CRC(NZ) Perma-Mend Repair Patch

Transcription

1 R(NZ) Perma-Mend Repair Patch R Industries (R Industries New Zealand) hemwatch Hazard Alert ode: 2 hemwatch: Version No: Safety Data Sheet according to HSNO Regulations Issue Date: 08/04/2016 Print Date: 14/07/2016 Initial Date: S.GHS.NZL.EN SETION 1 IDENTIFIATION OF THE SUBSTANE / MIXTURE AND OF THE OMPAN / UNDERTAKING Product Identifier Product name Synonyms Other means of identification R(NZ) Perma-Mend Repair Patch Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Use according to manufacturer's directions. Self-adhesive repair patch. Details of the supplier of the safety data sheet Registered company name Address R Industries (R Industries New Zealand) 10 Highbrook Drive Auckland East Tamaki New Zealand Telephone Fax Website customerservices@crc.co.nz Emergency telephone number Association / Organisation Emergency telephone numbers Other emergency telephone numbers SETION 2 HAZARDS IDENTIFIATION lassification of the substance or mixture onsidered a Hazardous Substance according to the criteria of the New Zealand Hazardous Substances New Organisms legislation. Not regulated for transport of Dangerous Goods. HEMWATH HAZARD RATINGS Flammability 1 Toxicity 0 Body ontact 2 Reactivity 1 hronic 2 Min Max 0 = Minimum 1 = Low 2 = Moderate 3 = High 4 = Extreme lassification [1] Eye Irritation ategory 2A, Respiratory Sensitizer ategory 1, Skin Sensitizer ategory 1, arcinogenicity ategory 2 Legend: Determined by hemwatch using GHS/HSNO criteria 1. lassified by hemwatch; 2. lassification drawn from ID EPA NZ ; 3. lassification drawn from E Directive 1272/ Annex VI 6.4A, 6.5A (respiratory), 6.5B (contact), 6.7B Label elements

2 GHS label elements SIGNAL WORD DANGER Hazard statement(s) H319 H334 H317 H351 auses serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. Suspected of causing cancer. Precautionary statement(s) Prevention P201 P261 P280 P281 Obtain special instructions before use. Avoid breathing dust/fumes. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Precautionary statement(s) Response P304+P340 P308+P313 P342+P311 P363 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF exposed or concerned: Get medical advice/attention. If experiencing respiratory symptoms: all a POISON ENTER or doctor/physician. Wash contaminated clothing before reuse. Precautionary statement(s) Storage P405 Store locked up. Precautionary statement(s) Disposal P501 Dispose of contents/container in accordance with local regulations. SETION 3 OMPOSITION / INFORMATION ON INGREDIENTS Substances See section below for composition of Mixtures Mixtures AS No %[weight] Name mineral fillers fiberglass polyester resin <1 styrene SETION 4 FIRST AID MEASURES NZ Poisons entre 0800 POISON ( ) NZ Emergency Services: 111 Description of first aid measures Eye ontact Skin ontact Inhalation Ingestion If this product comes in contact with the eyes: Wash out immediately with fresh running water. Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. Seek medical attention without delay; if pain persists or recurs seek medical attention. Removal of contact lenses after an eye injury should only be undertaken by skilled personnel. If skin contact occurs: Immediately remove all contaminated clothing, including footwear. Flush skin and hair with running water (and soap if available). Seek medical attention in event of irritation. If fumes, aerosols or combustion products are inhaled remove from contaminated area. Other measures are usually unnecessary. Immediately give a glass of water. First aid is not generally required. If in doubt, contact a Poisons Information entre or a doctor.

