ORGALLOY. High-performance polyamide alloys

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1 ORGALLOY High-performance polyamide alloys

2 Topics What is Orgalloy? Basic concept and advantages Orgalloy range Outstanding properties Applications 2 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

3 What is Orgalloy Immiscible blend of Polyamide and Polyolefin Polyamide 6 or 6,6 based alloy with a dispersed polyolefin phase Bad mixture of the 2 materials. Poor performance. Intimate mixture of materials. Compatibilizers guarantee the morphology and a constant level of performance. Stable over multiple processing runs. 3 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

4 Orgalloy performance is higher than PA6 Low density Thermal resistance Low moisture uptake: dimensional stability, constant properties. High chemical resistance and barrier properties Easy processing, high productivity Compatibility with other polymers Polyolefin Easy processing No moisture uptake Inert to polar solvents Impact resistant Polyamide 6 or 6,6 Mechanical strength Thermal resistance Barrier to HCs Chemical resistant to HCs 4 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

5 200 Extrusion tube, mandrel Extrusion blow molding Cable coating Orgalloy range LT Flexible LT...ES: Extrusion blow molding LT T6L: Heat stabilized 500 LE LE60..: PA6 based LE60THM: Very high modulus LE60LM: Low Modulus LE XV: Plasticized Extrusion tube, profile Blown & cast film Cable coating Blow molding extrusion RS 1,300 Rigid 8,200 MPA (Flexural modulus) Semi-flexible 2,000 R60ES: Blown film grade. RS60..: PA6 based RS66..: PA6.6 based RS..30 G.F.: GF reinforced (%) Injection molding 5 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

6 Topics What is Orgalloy? Basic concept and advantages Orgalloy range Outstanding properties Applications 6 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

7 Outstanding properties Density ~ 10% < PA6 & PA6,6: ideal for light weight components. Orgalloy PA6 &6,6 Density (g/cm3) 1,04 1,14 Very low weight and dimensionsional variations compared to PA6 & PA6,6 (factor 2 to 6). Specimen Variation Condition PA6 100*100*2 mm plates Weight Dimensions RS 6000 PA6,6 RS days, 23C, water 3.7% 1% 2.2% 0.6% 2 months, 23C, 50% moisture (initial state 24h after molding) 3 days, 23C, water 0.18% 0.08% 0.12% 0.02% 2 months, 23C, 50% moisture (initial state 24h after molding) PA6 GF30 RS % 0.02% 0.2% 0.05% 7 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

8 Very low moisture pick up 8 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

9 High chemical resistance Compared to classical PA6 & PA66, Orgalloy provides: Good performance retention to a broad range of different chemicals. Superior chemical resistance. Medium Temperature RS LE LT PA6 & PA66 Acetone Solvent Toluene Trichloroethylene MEK 23C Ethanol Alcohols Methanol 60C Methanol / Water 50/50 70C Glycols Ethylene-glycol / Water 50/50 115C Ethylene-glycol / Water 50/50 135C Acids Sulfonitric acid (H2SO4 400mg/L, HNO3 50mg/L, HCL 50mg/L) 95C H2SO4 3% HCL 10% 23C Base NAOH 5% 60C Fuel / Methanol 40C Hydrocarbons ASTM OIL n3 Brake fluid 80C Salts CaCl2 5% 60C ZnCL2 50% 40C 9 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

10 Unique barrier properties Medium Conditions (on 25 µm films) Units LE 6000 PE PP PA6 Water 75% 25C Polar liquids Methanol g/m 2 /24h 1, ,600 60% 20C Ethanol Oxygen 0% 25C cc/m 2 /24h 90 3,000 4, CO2 75% 290 9,000 9, Gases Pentane 0.4 8,000 30, % 20C Octane g/m 2 /24h Aromatics White spirit 0.4 1, % 20C Solvents Chloroform ,400 14, Orgalloy : unique synergies PA matrix: Excellent barrier performance to HCs and apolar components. PE phase: Good barrier performance to polar components. Orgalloy alloy-technology : permeation is lower than blend/mixture of PA6/PE. This is the nanocomposites synergetic effect of alloys. 10 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

