Material Safety Data Sheet

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1 Supplier: Permatex, Inc. 10 Columbus Blvd. Hartford, CT Telephone: 1-87-Permatex (877) Material Safety Data Sheet 1. PRODUCT IDENTIFICATION Product Name: Product Type: G Epoxy adhesive 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients Percent ACGIH 8 Hr. TWA: OSHA 8 Hr. TWA: BISPHENOL A-(EPICHLORHYDRIN) {REACTION PRODUCT} EPOXY RESIN EPOXY RESIN EPOXY RESIN HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Medical Conditions Recognized as Being Aggravated by Exposure: May cause eye and skin irritation. Possible sensitizer. Eye and skin contact, ingestion, inhalation. Repeated skin contact may cause allergic skin reactions. Heated vapors may cause headache, nausea, dizziness or respiratory irritation. Overexposure may cause eye and skin redness. Allergy, eczema, skin conditions. 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Eye Contact: If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention. If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Remove contaminated clothing. Wash area with soap and water. If irritation persists, seek medical attention. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. 5. FIRE FIGHTING MEASURES Flash Point ( F/C): Recommended Extinguishing Media: Special Fire-Fighting Procedures: Unusual Fire/Explosion Hazards: Lower Explosive Limit: Upper Explosive Limit: More than 200 degrees F. Method: Tag Closed Cup Carbon Dioxide, Dry Chemicals, Foam. Firefighters should wear self-contained breathing apparatus. Hydrogen chloride. Aldehydes, Oxides of carbon. Phenolics 6. ACCIDENTAL RELEASE MEASURES Spill Procedures: Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. Page 1 of 3

2 190528G 7. HANDLING AND STORAGE Storage: Store below 100 degrees F. Handling: Avoid prolonged skin contact. Keep away from eyes. Do not inhale vapors. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Skin: Ventilation: Respiratory Protection: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Water white to amber liquid Odor: MILD Boiling Point ( F): More than 300 degrees F. ph: Does not apply Solubility in Water: Slight Specific Gravity: VOC Content(Wt.%): 0.76% by weight; 8.75 g/l Vapor Pressure: Less than 5 mm Hg Vapor Density (Air=1): Evaporation Rate: 10. STABILITY AND REACTIVITY Chemical Stability: Hazardous Polymerization: Incompatabilities: Conditions to Avoid: 11. TOXICOLOGICAL INFORMATION See Section ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended Method of Disposal: US EPA Waste Number: 14. TRANSPORT INFORMATION DOT (49CFR 172) Domestic Ground Transport DOT Shipping Name: UN/ID Number: Marine Pollutant: IATA Proper Shipping Name: Class or Division: UN/NA Number: IMDG Proper Shipping: UN Number: Safety glasses or goggles. Rubber or plastic gloves General; local exhaust ventilation as necessary to control any air contaminants to within their exposure limits during the use of this product. An approved respirator (i.e. NIOSH, etc.) should be worn when exposures are expected to exceed the applicable limits. Stable at normal conditions WILL NOT OCCUR Oxidizing agents, bases, acids, amines, mercaptans. High temperatures. Hydrogen chloride. Aldehydes, Oxides of carbon. Phenolics Disposal should be made in accordance with federal, state and local regulations. NH - Not a RCRA Hazardous Waste Material Page 2 of 3

3 190528G 15. REGULATORY INFORMATION SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. CALIFORNIA PROP 65: WARNING: This product contains a chemical known to the State of California to cause cancer. TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION Estimated NFPA Rating: HEALTH 1, FLAMMABILITY 1, REACTIVITY 0 Estimated HMIS Classification: HEALTH 1, FLAMMABILITY 1, PHYSICAL HAZARD 0 NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Denise Boyd Health and Safety Manager Company: Permatex. Inc. 10 Columbus Blvd. Hartford, CT Telephone Number: 1-87-Permatex (877) Revision Date: 03/02/2001 Revision Number: 1 Page 3 of 3

