Toluene diisocyanate. General information

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1 Toluene diisocyanate General information Key Points Toxic via all routes of exposure Chemical classification: possible carcinogen, very toxic and irritant Inhalation causes dry throat, chest tightness, shortness of breath, coughing and wheezing. Exposure to high concentrations can cause inflammation of the airways, severe asthmatic symptoms and fluid accumulation in the lungs. Symptoms may be delayed for 4-8 hours after the exposure Ingestion of toluene diisocyanate may cause stomach upset. Skin contact with toluene diisocyanate causes irritation, inflammation, itching and blisters. Eye contact may cause irritation, itching, tearing, sensitivity to light and inflammation. Prepared by K Foxall CRCE HQ, HPA 2010 Version 1

2 Background Toluene diisocyanate is a colourless to pale yellow flammable liquid with a sharp pungent odour. It exists in two forms; 2,4- toluene diisocyanate and 2,6-toluene diisocyanate. The two different forms are known as isomers. Toluene diisocyanates are man-made chemicals that are commercially available as pure 2,4-toluene diisocyanate or as a mixture of the two forms. They are used to produce polyurethane foams for insulation, packaging and furniture. They are also used to make adhesives, sealants and polyurethane coatings for metal products and leather. accumulation in the lungs. The onset of symptoms may be immediate or delayed for 4-8 hours and can progress over a period of days. Some individuals may develop an allergic reaction to toluene diisocyanates after they have breathed them in and repeated exposure in the workplace can cause severe asthmatic symptoms. However the general public is not expected to be exposed to such levels. Exposure to toluene diisocyanates will mainly occur in the workplace although safe levels are enforced to protect the employees. The general public may be exposed to low levels of toluene diisocyanates due to their use in polyurethane products such as polyurethane varnishes but such low levels are not thought to be harmful. If exposed to toluene diisocyanates, the potential adverse health effects that may occur depend on the way people are exposed and the amount they are exposed to. Ingestion of toluene diisocyanates may cause stomach upset. Breathing in toluene diisocyanate vapour can cause dry throat, chest tightness, shortness of breath, coughing and wheezing. Stomach upset, headache, drowsiness, and loss of consciousness may also occur. Exposure to high concentrations can cause inflammation of the airways, severe asthmatic symptoms and fluid Skin contact with toluene diisocyanates causes irritation, inflammation, itching, blisters and contact dermatitis. They may be absorbed into the blood following skin contact and can lead to the development of asthma. Eye contact may cause irritation, itching, watering eyes, sensitivity to light and inflammation. The International Agency for Research on Cancer (IARC) has classified toluene diisocyanates as being possibly carcinogenic in humans. General information: Page 2 of 5

3 What are toluene diisocyanates? Frequently Asked Questions Toluene diisocyanates are colourless to pale yellow liquids with a sharp pungent odour that exists in two forms; 2,4-toluene diisocyanate and 2,6-toluene diisocyanate. They are manmade chemicals used to make polyurethane foams for insulation, packaging and furniture, adhesives, sealants and polyurethane coatings for metal products and leather. How do toluene diisocyanates get into the environment? Toluene diisocyanates are released into the environment during production, transport and use. They do not persist in the environment and are rapidly broken down in air and water. How will I be exposed to toluene diisocyanates? The general public may be exposed to very low levels of toluene diisocyanates when using polyurethane products such as polyurethane varnishes. People may also breathe in toluene diisocyanates if they are close to industrial areas where they are being released or where a spillage has taken place. Exposure can also occur in the workplace where toluene diisocyanates are produced or used. If there are toluene diisocyanates in the environment will I have any adverse health effects? The presence of toluene diisocyanates in the environment does not always lead to exposure. Clearly, in order for it to cause any adverse health effects you must come into contact with it. You may be exposed by breathing, eating, or drinking the substance or by skin contact. Following exposure to any chemical, the adverse health effects you may encounter depend on several factors, including the amount to which you are exposed (dose), the way you are exposed, the duration of exposure, the form of the chemical and if you were exposed to any other chemicals. Inhalation can cause dry throat, chest tightness, shortness of breath, coughing, wheezing, stomach upset, headache, drowsiness, and loss of consciousness. Exposure to high levels of toluene diisocyanates can cause inflammation of the airways, severe asthmatic symptoms and fluid accumulation in the lungs. Symptoms may be immediate or delayed for up to 4-8 hours after the exposure. Some individuals develop an allergic reaction to toluene diisocyanates following inhalation exposure. Re-exposure to the chemical can cause severe asthma symptoms that can be immediate or delayed for an hour or more. However this usually happens in the workplace and the general public is not expected to be exposed to such levels. Long-term inhalation exposure can also cause lung damage. Ingestion may result in stomach upset. Skin contact with toluene diisocyanate can cause irritation, inflammation, itching, blisters and contact dermatitis. Eye contact causes irritation, itching, tearing, sensitivity to light and inflammation. General information: Page 3 of 5

4 Can toluene diisocyanates cause cancer? The International Agency for Research on Cancer (IARC) has classified toluene diisocyanates as being possibly carcinogenic in humans. Do toluene diisocyanates affect children or damage the unborn child? There are no data available to assess the reproductive and developmental effects of toluene diisocyanates in humans. Exposure to toluene diisocyanate during pregnancy should be avoided because of its general toxic effects. What should I do if I am exposed to toluene diisocyanates? You should remove yourself from the source of exposure. If you have got toluene diisocyanates on your skin remove soiled clothing, wash the affected area with lukewarm water and soap for at least minutes and seek medical advice. If you have got toluene diisocyanates in your eyes remove contact lenses, wash the affected area with lukewarm water for at least minutes and seek medical advice. If you have inhaled or ingested toluene diisocyanates seek medical advice. This document will be reviewed not later than 3 years or sooner if substantive evidence becomes available. General information: Page 4 of 5

5 General information: Page 5 of 5

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