3 Indication of any immediate medical attention and special treatment needed Treat symptomatically. SETION 5 FIREFIGHTING MEASURES Extinguishing media Water spray or fog. Alcohol stable foam. Dry chemical powder. arbon dioxide. Special hazards arising from the substrate or mixture Fire Incompatibility Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition may result Advice for firefighters Fire Fighting Fire/Explosion Hazard Alert Fire Brigade and tell them location and nature of hazard. Wear breathing apparatus plus protective gloves. Prevent, by any means available, spillage from entering drains or water courses. Use water delivered as a fine spray to control fire and cool adjacent area. ombustible. Slight fire hazard when exposed to heat or flame. Heating may cause expansion or decomposition leading to violent rupture of containers. On combustion, may emit toxic fumes of carbon monoxide (O). May emit poisonous fumes. May emit corrosive fumes. SETION 6 AIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Minor Spills Major Spills lean up waste regularly and abnormal spills immediately. Avoid breathing dust and contact with skin and eyes. Wear protective clothing, gloves, safety glasses and dust respirator. Use dry clean up procedures and avoid generating dust. Moderate hazard. AUTION: Advise personnel in area. Alert Emergency Services and tell them location and nature of hazard. ontrol personal contact by wearing protective clothing. Personal Protective Equipment advice is contained in Section 8 of the SDS. SETION 7 HANDLING AND STORAGE Precautions for safe handling Safe handling Other information Avoid all personal contact, including inhalation. Wear protective clothing when risk of exposure occurs. Use in a well-ventilated area. Prevent concentration in hollows and sumps. Store in original containers. Keep containers securely sealed. Store in a cool, dry area protected from environmental extremes. Store away from incompatible materials and foodstuff containers. onditions for safe storage, including any incompatibilities Suitable container Storage incompatibility Packaging as recommended by manufacturer. heck that containers are clearly labelled Avoid reaction with oxidising agents SETION 8 EXPOSURE ONTROLS / PERSONAL PROTETION ontrol parameters OUPATIONAL EXPOSURE LIMITS (OEL) INGREDIENT DATA Source Ingredient Material name TWA STEL Peak Notes

4 New Zealand Workplace Exposure Standards (WES) styrene Styrene, monomer 213 mg/m3 / 50 ppm 426 mg/m3 / 100 ppm Skin absorption EMERGEN LIMITS Ingredient Material name TEEL-1 TEEL-2 TEEL-3 styrene Styrene Ingredient Original IDLH Revised IDLH mineral fillers fiberglass polyester resin styrene 5,000 ppm 700 ppm Exposure controls Appropriate engineering controls Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to provide this high level of protection. The basic types of engineering controls are: Process controls which involve changing the way a job activity or process is done to reduce the risk. Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation that strategically "adds" and "removes" air in the work environment. Personal protection Eye and face protection Skin protection Hands/feet protection Body protection Other protection Thermal hazards Safety glasses with side shields. hemical goggles. ontact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lenses or restrictions on use, should be created for each workplace or task. See Hand protection below NOTE: The material may produce skin sensitisation in predisposed individuals. are must be taken, when removing gloves and other protective equipment, to avoid all possible skin contact. ontaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed. The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer. Where the chemical is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. The exact break through time for substances has to be obtained from the manufacturer of the protective gloves and.has to be observed when making a final choice. Suitability and durability of glove type is dependent on usage. Experience indicates that the following polymers are suitable as glove materials for protection against undissolved, dry solids, where abrasive particles are not present. polychloroprene. nitrile rubber. butyl rubber. See Other protection below Overalls. P.V.. apron. Barrier cream. Recommended material(s) GLOVE SELETION INDEX Glove selection is based on a modified presentation of the: "Forsberg lothing Performance Index". The effect(s) of the following substance(s) are taken into account in the computer-generated selection: R(NZ) Perma-Mend Repair Patch Material PE/EVAL/PE PVA TEFLON NATURAL RUBBER PI A A A Respiratory protection Type A-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent) Required Minimum Protection Factor up to 10 x ES Half-Face Respirator A P1 Air-line* Full-Face Respirator - - Powered Air Respirator A PAPR-P1 - up to 50 x ES Air-line** A P2 A PAPR-P2 up to 100 x ES - A P3 - Air-line* x ES - Air-line** A PAPR-P3 NITRILE * - Negative pressure demand ** - ontinuous flow A(All classes) = Organic vapours, B AUS or B1 = Acid gasses, B2 = Acid

5 NITRILE+PV PV SARANEX-23 gas or hydrogen cyanide(hn), B3 = Acid gas or hydrogen cyanide(hn), E = Sulfur dioxide(so2), G = Agricultural chemicals, K = Ammonia(NH3), Hg = Mercury, NO = Oxides of nitrogen, MB = Methyl bromide, AX = Low boiling point organic compounds(below 65 deg) * PI - hemwatch Performance Index A: Best Selection B: Satisfactory; may degrade after 4 hours continuous immersion : Poor to Dangerous hoice for other than short term immersion NOTE: As a series of factors will influence the actual performance of the glove, a final selection must be based on detailed observation. - * Where the glove is to be used on a short term, casual or infrequent basis, factors such as "feel" or convenience (e.g. disposability), may dictate a choice of gloves which might otherwise be unsuitable following long-term or frequent use. A qualified practitioner should be consulted. Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures. The decision to use respiratory protection should be based on professional judgment that takes into account toxicity information, exposure measurement data, and frequency and likelihood of the worker's exposure - ensure users are not subject to high thermal loads which may result in heat stress or distress due to personal protective equipment (powered, positive flow, full face apparatus may be an option). Published occupational exposure limits, where they exist, will assist in determining the adequacy of the selected respiratory protection. These may be government mandated or vendor recommended. ertified respirators will be useful for protecting workers from inhalation of particulates when properly selected and fit tested as part of a complete respiratory protection program. Use approved positive flow mask if significant quantities of dust becomes airborne. Try to avoid creating dust conditions. SETION 9 PHSIAL AND HEMIAL PROPERTIES Information on basic physical and chemical properties Appearance Grey solid/patch with a styrene odour; not miscible with water. Physical state Solid Relative density (Water = 1) Odour Partition coefficient n-octanol / water Odour threshold Auto-ignition temperature ( ) ph (as supplied) Decomposition temperature Melting point / freezing point ( ) Viscosity (cst) Initial boiling point and boiling range ( ) Molecular weight (g/mol) Flash point ( ) 449 Taste Evaporation rate Explosive properties Flammability Oxidising properties Upper Explosive Limit (%) 6.6 Surface Tension (dyn/cm or mn/m) Lower Explosive Limit (%) 0.9 Volatile omponent (%vol) 0 Vapour pressure (kpa) 0.85 Gas group Solubility in water (g/l) Vapour density (Air = 1) Immiscible ph as a solution (1%) 3.6 VO g/l SETION 10 STABILIT AND REATIVIT Reactivity See section 7 hemical stability Possibility of hazardous reactions Unstable in the presence of incompatible materials. Product is considered stable. Hazardous polymerisation will not occur. See section 7 onditions to avoid See section 7 Incompatible materials See section 7 Hazardous decomposition products See section 5