11 Thermal resistance Extrusion / blow molding grades Orgalloy Half-life at different temperatures. Criteria: Strain at break. LT 5050 LT 5050 LE series LT ES series TEEE NAT NAT T6L Dumbbell IFC ISO IFC ISO IFC ISO IFC ISO IFC ISO 130ºC 840h 450h 3,250h 140ºC 650h 680h 1,400h 1,080h 150ºC 300h 200h 950h 650h 700h Temperature resistance: LT5050 T6L > LT ES series > LT NAT > LE Series Injection molding grades Half-life reached at 1000 to 2000h depending on criteria. Aging temperature = 150ºC RS 6635A 0h 1,000h 2,000h Flexural modulus (MPa) 8,210 8,080 8,420 Stress at break (MPa) Resilience (KJ/m 2 ) General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

12 Topics What is Orgalloy? Basic concept and advantages Orgalloy range Outstanding properties Applications 12 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

13 Grade Application Picture Key properties LT 5050 ES NOIR LT4060 ES T6L NOIR LT 5050 T6L NATUREL LE 60 THM Applications per grades Oil filler tubes Liner for gas tank Air intake ducts Barrier layer for air conditioning hoses LPG line Chemical packaging Return tubing for driving cable in sunroof system Cable: plastic protection profile Fuel station pipe Flexibility & Fatigue resistance Resistance to oils Low density, Good Melt strength Barrier to CH4 (> PE), Cold impact resistance Processing Thermal resistance (>TEEE) for severe under bonnet conditions Flexibility & Fatigue resistance Low density, Good Melt strength Easy switch from competitor products Combination with rubber, direct contact with lubricants. High barrier properties to refrigerants. Flexibility, Low density. Barrier properties to LPG & resistance to automotive fluids Flexibility Monolayer or three layer by extrusion blow molding. Light weight, Dimensional stability, chemical resistance. Excellent flexibility and surface properties (noise reduction) Dimensional stability Thermal resistance Chemical resistance to hydrocarbons Good resistance to both water & hydrocarbons. Low abrasion & friction. Low creeping Barrier to fuels (diesel + gasoline) Good impact resistance at -30 C on tubing 13 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

14 Applications per grades LE 60 LM XV NATUREL LE TCP 01 NATUREL LE 6000 NATUREL LE 6000 ST NATUREL R60 ES NATUREL RS series RS6000 Application Picture Key properties Hydraulic tubing Cable: tape Profiles & rolls (conveyors industry) Off-shore cable sheathing Technical films Electric connectors Sport Tube clamping (mainly RS6000) Ablition plate for miniature circuit breaker Flexibility, resistance to water, hydrocarbons, chemicals. Resistance to water & hydrocarbons. Low abrasion & friction. Low creeping. Low abrasion & friction and heat built up Chemical resistance Cold impact resistance, Food approved Replacement of EVA / PVC with lead sheathing. Only 1 layer: weight and flexibility gain. Resistance to water & hydrocarbons. Low friction coefficient. Barrier properties & Chemical resistance Thermal resistance, Mechanical strength, Low surface tension Dimensional stability, chemical resistance to automotive fluids Complex parts Light weight, Dimensional stability Sturdy and secure, UV resistant Low moisture pick-up, Chemical resistance Stiffness, Impact resistance Combination (co-molding with PP resins) Excellent Arc resistance & insulation properties Excellent processing ability RS 6635 A NOIR Fan shroud Dimensional stability, No conditioning required Vibration dampening Low molding tolerances 14 General presentation Orgalloy - High Performance Alloy - Arkema property Duplication prohibited

15 Specialty chemicals Innovative chemistry

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