: Alkaline Iodide Azide Solution I

Transcription

1 Date of issue: 01/10/2014 Version: 1.0 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form Product name Product code : Mixture : : LC Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : For laboratory and manufacturing use only Details of the supplier of the safety data sheet LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA USA T F info@labchem.com Emergency telephone number Emergency number : CHEMTREC: or SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Acute Tox. 4 (Dermal) H312 Skin Corr. 1A H314 Eye Dam. 1 H318 Aquatic Chronic 3 H Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS05 GHS07 : Danger : H312 - Harmful in contact with skin H314 - Causes severe skin burns and eye damage H412 - Harmful to aquatic life with long lasting effects : P260 - Do not breathe mist, vapours, spray P264 - Wash exposed skin thoroughly after handling P273 - Avoid release to the environment P280 - Wear protective gloves, protective clothing, eye protection, face protection P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P362+P364 - Take off contaminated clothing and wash it before reuse P405 - Store locked up P501 - Dispose of contents/container to comply with local, state and federal regulations 2.3. Other hazards Other hazards not contributing to the classification 2.4. Unknown acute toxicity (GHS-US) No data available : None under normal conditions. 01/10/2014 EN (English) Page 1

2 SECTION 3: Composition/information on ingredients 3.1. Substance Full text of H-phrases: see section Mixture Name Product identifier % GHS-US classification Water (CAS No) Not classified Sodium Hydroxide (CAS No) Acute Tox. 4 (Dermal), H312 Skin Corr. 1A, H314 Eye Dam. 1, H318 Aquatic Acute 3, H402 Potassium Iodide (CAS No) Eye Irrit. 2B, H320 Sodium Azide (CAS No) Acute Tox. 2 (Oral), H300 Acute Tox. 1 (Dermal), H310 Aquatic Acute 1, H400 Aquatic Chronic 1, H410 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). : Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. : Immediately call a POISON CENTER or doctor/physician. Wash with plenty of soap and water. Wash contaminated clothing before reuse. Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. : Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER or doctor/physician Most important symptoms and effects, both acute and delayed Symptoms/injuries : Causes severe skin burns and eye damage. Symptoms/injuries after skin contact : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. Symptoms/injuries after eye contact : Causes serious eye damage Indication of any immediate medical attention and special treatment needed Obtain medical assistance. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media Unsuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. : Do not use a heavy water stream Special hazards arising from the substance or mixture Reactivity : Thermal decomposition generates : Corrosive vapours Advice for firefighters Firefighting instructions Protection during firefighting : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures For non-emergency personnel Protective equipment Emergency procedures For emergency responders Protective equipment Emergency procedures : Protective goggles. Protective clothing. Gloves. : Evacuate unnecessary personnel. : Equip cleanup crew with proper protection. : Ventilate area. 01/10/2014 EN (English) 2/9

3 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Do not breathe mist, vapours, spray. Avoid contact during pregnancy/while nursing. : Wash exposed skin thoroughly after handling Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : incompatible materials. Keep container closed when not in use. Incompatible products : Strong oxidizers. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: lead. copper Specific end use(s) SECTION 8: Exposure controls/personal protection 8.1. Control parameters USA ACGIH ACGIH TWA (ppm) 0.01 ppm Inhalable fraction USA ACGIH ACGIH Ceiling (mg/m³) 0.29 mg/m³ USA ACGIH ACGIH Ceiling (ppm) 0.11 ppm USA ACGIH ACGIH Ceiling (mg/m³) 2 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 2 mg/m³ 8.2. Exposure controls Appropriate engineering controls Personal protective equipment Hand protection Eye protection Skin and body protection Respiratory protection Other information : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Ensure adequate ventilation. : Avoid all unnecessary exposure. : Wear protective gloves. : Chemical goggles or face shield. : Wear suitable protective clothing. : Wear appropriate mask. : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Colourless. Odour : None. Odour threshold ph 01/10/2014 EN (English) 3/9

4 Relative evaporation rate (butylacetate=1) Melting point Freezing point Boiling point Flash point Self ignition temperature Decomposition temperature Flammability (solid, gas) Vapour pressure Relative vapour density at 20 C Relative density Density Solubility Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidising properties Explosive limits : 1.4 g/ml : Soluble in water Other information SECTION 10: Stability and reactivity Reactivity Thermal decomposition generates : Corrosive vapours Chemical stability Stable under normal conditions Possibility of hazardous reactions Reacts violently with acids Conditions to avoid Direct sunlight. Extremely high or low temperatures Incompatible materials Strong acids. Strong oxidizers Hazardous decomposition products Iodine vapour. Nitrogen oxides. Thermal decomposition generates : Corrosive vapours. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity LD50 oral rat LD50 dermal rat LD50 oral rat LD50 dermal rabbit LD50 oral rat LD50 dermal rabbit : Harmful in contact with skin mg/kg 1347 mg/kg 27 mg/kg 20 mg/kg mg/kg 1350 mg/kg (Rabbit; Literature,Rabbit; Literature) 01/10/2014 EN (English) 4/9