6 SETION 11 TOXIOLOGIAL INFORMATION Information on toxicological effects Inhaled Ingestion Skin ontact Eye hronic The material is not thought to produce adverse health effects or irritation of the respiratory tract (as classified by E Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable control measures be used in an occupational setting. The material has NOT been classified by E Directives or other classification systems as "harmful by ingestion". This is because of the lack of corroborating animal or human evidence. The material is not thought to produce adverse health effects or skin irritation following contact (as classified by E Directives using animal models). Nevertheless, good hygiene practice requires that exposure be kept to a minimum and that suitable gloves be used in an occupational setting. Open cuts, abraded or irritated skin should not be exposed to this material This material can cause eye irritation and damage in some persons. Inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population. Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population. There has been concern that this material can cause cancer or mutations, but there is not enough data to make an assessment. There is some evidence from animal testing that exposure to this material may result in toxic effects to the unborn baby. R(NZ) Perma-Mend Repair Patch TOXIIT IRRITATION styrene TOXIIT dermal (rat) LD50: >2000 mg/kg [1] Inhalation (rat) L50: 11.8 mg/l/4hr [2] Inhalation (rat) L50: 24 mg/l/4hr [2] Inhalation (rat) L50: 2770 ppm/4hr [2] Oral (rat) LD50: 2650 mg/kg [2] IRRITATION Eye (rabbit): 100 mg/24h - moderate Eye (rabbit): 100 mg/24h - moderate Skin (rabbit): 500 mg - mild Skin (rabbit): 500 mg - mild Legend: 1. Value obtained from Europe EHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTES - Register of Toxic Effect of chemical Substances R(NZ) Perma-Mend Repair Patch STRENE The following information refers to contact allergens as a group and may not be specific to this product. ontact allergies quickly manifest themselves as contact eczema, more rarely as urticaria or Quincke's oedema. The pathogenesis of contact eczema involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. Other allergic skin reactions, e.g. contact urticaria, involve antibody-mediated immune reactions. Allergic reactions involving the respiratory tract are usually due to interactions between IgE antibodies and allergens and occur rapidly. Allergic potential of the allergen and period of exposure often determine the severity of symptoms. Some people may be genetically more prone than others, and exposure to other irritants may aggravate symptoms. Allergy causing activity is due to interactions with proteins. Attention should be paid to atopic diathesis, characterised by increased susceptibility to nasal inflammation, asthma and eczema. Exogenous allergic alveolitis is induced essentially by allergen specific immune-complexes of the IgG type; cell-mediated reactions (T lymphocytes) may be involved. Such allergy is of the delayed type with onset up to four hours following exposure. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the skin. WARNING: This substance has been classified by the IAR as Group 2B: Possibly arcinogenic to Humans. Acute Toxicity Skin Irritation/orrosion Serious Eye Damage/Irritation Respiratory or Skin sensitisation Mutagenicity arcinogenicity Reproductivity STOT - Single Exposure STOT - Repeated Exposure Aspiration Hazard Legend: Data available but does not fill the criteria for classification Data required to make classification available Data to make classification SETION 12 EOLOGIAL INFORMATION

7 Toxicity Ingredient Endpoint Test Duration (hr) Species Value Source styrene E50 96 Algae or other aquatic plants 0.72mg/L 4 styrene L50 96 Fish mg/L 4 styrene E10 96 Algae or other aquatic plants =0.13mg/L 1 styrene E50 48 rustacea 4.7mg/L 5 styrene NOE 168 rustacea mg/L 2 Legend: Extracted from 1. IULID Toxicity Data 2. Europe EHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. EETO Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data DO NOT discharge into sewer or waterways. Persistence and degradability Ingredient Persistence: Water/Soil Persistence: Air styrene HIGH (Half-life = 210 days) LOW (Half-life = 0.3 days) Bioaccumulative potential Ingredient Bioaccumulation styrene LOW (BF = 77) Mobility in soil Ingredient Mobility styrene LOW (KO = 517.8) SETION 13 DISPOSAL ONSIDERATIONS Waste treatment methods Product / Packaging disposal ontainers may still present a chemical hazard/ danger when empty. Return to supplier for reuse/ recycling if possible. Otherwise: If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill. Where possible retain label warnings and SDS and observe all notices pertaining to the product. Recycle wherever possible. onsult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Dispose of by: burial in a land-fill specifically licenced to accept chemical and / or pharmaceutical wastes or Incineration in a licenced apparatus (after admixture with suitable combustible material) Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed. Ensure that the disposal of material is carried out in accordance with Hazardous Substances (Disposal) Regulations SETION 14 TRANSPORT INFORMATION Labels Required Marine Pollutant HAZHEM NO Land transport (UN): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Air transport (IAO-IATA / DGR): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Sea transport (IMDG-ode / GGVSee): NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS Transport in bulk according to Annex II of MARPOL and the IB code SETION 15 REGULATOR INFORMATION Safety, health and environmental regulations / legislation specific for the substance or mixture

