Waste Management in the Chemical and Petroleum Industries

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1 Brochure More information from Waste Management in the Chemical and Petroleum Industries Description: The global chemical and petroleum industries have always had the challenge of disposing of chemical wastes, by products, and residuals, but with traditional techniques such as deep well injection and incineration proving flawed, the need for disposal by legal, safe and economically effective means has never been greater. Increasingly, the need to produce without pollution is the preferred model for industry, and the strategy of waste minimization is seen as the best way forward. This is particularly relevant in the petrochemical and chemical industries, where large quantities of hazardous and toxic wastes are produced which can pose formidable disposal problems. Covering the essentials of treatment, recovery and disposal of waste, as well as the requirements for process design and engineering of equipment and facilities in the chemical and petroleum industries, this book includes chapters on: - Wastewater Treatment - Physical Unit Operations - Chemical Treatment - Biological Treatment - Wastewater Treatment in Unconventional Oil and Gas Industries - Wastewater Sewer Systems - Sewage Treatment - Solid Waste Treatment and Disposal Primarily aimed at researchers and advanced students in chemical, petroleum, and environmental fields as well as those in civil engineering, this book should also provide a unique reference for industry practitioners and anyone interested in chemical and petroleum waste treatment and disposal. Contents: Preface xv Acknowledgments xix Biography xxi 1 Wastewater Treatment Characteristics of Wastewaters Suspended Solids Heavy Metals Dissolved Inorganic Solids Toxic Organic Compounds Surfactants Priority Pollutants Volatile Organic Compounds Treatment Stages Sources of Wastewater Discharge Options and Quality Requirements 8

2 1.2.3 Preliminary Wastewater Treatment Primary Wastewater Treatment Conventional Secondary Wastewater Treatment Nutrient Removal or Control Advanced Wastewater Treatment/Wastewater Reclamation Toxic Waste Treatment/Specific Contaminant Removal Sludge Processing Treatment Processes Selection of Treatment Processes Chemical Oxygen Demand (COD) in Wastewater Systems Determination of the COD Calculation of Theoretical Oxygen Demand 23 2 Physical Unit Operations Flow Measurement Screening Comminution Grit Removal Gravity Separation General Application Oil Water Separator General Design Considerations Conventional Rectangular Channel (API) Separators Parallel Plate Separators Oil Traps Oil Holding Basins Flow Equalization Application and Location Volume Requirements Mixing Description and Type Application Sedimentation 49

3 2.8.1 Sedimentation Theory Application and Type Design Considerations Number of Basins Inlet Arrangements Short Circuiting Outlet Arrangements Detention Time Surface Loading Rate Factors Affecting Sedimentation Dissolved Air Flotation (DAF) General System Configuration Variables Affecting DAF Efficiency Treatability Testing Design Considerations Instruments and Control Piping Chemical Facilities Material Estimation of Air Concentration in Dissolved Air Flotation (DAF) Systems Granular Media Filters General Filter Types and Applications System Design Parameters Cycle Time Vessels and Appurtenances Instrumentation and Controls 78 3 Chemical Treatment Introduction 81

4 3.1.1 Chemical Precipitation Chemical Coagulation Chemical Oxidation and Advanced Oxidation Ion Exchange Chemical Stabilization Definition and Application Activated Carbon Adsorption Chemical Precipitation Chemical Flocculation Definition and Applications Design Considerations Clarifier Chemical Addition Systems Disinfection Chemical Agents Mechanical Means Chlorination Application Chlorine Dosages Design Considerations 96 4 Biological Treatment Theory Biological Activated Carbon Process Biokinetic Theoretical Model Biological Treatment Processes Major Differences in Aerobic and Anaerobic Treatment Aerobic Processes Anaerobic Waste Treatment Aerobic, Anaerobic (Facultative) Waste Treatment Activated Sludge Units Applications Effects of Activated Sludge 114

5 4.3.3 Feed Composition Process Design Design Considerations Trickling Filters Trickling Filter Process Design Rotating Biological Contactor System Sewage Oxidation Ponds Wastewater Treatment in Unconventional Oil and Gas Industries Background Dissolved and Dispersed Hydrocarbon Components Dissolved Mineral Production Chemicals Produced Solids Dissolved Gases Toxicity Limitations of Coal Bed Water Shale Gas and Coal Seam Gas Produced Water, Treatment and Disposal Evaporation Pond Surface Stream Disposal Ion Exchange Membrane Filtration Technology Freeze Thaw Evaporation Adsorption Chemical Oxidation Filtration Constructed Wetlands Electrodialysis/Electrodialysis Reversal Deep Well Injection at Dedicated Onshore Sites Biological Aerated Filters Macro Porous Polymer Extraction Technology Thermal Technologies Re Thinking Technologies for Safer Facing 147

6 5.5 Water Treatment for Oil Sands Mining Recycling and Water Treatment Options Oily Water Treatment in Oil Sands Mining Wastewater Sewer Systems Stormwater Sewer System Oily Water Sewer System Non Oily Water Sewer System Chemical Sewer System(s) Disposal of Chemical Sewers Neutralization Systems Type of Chemical Wastes Sanitary Sewer System Special Sewer Systems Effluent Sources and Disposals Particular Effluents in Refinery and Petrochemical Plants Caustic Scrubs (Heavy Oils) Desalter Wastewater Foul or Sour Waters Spent Caustic Solutions MTBE or Leaded Contaminated Streams Benzene Contaminated Streams Spent Sulfuric Acid Products Nitrogen Base Components Cyanides Aluminum Chloride Polyelectrolyte Ferric Chloride Phosphoric Acid Hydrofluoric Acid Other Spent Catalysts Chemical Cleaning Wastes Sulfur Solidification and Crushing Facilities and Loading

