Advanced Materials Help Make Solar Panels More Powerful DuPont Solamet PV19x New Front Side Silver Metallizations
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1 Advanced Materials Help Make Solar Panels More Powerful DuPont Solamet PV19x New Front Side Silver Metallizations DuPont Microcircuit Materials
2 DuPont Solamet Driving Cell Performance Evolution New Higher efficiency PV19x Looking to the future: High efficiency LDE, PV17x High efficiency enhanced LDE, PV18x High efficiency improved fine line, PV18x Fine line aspect ratio will be key focus in metallization development to improve p-type cell efficiency Standard p-type PV16x First to introduce LDE with Solamet PV17x achieving a step change in efficiency New Gen. Solamet PV19x enabling extreme LDE with excellent fine line capability Copyright All rights reserved. 2
3 DuPont Solamet Driving Cell Performance Evolution Fine line aspect ratio is key to efficiency improvement with pattern optimization Screen Technology Paste DuPont Solamet for Fine Line Pattern Design Advance fine line innovations achieved by synergy from screen technology, paste and pattern design Copyright All rights reserved. 3
4 Lower Cost of Ownership, Greater Profitability DuPont Solamet PV19x delivers higher cell performance through: Fine Line Capability Processing Latitude Reliability Copyright All rights reserved. 4
5 Lower Cost of Ownership, Greater Profitability DuPont Solamet PV19x delivers higher cell performance through: Fine Line Capability Processing Latitude Reliability Copyright All rights reserved. 5
6 DuPont Solamet PV19A Demonstrates Superior Fine Line Control 30µm Reference 30µm Solamet PV19A Excellent fine line aspect ratio to sustain fill factor and gridline conductivity Copyright All rights reserved. 6
7 DuPont Solamet PV19A Demonstrates Superior Fine Line Paste Transfer 35µm screen opening Reference PV19A Reference 30µm screen opening PV19A Excellent printability down to 30µm screen opening: Reduced line spreading Better line definition Smoother morphology No printing EL defect Copyright All rights reserved. 7
8 DuPont Solamet PV19A Achieves Higher Cell Efficiency >0.1% Efficiency improvement on multi cells Improved line width control with significant Isc benefit on 35µm screen opening Excellent aspect ratio to boost fill factor and gridline conductivity Copyright All rights reserved. 8
9 Lower Cost of Ownership, Greater Profitability DuPont Solamet PV19x delivers higher cell performance through: Fine Line Capability Processing Latitude Reliability Copyright All rights reserved. 9
10 DuPont Solamet PV19x Enabling Extreme LDE by Reducing Contact Resistance by an order of Magnitude N=60pc N=60pc Diffusion insights to advance cell performance through innovative chemistry Excellent contact capability allowing robust processing latitude Copyright All rights reserved. 10
![Percent [%] DuPont Solamet PV19x Industry Collaboration 1: Superior Performance and Yield Demonstrated on Multi Cells Cell Efficiency Distribution 9 18.14 18.29 8 7 Ref-2 PV19x >0.](/docs-images/48/23965382/images/11-0.png "15% Efficiency gain on multi proven in pilot run 6 5 4 Robust processing latitude allowing tighter cell distribution to reduce low efficiency binning <17.")
11 Percent [%] DuPont Solamet PV19x Industry Collaboration 1: Superior Performance and Yield Demonstrated on Multi Cells Cell Efficiency Distribution Ref-2 PV19x >0.15% Efficiency gain on multi proven in pilot run Robust processing latitude allowing tighter cell distribution to reduce low efficiency binning <17.8% Production yield increased from 93% to 98.5% for >260W power output Customer A N=2500pc Efficiency Copyright All rights reserved. 11
12 Solamet PV19x Industry Collaboration 2: Multi Cell with High Rsheet Emitters Paste Screen Rsheet Eff (%) Eff gain (rel. %) Voc Isc FF 3BB 35umx 100F 90ohm/sq 17.91% PV19x Customer B N=200pc 3BB 31umx 110F 100ohm/sq 18.02% 0.11% ohm/sq 18.04% 0.13% Maximize efficiency through high Rsheet and fine line pattern optimization Copyright All rights reserved. 12
13 DuPont Solamet PV19x Industry Collaboration 3: Mono Cell with Extreme LDE Paste Rsheet ΔEff (rel. %) Voc Isc FF Ref-2 70ohm/sq PV19x (LDE) +0.23% Ref-2 70ohm/sq -0.03% PV19x (extreme-lde) +0.3% N=40pc Significant Voc/Isc benefit while maintaining fill factor through diffusion optimization and innovative paste technology Copyright All rights reserved. 13
14 Lower Cost of Ownership, Greater Profitability DuPont Solamet PV19x delivers higher cell performance through: Fine Line Capability Processing Latitude Reliability Copyright All rights reserved. 14
15 Field Studies Reveal Quality Issues Encapsulant, 4% Backsheet, 9% Cell, 24% DuPont Field Module Program Inspected >60 global installations (>200 MW & 1.5 million modules) in NA, EU, & AP ranging from 0-30 years installed Defect Not Detected, 59% Others, 1% Mismatch, 1% Subcomponent degradation mode pareto based on visual inspection Glass, 2% Data includes c-si modules from > 45 module manufacturers Accepted for presentation at IEEE PVSC (New Orleans, 2015, A. Bradley et al) 41% of inspected modules exhibited some visual defect Findings consistent with BP and SunPower data Copyright All rights reserved. 15
16 DuPont Holistic Cell and Module Durability Program Evaluate durability for PV materials and their interactions and synergies in module Develop products with highest durability to deliver more power output Copyright All rights reserved. 16
17 Aged Bonding Strength and Corrosion Resistance are Common Accelerated Testing Protocols for Metallization Related Durability Cu Sn/Pb Ag Si Aged Bonding Strength (for Busbar) Weak solder bond connection after acceleration test Corrosion Resistance (for Finger Line) Loss of finger grid contact after accelerated test Copyright All rights reserved. 17
18 New Generation Solamet Designed to Improve Aged Bonding Strength Successful differentiation of pastes allows development of superior products *Relevance to fielded modules is under investigation DuPont All rights reserved 18
19 DuPont Solamet PV19x Lower Cost of Ownership, Greater Profitability and Reliability Proprietary technology delivering >0.15% efficiency improvement on multi cell with proven module reliability Excellent fine line printability down to 30µm screen opening with improved aspect ratio to maintain FF and gridline conductivity Robust processing latitude to reduce low efficiency binning and improve production yield Enabling extreme LDE by reducing contact resistance by an order of magnitude to further boost Efficiency New, advanced materials such as Solamet PV series metallization pastes can enable 20% cost of ownership reduction by 2020 through increased cell efficiency and lower materials consumption..without compromising solar panel reliability and durability Copyright All rights reserved. 19
20 photovoltaics.dupont.com Copyright 2015 DuPont. All rights reserved. The DuPont Oval Logo, DuPont, The miracles of science, and all products denoted with or are trademarks or registered trademarks of E.I. du Pont de Nemours and Company or its affiliates. Images reproduced by E.I. du Pont de Nemours and Company under license from the National Geographic Society. DuPont All rights reserved
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