4 Supplier: Permatex, Inc. 10 Columbus Blvd. Hartford, CT Telephone: 1-87-Permatex (877) Material Safety Data Sheet 1. PRODUCT IDENTIFICATION Product Name: Product Type: G Epoxy hardener 2. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients Percent ACGIH 8 Hr. TWA: OSHA 8 Hr. TWA: POLYMERCAPTAN MIXTURE 2,4,6- TRIS(DIMETHYLAMINOMETHYL)P HENOL NONYLPHENOL HEPTAKIS (DISPROPYLENEGLYCOL) - TRIPHOSPHITE HAZARDS IDENTIFICATION Toxicity: Primary Routes of Entry: Signs and Symptoms of Exposure: Medical Conditions Recognized as Being Aggravated by Exposure: May cause eye, skin and respiratory irritation. The aminophenol can cause severe irritation and may be corrosive on prolonged contact. It may be a sensitizer. It can also be corrosive to eye tissue, leading to permanent injury including blindness. It may irritate the respiratory tract and may cause delayed lung damage upon overexposure to fumes or vapors. It can cause fatigue, muscular weakness, labored breathing or gastrointestinal irritation if swallowed. The relatively low concentration of the aminophenol in the product may minimize some or all of these effects. Eye and skin contact, ingestion, inhalation. Repeated skin contact may cause allergic skin reactions. Inhaling may cause mild irritation to the nose, throat and respiratory tract and may result in central nervous system (CNS) depression. Moderately toxic if swallowed. Irritating to mouth, throat and stomach with nausea. It is possible that irritation may be severe and lead to burns. Preexisting eye, skin and respiratory disorders may be aggravated by overexposure to this product. 4. FIRST AID MEASURES Ingestion: Inhalation: Skin Contact: Eye Contact: If swallowed, DO NOT induce vomiting. Keep individual calm. Obtain medical attention. If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical attention. Remove contaminated clothing. Wash area with soap and water. If irritation persists, seek medical attention. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes and get medical attention if irritation persists. 5. FIRE FIGHTING MEASURES Flash Point ( F/C): Recommended Extinguishing Media: Special Fire-Fighting Procedures: More than 200 degrees F. Method: Tag Closed Cup Carbon Dioxide, Dry Chemicals, Foam. Firefighters should wear self-contained breathing apparatus. Oxides of carbon. Oxides of sulfur, Oxides of nitrogen, Oxides of phosphorus. Phenol. Hydrogen sulfide, Phosphines Page 1 of 3

5 390212G Unusual Fire/Explosion Hazards: Lower Explosive Limit: Upper Explosive Limit: 6. ACCIDENTAL RELEASE MEASURES Spill Procedures: 7. HANDLING AND STORAGE Maintain good ventilation. Take up with an inert absorbent. Store in a closed waste container until disposal. Storage: Store below 100 degrees F. Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Eyes: Skin: Ventilation: Respiratory Protection: 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear viscous liquid Odor: DISAGREEABLE Boiling Point ( F): Greater than 300 degrees F. ph: Does not apply Solubility in Water: Slight Specific Gravity: 1.08 VOC Content(Wt.%): 11.08% by weight; g/l Vapor Pressure: Less than 5 mm Hg Vapor Density (Air=1): Evaporation Rate: 10. STABILITY AND REACTIVITY Chemical Stability: Hazardous Polymerization: Incompatabilities: Conditions to Avoid: 11. TOXICOLOGICAL INFORMATION See Section ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended Method of Disposal: US EPA Waste Number: 14. TRANSPORT INFORMATION DOT (49CFR 172) Domestic Ground Transport DOT Shipping Name: UN/ID Number: Marine Pollutant: Safety glasses or goggles. Rubber or plastic gloves General ventilation is usually adequate. An approved respirator (i.e. NIOSH, etc.) should be worn when exposures are expected to exceed the applicable limits. Stable at normal conditions WILL NOT OCCUR Strong oxidizers, epoxy/amine mixtures; possibly acids, peroxides, acetaldehyde, caustics. High temperatures. Oxides of carbon. Oxides of sulfur, Oxides of nitrogen, Oxides of phosphorus. Phenol. Hydrogen sulfide, Phosphines Disposal should be made in accordance with federal, state and local regulations. NH - Not a RCRA Hazardous Waste Material Page 2 of 3

6 390212G IATA Proper Shipping Name: Class or Division: UN/NA Number: IMDG Proper Shipping: UN Number: 15. REGULATORY INFORMATION SARA 313 Chemicals: The following component(s) is listed as a SARA Section 313 Toxic Chemical. CALIFORNIA PROP 65: No California Prop 65 chemicals are known to be present. TSCA Inventory Status: All components of this product are listed (or exempt) on the EPA TSCA inventory. 16. OTHER INFORMATION Estimated NFPA Rating: HEALTH 2, FLAMMABILITY 1, REACTIVITY 0 Estimated HMIS Classification: HEALTH 2, FLAMMABILITY 1, PHYSICAL HAZARD 0 NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Denise Boyd Health and Safety Manager Company: Permatex. Inc. 10 Columbus Blvd. Hartford, CT Telephone Number: 1-87-Permatex (877) Revision Date: 03/02/2001 Revision Number: 1 Page 3 of 3

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