7 Systems Drainage Water Containing Solids, Emulsifying Agents, etc Heavy Viscous Oils Drainage Toxic Metal Contaminated Streams Solvent Processes Drainage Treating Processes Drainage Petrochemical Plants Special Effluents Summary of Disposal/Treatment Methods NGL, LNG, and LPG Area Effluents Liquefied Gas Spill Gas Treatment Facilities Effluents Effluents from Terminals, Depots, and Product Handling Areas General Considerations and Conditions for Release of Wastes Characteristics and Composition of Waste Characteristics of the Discharge Site and Receiving Environment Availability of Waste Technologies Effluent Wastewater Characteristics Flow Temperature ph Oxygen Demand Phenol Content Sulfide Content Oil Content Light Hydrocarbon Solubility in Water Predicting Water Hydrocarbon System Mutual Solubility Wastewater Emissions Point Source Discharge Effluent Permissible Concentrations Sewage Treatment 195

8 7.1 Sewage Effluents Receiving Water Final Effluents of Domestic Wastewater Plants Methods of Sewage Treatment: General Conventional Methods Choice of System: General Design of Sewage Treatment Plants: General Guidances Design of Small Sewage Treatment Plants Collection of Information Preliminary Treatment Primary and Secondary Settlement Tanks Capacities of Primary Settlement Tanks Sludge Digesters Drying Beds Secondary Settlement Tanks Biological Filters Distribution Volume of Filter Mineral Filter Media Activated Sludge Units Tertiary Treatment (Polishing) Processes Disposal of Final Effluent Advanced Wastewater Treatment Effects of Chemical Constituents in Wastewater Advanced Wastewater Treatment Operations and Processes Effluent Disposal and Reuse Direct and Indirect Reuse of Wastewater Solid Waste Treatment and Disposal Basic Considerations Classification Methodology Sources 216

9 8.1.4 Characteristics Quantities Sludge Handling, Treatment, and Reuse General Sludge and Scum Pumping Sludge Piping Preliminary Operation Facilities Thickening (Concentration) Stabilization Design Considerations Lime Stabilization Heat Treatment Anaerobic Sludge Digestion Composting Conditioning Disinfection Dewatering Sludge Dewatering Methods Vacuum Filtration Centrifugation Belt Filter Press Sludge Drying Beds Lagoons Heat Drying Thermal Reduction Thermal Reduction Process Applications Land Application of Sludge Chemical Fixation Final Sludge and Solids Conveyance, Storage, and Disposal Conveyance Methods Environmental Considerations in Sludge Transportation 246

10 Sludge Storage Final Disposal Incineration Ash Handling and Disposal Disposal of Solid Waste Types of Waste Siting of Hazardous Waste Facilities Non Hazardous Waste Sources, Segregation, Quantities, and Characteristics of Solid Waste in Refineries Source Reduction Methods Resource Recovery and Waste Minimization Hazardous Waste Reduction Treatment Prior to Ultimate Disposal Disposal of Waste Generated in Drilling Wells General Sampling Considerations Air Monitoring of Waste for Employee Protection Procedures Hazards Quality Assurance Consideration 275 Definitions and Terminology 277 Bibliography and Further Reading 307 Index 323 Ordering: Order Online - Order by Fax - using the form below Order by Post - print the order form below and send to Research and Markets, Guinness Centre, Taylors Lane, Dublin 8, Ireland.

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12 Page 1 of 2 Fax Order Form To place an order via fax simply print this form, fill in the information below and fax the completed form to (from USA) or (from Rest of World). If you have any questions please visit Order Information Please verify that the product information is correct. Product Name: Web Address: Office Code: Waste Management in the Chemical and Petroleum Industries SC Product Format Please select the product format and quantity you require: Hard Copy (Hard Back): Quantity USD USD 29 Shipping/Handling * Shipping/Handling is only charged once per order. Contact Information Please enter all the information below in BLOCK CAPITALS Title: Mr Mrs Dr Miss Ms Prof First Name: Last Name: Address: * Job Title: Organisation: Address: City: Postal / Zip Code: Country: Phone Number: Fax Number: * Please refrain from using free accounts when ordering (e.g. Yahoo, Hotmail, AOL)

13 Page 2 of 2 Payment Information Please indicate the payment method you would like to use by selecting the appropriate box. Pay by credit card: You will receive an with a link to a secure webpage to enter your credit card details. Pay by check: Please post the check, accompanied by this form, to: Research and Markets, Guinness Center, Taylors Lane, Dublin 8, Ireland. Pay by wire transfer: Please transfer funds to: Account number Sort code Swift code IBAN number Bank Address ULSBIE2D IE78ULSB Ulster Bank, Main Street, Blackrock, Co. Dublin, Ireland. If you have a Marketing Code please enter it below: Marketing Code: Please note that by ordering from Research and Markets you are agreeing to our Terms and Conditions at Please fax this form to: (646) or (646) From USA or From Rest of World

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