Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 0 Health Hazard Fire Hazard 0 See Section 5. Section. Chemical Product and Company Identification Page Number: Common Name/ Trade Name Manufacturer Commercial Name(s) Synonym Chemical Name Chemical Family Chemical Formula Supplier Sorbitan monooleate SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA SPAN 80, Arlacel 80, Sorbitan O Sorbitan oleate; Sorbitan monooleic acid ester Sorbitan Monooleate C24H44O6 SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA Catalog Number(s). CAS# RTECS CI# CALL (30) YY902, SPA83, SPA WG TSCA T S C A 8 ( b ) i n v e n t o r y : Sorbitan monooleate IN CASE OF EMERGENCY CHEMTREC (24hr) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight ) Sorbitan monooleate Toxicological Data on Ingredients Section 3. Hazards Identification Potential Acute Health Effects Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Potential Chronic Health Effects CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: Repeated or prolonged exposure is not known to aggravate medical condition.

2 Sorbitan monooleate Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 5 minutes. WARM water MUST be used. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Inhalation Serious Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion Serious Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt or waistband. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances May be combustible at high temperature. OPEN CUP: >48.89 C (300 F). These products are carbon oxides (CO, CO2). Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks. Explosion Hazards in Presence of Various Substances Risks of explosion of the product in presence of mechanical impact: Risks of explosion of the product in presence of static discharge: Fire Fighting Media and Instructions Fire Hazards Explosion Hazards SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Section 6. Accidental Release Measures Small Spill Large Spill Absorb with an inert material and put the spilled material in an appropriate waste disposal. Absorb with an inert material and put the spilled material in an appropriate waste disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Do not breathe gas/fumes/ vapor/spray. Keep away from incompatibles such as oxidizing agents. Keep container tightly closed. Keep container in a cool, well-ventilated area.

3 Sorbitan monooleate Page Number: 3 Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Safety glasses. Synthetic apron or lab coat. Gloves (impervious). Respiratory protection is not normally needed if engineering controls provide for adequate ventilation. Respiratory protection is not necessary for normal handling. Good room ventilation or use of local exhaust (fume hood) is sufficient. Use a vapor respirator under conditions where exposure to the substance is apparent (e.g. generation of high concentrations of mist or vapor, inadequate ventilation, development of respiratory tract irritation), and engineering controls are not feasible. Be sure to use an approved/certified respirator or equivalent. Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Section 9. Physical and Chemical Properties Physical state and appearance Liquid. Odor Molecular Weight ph (% soln/water) g/mole Taste Color Amber. Yellow. Boiling Point >00 C (22 F) Melting Point Critical Temperature Specific Gravity (Water = ) Vapor Pressure Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Dispersed in cold water. Solubility Very slightly soluble in diethyl ether. Insoluble in cold water, acetone. Soluble in most mineral, vegetable oils, ethyl acetate, 3-etehyoxyethanol, contonseed oil. Insoluble in ethylene glycol, propylene glycol. Slightly soluble in low alohols, diethyl ether,,4-dioxane,,,-trichloroethylene. Section 0. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Heat, incompatible materials Reactive with oxidizing agents. Non-corrosive in presence of glass. Corrosivity

4 Sorbitan monooleate Page Number: 4 Polymerization Will not occur. Section. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Absorbed through skin. Eye contact. LD50: LC50: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. May affect genetic material (mutagenic) Acute Potential Health Effects: Skin: It may cause slight skin irritation, although. It probably will not be absorbed through the skin. Eyes: It may cause slight eye irritation, although no irritation is likely to develop following contact with human eyes. Inhalation: No irritation is expected to be associated with inhalation of this material. No toxic effects are known to be associated with inhalation of vapors from this material. Ingestion: This material is not likely to cause irritation upon ingestion. No toxic effects are expected following acute ingestion of this product. Chronic Potential Health Effects: Ingestion: According to the Registery of Toxic Effects of Chemical Substances (RTECS), prolonged or repeated ingestion may affect the liver (liver enlargement), urinary system (increased kidney weight, and tubular changes of uncertain pathological significance), and blood (pigmented or nucleated red blood cells) Section 2. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The product itself and its products of degradation are not toxic. Section 3. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 4. Transport Information DOT Classification Identification Not a DOT controlled material (United States). Special Provisions for Transport DOT

5 Sorbitan monooleate Page Number: 5 Section 5. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations TSCA 8(b) inventory: Sorbitan monooleate California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No ). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. Other Classifications WHMIS (Canada) Not controlled under WHMIS (Canada). DSCL (EEC) This product is not classified according to the EU regulations. HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 0 C National Fire Protection Association (U.S.A.) Health 0 Flammability Specific hazard WHMIS (Canada) DSCL (Europe) TDG (Canada) ADR (Europe) Protective Equipment Gloves (impervious). Lab coat. Safety glasses.

6 Sorbitan monooleate Page Number: 6 Section 6. Other Information MSDS Code References Other Special Considerations S4625 Validated by Sonia Owen on 2/3/202. Verified by Sonia Owen. Printed 2/3/202. CALL (30) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein.