TÜRKAK TÜRK AKREDİTASYON KURUMU TURKISH ACCREDITION AGENCY tarafından akredite edilmiş

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1 TÜRKAK TÜRK AKREDİTASYON KURUMU TURKISH ACCREDITION AGENCY tarafından akredite edilmiş EKOTEKS EKOTEKS LABORATUVAR ve GÖZETİM Esenyurt Firuzköy Bulvarı No: Avcılar İstanbul/ TÜRKİYE TEST REORT DENEY RAORU Customer name: AS ERDOĞAN DERİ SAN. TİC. LTD. ŞTİ. Address: Merkez Mah. Remzi Özkaya Sok. No:10 Yenibosna/ Bahçelievler- İSTANBUL Buyer name: - Contact erson: ELİF CANDOĞAN Order No: - Article No: - Name and identity of test item: One sample of brown leather panel with cream furry part on front The date of receipt of test item: Date of test: Remarks: - Sampling: End-Use: The results given in this report belong to the received sample by vendor. Not specified Care Label: - Number of pages of the report: 7 The Turkish Accreditation Agency (TURKAK) is signatory to the multilateral agreements of the European co-operation for the Accreditation (EA) and of the International Laboratory Accreditation (ILAC) for the Mutual recognition of test reports. The test and/or measurement results, the uncertainties (if applicable) with confidence probability and test methods are given on the following pages which are part of this report. Seal Date erson in charge of test Şafak AKDENİZ Head of Testing Laboratory Sevim A. RAZAK This report shall not be reproduced other than in full except with the permission of the laboratory. Testing reports without signature and seal are not valid. age 1 / 7

2 REQUIRED TESTS COMMENTS ECOLOGICAL TEST Heavy Metal Chlorphenols Chromium VI Formaldehyde Total Lead Content Determination of hthalates Forbidden Arylamines In Dyestuff : ass F: Fail R: Refer to retailer technologist. Requirements were given by vendor. REMARK: Original samples are kept for 3 months and all technical records are kept for 5 years unless otherwise specified. The reported uncertainty is based on a standard uncertainty multiplied by a coverage factor k=2, providing a level of confidence of approximately 95 %. Tests marked (*) in this report are not included in the accreditation schedule. This report shall not be reproduced other than in full except with the permission of the laboratory. Testing reports without signature and seal are not valid. age 2 / 7

3 TEST S HEAVY METAL; DIN :2010 Extractable heavy metals are extracted at 40 C in artificial acidic perspiration solution (ph=5.5). and determined using IC-MS. (DIN E29 and ISO ) Arsenic (As) < 100 mg/kg Cadmium (Cd) < 100 mg/kg Mercury (Hg) < 100 mg/kg Nickel (Ni) < 100 mg/kg Antimony (Sb) < 100 mg/kg N.D (1) : Not detected CHLORHENOLS; ISO 17070:2006 Sample is extracted with acetone then esterificated with acidanhydrite and determined using a GC/MS. In reference to DIN and 35 LMBG :2001. Total Trichlorphenol Total Tetrachlorphenol entachlorphenol < 0.5 mg/kg < 0.5 mg/kg < 0.5 mg/kg N.D (1) : Not detected Chlorphenol Standards CAS No. Result 2,3,4-Trichlorphenol ,3,5-Trichlorphenol ,3,6-Trichlorphenol ,4,5-Trichlorphenol ,4,6-Trichlorphenol ,4,5-Trichlorphenol ,3,4,5-Tetrachlorphenol ,3,4,6-Tetrachlorphenol ,3,5,6-Tetrachlorphenol C 6 -entachlorphenol age 3 / 7

4 TEST S CHROMIUM VI; ISO (*) The sample is extracted with buffer solution. Measured by using UV-VIS Specrometer. (1) N.D.: Not detected < 3.0 mg/kg FORMALDEHYDE; ISO :2008 (*) The leather sample is eluted with detergent solution at 40 C.The eluate is treated with2.4- dinitrophenylhydrazine,whereby formaldehyde reacts to give a yellow compound The amount of formaldehyde is detected at 360 nm and quantified using by HLC. (1) N.D.: Not detected < 20 mg/kg TOTAL LEAD CONTENT; CSC CH-E :2012 Sample is digested in microwave oven. After filtration, measured by using IC-MS. (1) N.D.: Not detected < 90.0 mg/kg age 4 / 7

