Material Safety Data Sheet

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1 Material Safety Data Sheet Revision Number: Issue date: 02/17/ PRODUCT AND COMPANY IDENTIFICATION Product type: Sealant Item number: Region: United States Company address: Contact information: Henkel Corporation Telephone: One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center Rocky Hill, Connecticut (toll free) or TRANSPORT EMERGENCY Phone: CHEMTREC (toll free) or Internet: 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW HMIS: Physical state: Paste HEALTH: *2 Color: White FLAMMABILITY: 3 Odor: Alcoholic PHYSICAL HAZARD: 0 Personal Protection: See MSDS Section 8 WARNING: FLAMMABLE LIQUID AND VAPOR. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF SWALLOWED OR INHALED. Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: May be harmful if inhaled. Vapors may cause headaches, nausea, dizziness and respiratory tract irritation. May cause skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. May cause mild irritation Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May be harmful if swallowed. Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Eye, skin, and respiratory disorders. This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). See Section 11 for additional toxicological information. Page 1 of 5

2 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous components CAS NUMBER % 2-Propanol Talc Castor oil Polyvinyl butyral - polyvinyl alcohol - polyvinyl acetate terpolymer Titanium dioxide Ethene, tetrafluoro-, homopolymer Quartz (SiO2) FIRST AID MEASURES Inhalation: Skin contact: Eye contact: Ingestion: Move to fresh air. If symptoms persist, seek medical advice. Wash with soap and water. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. Do not induce vomiting. Keep individual calm. Get medical attention. 5. FIRE FIGHTING MEASURES Flash point: Autoignition temperature: 23 C (73.4 F) Tagliabue closed cup C ( F) Estimated Flammable/Explosive limits - lower: 2.3 % Flammable/Explosive limits - upper: 12.7 % Extinguishing media: Special firefighting procedures: Unusual fire or explosion hazards: Hazardous combustion products: Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Oxides of carbon. Toxic fluorides. 6. ACCIDENTAL RELEASE MEASURES Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and unprotected personnel. Environmental precautions: Clean-up methods: Ventilate area. Remove all sources of ignition. Remove all sources of ignition. Ventilate area. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Handling: Storage: Do not get in eyes. Keep away from heat, spark and flame. Store away from heat, sparks, flames, or other sources of ignition. For information on product shelf life contact Henkel Customer Service at (800) Page 2 of 5

3 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper exposure controls and protective equipment for each task performed. Hazardous components ACGIH TLV OSHA PEL AIHA WEEL OTHER 2-Propanol 200 ppm TWA 400 ppm ( ppm STEL mg/m3) TWA Talc 20 MPPCF TWA 2.4 MPPCF TWA 2 mg/m3 TWA 0.1 mg/m3 TWA 0.3 mg/m3 TWA 50 ppm Castor oil Polyvinyl butyral - polyvinyl alcohol - polyvinyl acetate terpolymer Titanium dioxide 10 mg/m3 TWA 15 mg/m3 TWA Ethene, tetrafluoro-, homopolymer Quartz (SiO2) mg/m3 TWA 2.4 MPPCF TWA 0.1 mg/m3 TWA 0.3 mg/m3 TWA 10 mg/m3 TWA 5 mg/m3 TWA Engineering controls: Respiratory protection: Eye/face protection: Skin protection: Provide adequate local exhaust ventilation to maintain worker exposure below exposure limits. Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Safety goggles or safety glasses with side shields. Chemical resistant, impermeable gloves. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state: Paste Color: White Odor: Alcoholic Odor threshold: Not available ph: Not applicable Vapor pressure: 33 mm hg (20 C (68 F)) Boiling point/range: 82 C (179.6 F) Melting point/ range: Not determined Specific gravity: 1.12 at 25 C (77 F) Vapor density: 2.07 Flash point: 23 C (73.4 F) Tagliabue closed cup Flammable/Explosive limits - lower: 2.3 % Flammable/Explosive limits - upper: 12.7 % Autoignition temperature: C ( F) Estimated Evaporation rate: 7.7 (Ether = 1) Solubility in water: partially soluble Partition coefficient (n-octanol/water): Not determined VOC content: %; g/l Page 3 of 5

4 10. STABILITY AND REACTIVITY Stability: Hazardous reactions: Hazardous decomposition products: Incompatible materials: Conditions to avoid: Stable Will not occur. Toxic fluorides. Oxides of carbon. Oxidizing agents. Acids. Aldehydes. Amines. Heat, flames, sparks and other sources of ignition. 11. TOXICOLOGICAL INFORMATION Hazardous components NTP Carcinogen IARC Carcinogen OSHA Carcinogen (Specifically Regulated) 2-Propanol No No No Talc No No No Castor oil No No No Polyvinyl butyral - polyvinyl alcohol - polyvinyl acetate terpolymer No No No Titanium dioxide No Group 2B No Ethene, tetrafluoro-, homopolymer No No No Quartz (SiO2) Known carcinogen. Group 1 No Hazardous components 2-Propanol Talc Castor oil Polyvinyl butyral - polyvinyl alcohol - polyvinyl acetate terpolymer Titanium dioxide Ethene, tetrafluoro-, homopolymer Quartz (SiO2) Health Effects/Target Organs Allergen, Blood, Brain, Central nervous system, Irritant, Kidney, Liver, Spleen Irritant, Lung, Some evidence of carcinogenicity Irritant No Records Irritant, Respiratory, Some evidence of carcinogenicity No Target Organs Immune system, Lung, Some evidence of carcinogenicity 12. ECOLOGICAL INFORMATION Ecological information: Not available 13. DISPOSAL CONSIDERATIONS Information provided is for unused product only. Recommended method of disposal: Hazardous waste number: Follow all local, state, federal and provincial regulations for disposal. D001: Ignitable. 14. TRANSPORT INFORMATION U.S. Department of Transportation Ground (49 CFR) Resin solution Exceptions: (Not more than 5 L), ORM-D, Consumer Commodity International Air Transportation (ICAO/IATA) Resin solution Exceptions: Consumer Commodity, ID 8000, Class 9, (Not more than 500 ml) Page 4 of 5

5 Water Transportation (IMO/IMDG) RESIN SOLUTION United States Regulatory Information 15. REGULATORY INFORMATION TSCA 8 (b) Inventory Status: TSCA 12(b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: CERCLA Reportable quantity: California Proposition 65: All components are listed or are exempt from listing on the Toxic Substances Control Act Inventory. above reporting de minimus above reporting de minimus Immediate Health, Delayed Health, Fire above reporting de minimus 2-Propanol (CAS# ) 100 lbs. (45.4 kg) This product contains a chemical known in the State of California to cause cancer. This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: All components are listed on or are exempt from listing on the Canadian Domestic Substances List. B.2, D.2.A, D.2.B 16. OTHER INFORMATION This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Prepared by: Kyra Kozak Woods, Manager, Regulatory Affairs DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits. Page 5 of 5

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