Marsa Thermal Treatment Facility Yearly Emissions Statement (revised June 2011)

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1 Marsa Thermal Treatment Facility Yearly Emissions Statement (revised June 2011) Declaration Period: 2010 FACILITY DETAILS IPPC permit number: IP 0004/07 Name of the facility: MARSA THERMAL TREATMENT FACILITY Street address: TRIQ IL-BICCERIJA Town/village: MARSA Country: MALTA Coordinates of the location: 54825; Number of installations in the same 1 facility: PLANT OWNER Name of company: WASTESERV MALTA LIMITED TYPE OF PLANT Thermal input (MW): 4.5MW Thermal output (MW): Capacity for fuel (tonnes per hour): kg/hr Capacity for waste (tonnes per hour): Max 1.2t/hr EMISSIONS TO AIR SOURCE OF EMISSIONS Maximum stack temperature of flue gas at the point of discharge at maximum rated power in oc: Volumetric flow rate at maximum rated power in Nm3/h Oxygen content of flue gas volumetric flow in % related to Nm3/h Size of stack opening/cross section of stack in m2: Height of discharge emissions above ground in m: DESIGN FUELS Design fuel or waste mixture: Fuel/waste contained in design mix: OPERATING DATA , % Fuel to be used is diesel and waste that can be incinerated (refer to section 3.19 of IPPC Application submitted to MEPA) Approx. 10% of waste load 1

2 Number of operating hours: 6635 Emission performance of the plant Please see attached Incidents Report (number and duration of emission (Annex 3) exceedances): INFORMATION ABOUT FUEL Name: Heating gasoil Diesel Fuel (for space heating purposes) EneMalta 46,800kg/month 43,000KJ/kg USED WASTE (increase rows for different waste streams e.g. animal waste, clinical, etc.) Name: Animal by-products (EWC , , , ) Animal waste including slaughterhouse waste from public and private slaughterhouses and fallen animals. Slaughterhouses of animals including chickens, ruminants, pigs and rabbits. Fallen animals are generated on animal farms tonnes 3-6MJ/Kg 6, tonnes Name: Clinical Waste (EWC *, *, *) Biological and biomedical hazardous waste Hospitals tonnes 18MJ/Kg tonnes Name: Pharmaceutical waste (EWC *, ) Pharmaceutical waste Pharmaceutical Manufacturing and Distribution Activities 2

3 6.41 tonnes 5-18MJ/Kg tonnes Name: Refuse Derived Fuel (EWC *, , , , , , * Paper material, shredded waste wood, textiles and contaminated trees that needs to be thermally treated. Civic Amenity Sites and Plant Protection Division tonnes 16MJ/Kg tonnes Name: Oily contaminated material (EWC *) Contaminated oily rags and sand absorbent Manufacturing Industry 0.43 tonnes Approx 18-20MJ/Kg 5.18 tonnes Name: Solvents (EWC *) Liquid non-aqueous (organic) waste Manufacturing industry 0.49 tonnes 21 MJ 5.85 tonnes Name: Paints (EWC *, ) Paints and sealants/adhesives Manufacturing industry, CA sites 5.6 tonnes 16.6 MJ 3

4 67.18 tonnes Name: Ink Cake (EWC *) Ink cake residue from printing industry Printing industry 3.15 tonne 3.5MJ tonnes Name: Pesticides and inorganic unused products (EWC *) Expired pesticides and inorganic unised products Agricultural Industry 0.01 tonne 5 MJ 0.12 tonnes AIR EMISSION LIMIT VALUES Fuel: Diesel Reference oxygen content is volume 11% Emission limit for each pollutant as Refer to IP 0004/07 prescribed in the permit: EMISSIONS OF AIR POLLUTING SUBSTANCES (A) FOR CONTINUOUSLY MONITORED EMISSIONS Carbon Monoxide Method applied for monitoring and IR analysis (Continuous) Environnement MIR 9000 with SEC probe Reference oxygen content in volume 11 Emission loads per year in kgs per 2, kg/year year: Emission concentrations of air mg/nm 3 pollutants in the flue gas at stack (monthly average): Sulphur Oxides Method applied for monitoring and IR analysis (Continuous) Environnement MIR 9000 with SEC probe Reference oxygen content in volume 11 4