5 Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity (single exposure) : Causes severe skin burns and eye damage. : Causes serious eye damage. Specific target organ toxicity (repeated exposure) Aspiration hazard Potential Adverse human health effects and symptoms Symptoms/injuries after skin contact Symptoms/injuries after eye contact SECTION 12: Ecological information Toxicity Ecology - water EC50 Daphnia 1 LC50 fishes 1 EC50 Daphnia 1 : Based on available data, the classification criteria are not met. Harmful in contact with skin. : Repeated exposure to this material can result in absorption through skin causing significant health hazard. Harmful in contact with skin. : Causes serious eye damage. : Harmful to aquatic life with long lasting effects. 420 mg/l 3200 mg/l 120 h 2.7 mg/l 24 h LC50 fishes mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) LC50 other aquatic organisms mg/l (96 h) EC50 Daphnia mg/l (48 h; Daphnia pulex) EC50 other aquatic organisms mg/l (Protozoa; Toxicity test) LC50 fish mg/l (96 h; Lepomis macrochirus) TLM fish ppm (24 h; Lepomis macrochirus) Threshold limit other aquatic organisms ,96 h LC50 fishes mg/l (96 h; Salmo gairdneri (Oncorhynchus mykiss); Solution >=50%) EC50 Daphnia mg/l (48 h; Ceriodaphnia sp.; Nominal concentration) LC50 fish mg/l (48 h; Leuciscus idus) TLM fish 1 99 mg/l (48 h; Lepomis macrochirus) TLM fish ppm (96 h; Gambusia affinis) Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) May cause long-term adverse effects in the environment. Biodegradability: not applicable. 01/10/2014 EN (English) 5/9

6 Biochemical oxygen demand (BOD) Chemical oxygen demand (COD) ThOD BOD (% of ThOD) Biodegradability: not applicable. No (test)data on mobility of the substance available Not bioaccumulative. Bioaccumulation: not applicable Mobility in soil Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations Ecology - waste materials SECTION 14: Transport information : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to comply with local, state and federal regulations. : Avoid release to the environment. In accordance with DOT Transport document description : UN1824 Sodium hydroxide solution, 8, II UN-No.(DOT) : 1824 DOT NA no. : UN1824 DOT Proper Shipping Name : Sodium hydroxide solution Department of Transportation (DOT) Hazard : 8 - Class 8 - Corrosive material 49 CFR Classes Hazard labels (DOT) : 8 - Corrosive Packing group (DOT) : II - Medium Danger 01/10/2014 EN (English) 6/9

7 DOT Special Provisions (49 CFR ) : B2 - MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized. IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kpa at 50 C (1.1 bar at 122 F), or 130 kpa at 55 C (1.3 bar at 131 F) are authorized. N34 - Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. T (d)(2) Normal (d)(3) TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the following: (image) Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions may be calculated using the formula: (image) Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively. DOT Packaging Exceptions (49 CFR 173.xxx) : 154 DOT Packaging Non Bulk (49 CFR 173.xxx) : 202 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Quantity Limitations Passenger aircraft/rail : 1 L (49 CFR ) DOT Quantity Limitations Cargo aircraft only (49 : 30 L CFR ) DOT Vessel Stowage Location : A - The material may be stowed on deck or under deck on a cargo vessel and on a passenger vessel. DOT Vessel Stowage Other : 52 - Stow separated from acids Additional information Other information : No supplementary information available. ADR Transport document description : Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's 1000 lb List of Lists) : SARA Section 302 Threshold Planning 1000 lb Quantity (TPQ) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's 1000 lb List of Lists) : SARA Section 311/312 Hazard Classes Immediate (acute) health hazard 01/10/2014 EN (English) 7/9

8 15.2. International regulations CANADA WHMIS Classification Class E - Corrosive Material Listed on the Canadian DSL (Domestic Sustances List) inventory. WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects WHMIS Classification Uncontrolled product according to WHMIS classification criteria Listed on the Canadian DSL (Domestic Sustances List) inventory. WHMIS Classification Class E - Corrosive Material EU-Regulations Classification according to Regulation (EC) No. 1272/2008 [CLP] Classification according to Directive 67/548/EEC or 1999/45/EC Not classified National regulations Listed on the Canadian Ingredient Disclosure List Listed on the Canadian Ingredient Disclosure List US State regulations SECTION 16: Other information Other information : None. Full text of H-phrases: see section 16: Acute Tox. 1 (Dermal) Acute toxicity (dermal), Category Acute Tox. 2 (Oral) Acute toxicity (oral), Category Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category Aquatic Acute 1 Hazardous to the aquatic environment AcuteHazard, Category Aquatic Acute 3 Hazardous to the aquatic environment AcuteHazard, Category Aquatic Chronic 1 Hazardous to the aquatic environment Chronic Hazard, Category Aquatic Chronic 3 Hazardous to the aquatic environment Chronic Hazard, Category Eye Dam. 1 Serious eye damage/eye irritation, Category Eye Irrit. 2B Serious eye damage/eye irritation, Category 2B Skin Corr. 1A Skin corrosion/irritation, Category 1A H300 Fatal if swallowed H310 Fatal in contact with skin H312 Harmful in contact with skin H314 Causes severe skin burns and eye damage 01/10/2014 EN (English) 8/9

9 H318 Causes serious eye damage H320 Causes eye irritation H400 Very toxic to aquatic life H402 Harmful to aquatic life H410 Very toxic to aquatic life with long lasting effects H412 Harmful to aquatic life with long lasting effects NFPA health hazard NFPA fire hazard NFPA reactivity : 3 - Short exposure could cause serious temporary or residual injury even though prompt medical attention was given. : 0 - Materials that will not burn. : 1 - Normally stable, but can become unstable at elevated temperatures and pressures or may react with water with some release of energy, but not violently. HMIS III Rating Health Flammability Physical Personal Protection : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given : 0 Minimal Hazard : 1 Slight Hazard : H SDS US (GHS HazCom 2012) Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. 01/10/2014 EN (English) 9/9