5 TEST S DETERMINATION OF HTHALATES; EN 14372: 2004 Test sample is extracted in suitable organic solvent in extraction device. The extract is analyzed by HLC and result is given by GC/MS. Cas No: DB/ Dibutylphthalate ( ) BB/ Butylbenzylphthalate ( ) DID/ Di-isodecylphthalate ( )/ ( ) DEH/ Di-(2-ethylhexyl) phthalate ( ) DNO/ Di-n-octylphthalate ( ) DIN/ Di-iso-nonylphthalate ( )/ ( ) DIB/ Bis iso butyl phthalate ( ) DH/Di-n-hexyl phthalate ( ) DIH/Di-C6-8-branched alkyphthalates ( ) DHNU/Di-C7-11-branched alkyphthalates ( ) DME/Di-(2-methoxyethyl) phthalate ( ) D/Di-pentylphthalate (n-, iso or mix) ( ; ; ; ) Total amount of phthalates < 0.1 % : Not detected age 5 / 7

6 TEST S FORBIDDEN AROMATIC ARYLAMINES-MAK III GROU A1&A2 CATEGORY Corresponding to the Ordinance on Commodities (Bedarfsgegenständeverordnung) be in force respectively the directive 2002/61/EEC the use of certain azo colorants is banned, which can release by reductive cleavage of their azo group(s) one or more of certain listed aromatic and cancerogenic amines. Arylamines of class MAK III A1/ A2 are determined and quantified using a Gas Chromatography / Mass Selective Detector (GC/MSD) List of arylamines,that are not allowed to be split off from dyes under reductive conditions ; Nr Substances CAS No Index No EC number MAK III A Aminobiphenyl Benzidine Chloro-o-toluidine Naphthylamine ( -Naphthylamine) MAK III A2 05* o-aminoazotoluol (4-amino-2,3-dimethylazobenzene) p-chloroaniline (4-chloroaniline) ,4-Diaminoanisole (4-Methoxy-m-phenylenediamine) ,4 -Diaminodiphenylmethane (4,4 -methylendianiline) ,3 -Dichlorbenzidine (3,3 -dichlorobiphenyl-4, xylendiamine) 10 3,3 -Dimethoxybenzidine (o-dianisidine) X ,3 -Dimethylbenzidine (o-tolidine) (4,4 -bi-o-toluidine) ,3 -Dimethyl-4,4 -diaminodiphenylmethane (4,4 -methylene di-o-toluidine) 13 4,4 -Methylene-bis-(2-chloro-aniline) (2,2 -dichloro-4, methylenedianiline) 14* 2-Amino-4-nitrotoluene (5-nitro-o-toluidine) ,4 -Oxydianiline (4,4 -Diaminodiphenylether) ,4 -Thiodianiline ( 4,4 -Diaminodiphenylsulfide) o-toluidine (2-aminotoluene) X Methyl-1,3-phenylendiamin (4-methyl-m-phenylendiamin) (2,4-Toluenediamine) 19 2,4,5-Trimethylaniline o-anisidine (2-Methoxyaniline) Methoxy-5-methylaniline (p-cresidine) (6-methoxy-mtoluidine) ** 4-Amino Azobenzene *** 2,4-Xylidine *** 2,6-Xylidine * The CAS-numbers (No. 5) and (No. 14) are detected further reduced to CAS-numbers (No. 17) and (No. 18). ** Azo colorants that are able to form 4-aminoazobenzene, generate under the condition of the below mentioned methods aniline and 1,4- phenylenediamine. For the detection of 4-aminoazobenzene the official testing methods are therefore modified. Regarding 4-aminoazobenzene (Cas No: ) : The official method is 64 LFGB September 2006 under consideration of the amendment 64 LFGB ,amendment April 2008 *** Not regulated by law Note: In case the sample was a blend of coloured synthetic material with further coloured fibers several test methods were carried out if necessary. age 6 / 7

7 TEST S Component Name Test Method Forbidden Arylamines in Dyestuff Results Conclusion Cream furry main Brown leather main DIN EN :2012 ass (without extraction) ISO :2010 ND (¹) ass ND (¹) Max. limit specified according to vendor s requirement = 30 mg/kg (individual). Interpretation: (1) N.D.: Not detected according to the analysis as carried out, azo colourants banned under the Ordinance on Commidities were not detected in the article submitted. LS.: Lack of sample. NA: Not applicable. "<" = less than 0 = Test not necessary (commodity not coloured or printed) mg/kg = milligram per kilogram ppm= part per million (mg/kg) Note : If an arylamine is listed in the test table, this means; The analytical result suggest that the commodity submitted has been manufactured or treated using azo colourant(s) which can release one or more of certain listed amines by cleavage of their azo group(s). age 7 / 7