5 Emission loads per year in kgs per year: Emission concentrations of air pollutants in the flue gas at stack (monthly average): Method applied for monitoring and Reference oxygen content in volume Emission loads per year in kgs per year: Emission concentrations of air pollutants in the flue gas at stack (monthly average): Method applied for monitoring and Reference oxygen content in volume Emission loads per year in kgs per year: Emission concentrations of air pollutants in the flue gas at stack (monthly average): kg/yr 3.43 mg/nm 3 Nitrous Oxides IR analysis (Continuous) Environnement MIR 9000 with SEC probe 11 11, kg/yr mg/nm 3 Dust Opacity Monitor LAND 3500 MkIV kg/yr 1.53 mg/nm 3 (B) FOR DISCONTINUOUSLY MONITORED EMISSIONS Method applied for monitoring and Reference oxygen content in volume Emission loads per year in kgs per year (calculated values): Method applied for monitoring and Reference oxygen content in volume Emission loads per year in kgs per year (calculated values): Antimony (Sb), Arsenic (As), Lead (Pb), Chromium (Cr), Cobalt (Co), Copper (Cu), Manganese (Mn), Nickel (Ni), Vanadium (V) and their compounds, expressed as their native elements, respectively (TOTAL) UNI EN 14385: kg Mercury and compounds UNI EN 14385: kg Dioxins and furans 5

6 Method applied for monitoring and Reference oxygen content in volume Emission loads per year in kgs per year (calculated values): UNI EN 1948: kg INFORMATION ABOUT THE FLUE GAS TREATMENT SYSTEM Indication whether a FGT system is Yes installed: Type of FGT system: Dry Scrubbing System Description of technology used: Injection of Sodium Bicarbonate and Activated Carbon followed with filtration using a Baghouse Filter. Technical data: Max filter inlet temperature: 180 C Effective flowrate at 180 C: 24,400Em 3 /hr Filtering surface: 468m2 Bag dimensions: Ø 125mm x 2510mm No. of Bags: 468 Max filtration rate: 0.85m/min Bag fabric: P84 Bag weight: 550g/m 2 Compressed air consumption at 7bar: 1000NI/min Cleaning efficiency: 99% EXCEEDANCE OF EMISSION LIMIT VALUES TO AIR HCl See attached Incidents Report (Annex 3) Suggestions for technical improvements in N/A SO 2 See attached Incidents Report (Annex 3) Suggestions for technical improvements in N/A CO See attached Incidents Report (Annex 3) Suggestions for technical improvements in Improvement in the Air Supply to PCC 6

7 TOC See attached Incidents Report (Annex 3) Suggestions for technical improvements in Improvement in the Air Supply to PCC NO X See attached Incidents Report (Annex 3) Suggestions for technical improvements in Introduction of UREA injection. Dust See attached Incidents Report (Annex 3) Suggestions for technical improvements in AUDIT REPORT Results of the audit: Date of last audit: Independent, accredited expert who effected the audit: Description of possible reportable shortcomings: EXTERL PARTICIPANTS IN ISSUING EMISSIONS STATEMENT Name: Organisation: Accredition: EMISSIONS TO WATER TYPE AND OBJECTIVE OF WASTE WATER TREATMENT SYSTEMS Type of WWT system: Objective of system: Daily waste water flow in m3: 5 Operating hours per year: 8760 Direct or indirect discharger: Direct WATER POLLUTING SUBSTANCES Limit values for concentrations (mg/l) and loads (tonnes or kg per hour; tonnes or kg per year) of pollutants: 7

8 Specific loads of pollutants per tonne of REPORTABLE EXCEEDANCE OF THRESHOLD VALUES FOR EMISSIONS TO WATER BOD Yearly and monthly emission load in 9.4tons/year Specific loads of pollutants per tonne of 1.29kg/ton of material COD Yearly and monthly emission load in Specific loads of pollutants per tonne of 4.7tons/year Yearly and monthly emission load in Specific loads of pollutants per tonne of 0.65kg/ton of material Suspendable Solids 9.5tons/year Total-N 1.31kg/ton of material 8

9 Yearly and monthly emission load in tons/year Specific loads of pollutants per tonne of 0.014kg/ton of material Kiedhal-N Yearly and monthly emission load in Specific loads of pollutants per tonne of tons/year Phosphate Yearly and monthly emission load in Specific loads of pollutants per tonne of kg/ton of material tons/year Yearly and monthly emission load in Specific loads of pollutants per tonne of 0.01kg/ton of material TDS (Total Dissolved Salts) tons/year 0.116kg/ton of material EXTERL PARTICIPANTS IN ISSUING EMISSIONS STATEMENT Name: Rete BIOLAB 9

