 Beverages Orange juice debittering Amberlite FPX66 Water for breweries De-alkalisation, partial deionisation Amberlite PWC13 Water for soft drinks Removal of colour and natural organics Amberlite PWA Rohm and Haas Company IER23

24 Pharmaceutical applications Resins as active ingredients Duolite AP143 = cholestyramine Blood cholesterol control Amberlite IRP69 = sodium polystyrene sulphonate Reduces blood potassium level Resins as drug excipients ART (advanced release technologies) A series of technologies and products Tablet disintegrants Taste-masking Slow release Amberlite IRP64 Taste masking Controlled release of drugs Nicotine loaded chewing gums 2007 Rohm and Haas Company IER24

25 Biotechnologies Amberlite Cobalamion Purification of Vitamin B 12 from fermentation broths Amberlite XAD1600 Non-ionic adsorbent Separation of two or more similar species Production & purification of antibiotics Amberzyme Oxirane Enzyme immobilisation Amberchrom CG & XT Adsorption Reversed phase liquid chromatography Purification of proteins and peptides 2007 Rohm and Haas Company IER25

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