8 This substance is to be managed using the conditions specified in an applicable Group Standard HSR Number Group Standard HSR leaning Products (Toxic [6.7]) Group Standard 2006 HSR Laboratory hemicals and Reagent Kits Group Standard 2006 HSR Lubricants (Toxic [6.7]) Group Standard 2006 HSR Fuel Additives (Toxic [6.7]) Group Standard 2006 HSR Aerosols (Toxic [6.7]) Group Standard 2006 HSR Animal Nutritional and Animal are Products Group Standard 2006 HSR Polymers (Toxic [6.7]) Group Standard 2006 HSR Reagent Kits Group Standard 2006 HSR Metal Industry Products (Toxic [6.7]) Group Standard 2006 HSR N.O.S. (Toxic [6.1, 6.7]) Group Standard 2006 HSR Photographic hemicals (Toxic [6.7]) Group Standard 2006 HSR Additives, Process hemicals and Raw Materials (Toxic [6.7]) Group Standard 2006 HSR Dental Products (Toxic [6.7]) Group Standard 2006 HSR Embalming Products (Toxic [6.7]) Group Standard 2006 HSR Surface oatings and olourants (Toxic [6.7]) Group Standard 2006 HSR Pharmaceutical Active Ingredients Group Standard 2010 HSR Leather and Textile Products (Toxic [6.7]) Group Standard 2006 HSR Water Treatment hemicals (Toxic [6.7]) Group Standard 2006 HSR Refining atalysts Group Standard 2006 HSR orrosion Inhibitors (Toxic [6.7]) Group Standard 2006 HSR osmetic Products Group Standard 2006 HSR Veterinary Medicine (Limited Pack Size, Finished Dose) Standard 2012 HSR Veterinary Medicines (Non-dispersive losed System Application) Group Standard 2012 HSR Veterinary Medicines (Non-dispersive Open System Application) Group Standard 2012 HSR Solvents (Toxic [6.7]) Group Standard 2006 STRENE( ) IS FOUND ON THE FOLLOWING REGULATOR LISTS International Agency for Research on ancer (IAR) - Agents lassified by the IAR Monographs International Air Transport Association (IATA) Dangerous Goods Regulations - Prohibited List Passenger and argo Aircraft New Zealand Hazardous Substances and New Organisms (HSNO) Act - lassification of hemicals New Zealand Inventory of hemicals (NZIo) New Zealand Workplace Exposure Standards (WES) Location Test ertificate Subject to Regulation 55 of the Hazardous Substances (lasses 1 to 5 ontrols) Regulations, a location test certificate is required when quantity greater than or equal to those indicated below are present. Hazard lass Quantity beyond which controls apply for closed containers Approved Handler Quantity beyond which controls apply when use occurring in open containers Subject to Regulation 56 of the Hazardous Substances (lasses 1 to 5 ontrols) Regulations and Regulation 9 of the Hazardous Substances (lasses 6, 8, and 9 ontrols) Regulations, the substance must be under the personal control of an Approved Handler when present in a quantity greater than or equal to those indicated below. lass of substance Quantities Refer Group Standards for further information Tracking Requirements National Inventory Australia - AIS anada - DSL anada - NDSL hina - IES Status N (styrene)

9 Europe - EINE / ELINS / NLP Japan - ENS Korea - KEI New Zealand - NZIo Philippines - PIS USA - TSA Legend: = All ingredients are on the inventory N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see specific ingredients in brackets) SETION 16 OTHER INFORMATION Other information lassification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the hemwatch lassification committee using available literature references. A list of reference resources used to assist the committee may be found at: The SDS is a Hazard ommunication tool and should be used to assist in the Risk Assessment. Many factors determine whether the reported Hazards are Risks in the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering controls must be considered. Definitions and abbreviations P-TWA: Permissible oncentration-time Weighted Average P-STEL: Permissible oncentration-short Term Exposure Limit IAR: International Agency for Research on ancer AGIH: American onference of Governmental Industrial Hygienists STEL: Short Term Exposure Limit TEEL: Temporary Emergency Exposure Limit IDLH: Immediately Dangerous to Life or Health oncentrations OSF: Odour Safety Factor NOAEL :No Observed Adverse Effect Level LOAEL: Lowest Observed Adverse Effect Level TLV: Threshold Limit Value LOD: Limit Of Detection OTV: Odour Threshold Value BF: Biooncentration Factors BEI: Biological Exposure Index This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or criticism, as permitted under the opyright Act, no part may be reproduced by any process without written permission from HEMWATH. TEL (+61 3)