10 Organisation: Accredition: Tektraco Ltd Compliance with Table Total Data tally MEAN ANNUAL COMPLIANCE Number of Months Filed 12 Number of months remaining 0 HCl CO SO2 TOC NOx Dust % Compliance with 100% limit % Compliance with 97% limit % Compliance with 95% limit 95.2 % Daily compliance (CO) 50.0 Wastewater analysis 12/5/ /05/ /05/ /05/ /05/2011 Average BOD ,146.8 mg/l COD ,580.0 mg/l Suspendable Solids ,200.0 mg/l Total-N mg/l N Kiedhal-N mg/l N Phosphate mg/l P ph a 20C TDS (Total Dissolved Salts) mg/l Quantity of waste water daily 5000 ltrs Working hours 365 days Daily Yearly BOD Kg COD Kg Suspendable Solids Kg Total-N Kg Kiedhal-N Kg Phosphate Kg ph a 20C Kg TDS (Total Dissolved Salts) Kg 10

11 PERMIT IP 0004/07 FACILITY - MMARSA THERMAL TREATMENT FACILITY LIST OF PERMITTED WASTES QUANTITY/TONNES FORESTRY, HUNTING AND FISHING, FOOD PREPARATION & PROCESSING wastes from agriculture, horticulture, aquaculture, forestry, hunting and fishing January February March April May June July August September October November December animal-tissue waste waste not otherwise specified wastes from the preparation and processing of meat, fish and other foods of animal origin animal-tissue waste , materials unsuitable for consumption or processing WASTES FROM ORGANIC CHEMICAL PROCESSES wastes from the MFSU of organic paint and plant protection products (except and ), wood preserving agents(except ) and other biocides * solid wastes containing dangerous substances waste from the MFSU of pharmaceuticals * solid wastes containing dangerous substances WASTE FROM THE MFSU OF COATINGS (PAINTS, VARNISHES AND VITREOUS EMELS) 08 ADHESIVES, SEALANTS AND PRINTING INKS wastes from the MFSU and removal of paint and varnishes * waste paint and varnish containing organic solvents or other dangerous substances waste paint and varnish other than those mentioned in wastes from the MFSU of printing inks * ink sludges containing dangerous substances wastes from the MFSU of adhesives and sealants (including waterproofing products) waste adhesives and sealants other than those mentioned in WASTE PACKAGING, ABSORBENTS, WIPING CLOTHS, FILTER MATERIALS AND PROTECTIVE 15 CLOTHING NOT OTHERWISE SPECIFIED packaging (including separately collected municipal packaging waste) * packaging containing residues of or contaminated by dangerous substances absorbents, filter materials, wiping cloths and protective clothing * absorbents, filter materials (including oil filters not otherwise specified), wiping cloths, protective clothing contaminated by dangerous substances Sub Totals absorbents, filter materials (including oil filters not otherwise specified), wiping cloths, protective clothing other than those mentioned in * WASTES NOT OTHERWISE SPECIFIED IN THE LIST off-specification hatches and unused products Inorganic wastes other than those mentioned in WASTE FROM HUMAN OR ANIMAL HEALTHCARE AND/OR RELATED RESEARCH 18 (except kitchen and restaurant wastes not arising from immediate healthcare) wastes from natal care, diagnosis, treatment or prevention from disease in humans * waste whose collection and disposal is subject to special requirements in order to prevent infection medicines other than those mentioned in Waste from research, diagnosis, treatment or prevention of disease involving animals * waste whose collection and disposal is subject to special requirements in order to prevent infection * chemicals consisting of or containing dangerous substances WASTES FROM WASTE MAGEMENT FACILITIES, OFF-SITE WASTE WATER TREATMENT 19 PLANTS AND PREPARATION OF WATER INTENDED FOR HUMAN CONSUMPTION/INDUSTRIAL USE wastes from the mechanical treatment of waste (for example sorting, crushing, compacting, palletising) paper and cardboard wood other than that mentioned in combustible waste (refuse derived fuel) MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIOL WASTES 20 (INCLUDING SEPARATELY COLLECTED FRACTIONS) separately collected fractions (excedpt 15 01) * oil and fat other than those mentioned in , Note: All Data submitted is subject to Revision

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