MATERIAL SAFETY DATA SHEET

Transcription

1 MATERIAL SAFETY DATA SHEET Print date: 1. PRODUCT AND COMPANY IDENTIFICATION Item Number: FF , FF Revision Date:. Formula Number: , Article code(s) and Size: Lemon Fresh Powder 50oz UPC: Lemon Fresh Powder 75oz UPC: Lemon Fresh Powder 100oz UPC: Orange Fresh Powder 75oz UPC: Product Description: Manufacturer Emergency Telephone Number: Transportation Emergencies: Automatic dishwasher detergent (powder) Reckitt Benckiser Inc. Morris Corporate Center IV 399 Interpace Parkway (P.O. Box 225) Parsippany, New Jersey (U.S.) (U.S. & Canada) CHEMTREC Outside U.S. and Canada (North America), call Chemtrec: COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-Number Proportion (% w/w) ACGIH - Occupational Exposure Limits - TWAs OSHA PEL SODIUM CARBONATE PENTASODIUM TRIPHOSPHATE SODIUM SILICATE Sodium Dichloroisocyanurate Dihydrate % None None % None None 1-5 % None None < 2.5 % None None Page 1 of 7

2 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW CAUTION: HARMFUL IF SWALLOWED EYE IRRITANT SKIN IRRITANT WARNING: DO NOT use together with other products. May release dangerous gases. (Chlorine). KEEP OUT OF REACH OF CHILDREN 4. FIRST AID MEASURES Skin Contact Eye Contact Inhalation Ingestion Protection of First-aiders Aggravated Medical Conditions: Wash off immediately with soap and plenty of water removing all contaminated clothes and shoes If skin irritation persists, call a physician. Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes Keep eye wide open while rinsing If symptoms develop or persist, call a physician Move to fresh air. Clean mouth with water and afterwards drink plenty of water Call a physician or Poison Control Center immediately Do not induce vomiting without medical advice Never give anything by mouth to an unconscious person Use personal protective equipment 5. FIRE-FIGHTING MEASURES Flash point ( C): Flammability Limits in Air: Lower Upper Autoignition Temperature: Suitable Extinguishing Media: Extinguishing Media which must not be used for safety reasons: Specific hazards: Unusual hazards: Special Protective Equipment for Fire Fighters: Precautions for Fire Fighters: As suitable for surrounding fire. None known. As in any fire, wear self-contained breathing apparatus, pressure-demand, MSHA / NIOSH (approved or equivalent) and full protective gear. Standard procedure for chemical fires. Page 2 of 7

3 NFPA: Health Hazard 2 Flammability 0 Instability: 0 HMIS: Health Hazard 2 Flammability: 0 Physical Hazard: 0 Key: (Also see Sections 3 & 8) 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions: Methods for Cleaning Up Use personal protective equipment. Prevent product from entering drains. Local authorities should be advised if significant spillages cannot be contained. Take up mechanically and collect in suitable container for disposal Avoid dust formation Clean contaminated surface thoroughly After cleaning, flush away traces with water 7. HANDLING AND STORAGE Handling Storage Safe Handling Advice: Keep out of the reach of children. Keep in properly labeled containers. Keep containers tightly closed in a cool, well-ventilated place. Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Avoid dust formation. STORAGE Conditions for Safe Storage: Keep containers dry and tightly closed to avoid moisture absorption and contamination. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Engineering Controls: For occupational exposures, ensure adequate ventilation. Personal Protection Eye/Face Protection Hand Protection Skin and Body Protection: Eye Protection: Hygiene Measures: If splashes are likely to occur, wear: Safety glasses with side-shields Long sleeved clothing Impervious gloves Usual safety precautions while handling the product will provide adequate protection against injury or irritation. Follow product label instructions. Safety glasses. Avoid contact with eyes, skin, and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour: Odour Solid. Granular. Powder. perfumed, typical to meet the Tradename descriptor Page 3 of 7

4 ph VALUE 9. PHYSICAL AND CHEMICAL PROPERTIES 10.8 (10 % in water) Flash Point: Not applicable Autoignition Temperature: Specific gravity [g/l]: Vapour Pressure: Not determined. Solubility: Explosion limits: - upper: No data available. - lower: No data available. 10. STABILITY AND REACTIVITY Stability: Polymerization: Hazardous Decomposition Products: Materials to Avoid: Conditions to Avoid: Stable under recommended storage conditions. Hazardous polymerisation does not occur. Oxides of carbon and unknown organic compounds. Do not mix with other household chemicals. Store away from excessive heat and moisture. 11. TOXICOLOGICAL INFORMATION PRODUCT TOXICITY DATA LD50 Oral: LD50 Dermal: LC50 Inhalation (Dust): LC50 Inhalation (Vapor): > 4000 mg/kg (rat) No information available No information available No information available Acute Effects: Eye Irritation Skin Irritation Inhalation Ingestion Sensitization Chronic Effects: Irritating to eyes. Irritating to skin and mucous membranes None expected during normal conditions of use. Health injuries are not known or expected under normal use. Not expected to be a skin sensitiser Specific Effects Carcinogenic Effects: Mutagenic Effects Reproductive Toxicity: Additional Toxicity Information: Not listed as carcinogenic by OSHA, NTP or IARC. Information is based on available component data and toxicity result of similar products. COMPONENT TOXICITY DATA Chemical Name LD50 Oral - With Units - Rat - mg/kg LD50 Dermal - With Units - Rat/Rabbit - mg/kg Page 4 of 7

5 Chemical Name LD50 Oral - With Units - Rat - mg/kg LD50 Dermal - With Units - Rat/Rabbit - mg/kg SODIUM CARBONATE mg/kg ( Rat ) - PENTASODIUM TRIPHOSPHATE mg/kg ( Rat ) 7940 mg/kg ( Rabbit ) SODIUM SILICATE mg/kg ( Rat ) - Sodium Dichloroisocyanurate Dihydrate mg/kg ( Rat ) ECOLOGICAL INFORMATION PRODUCT TOXICITY DATA Aquatic toxicity: Component Information Sodium Sulfate Ecotoxicity:= 13 mg/l 96 Hr LC50 bluegill sunfish (Static) = mg/l 24 Hr LC50 fathead minnow = mg/l 96 Hr LC50 mosquito fish = 4547 mg/l 96 Hr LC50 water flea Sodium Carbonate Ecotoxicity:= 320 mg/l LC50 bluegill 96 h Static Sodium Tripolyphosphate Ecotoxicity:No test data on the actual product Sodium Silicate Ecotoxicity:No test data on the actual product Sodium Dichloroisocyanurate Dihydrate Ecotoxicity: = 0.28 mg/l LC50 Lepomis macrochirus 9g h Static = 0.18 mg/l 48 Hr EC50 Daphnia Magna Nonionic Ecotoxicity:No test data on the actual product Other Information Ozone Depletion Potential (ODP) (R-11 = 1): Global Warming Potential (GWP): Additional Ecological Information: 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Contaminated Packaging: Dispose of in accordance with local regulations. Empty container can be disposed of as household trash or rinsed and recycled where appropriate. 14. TRANSPORT INFORMATION DOT Not regulated TDG Page 5 of 7

6 MEX ICAO IATA IMDG/IMO RID ADR ADN 14. TRANSPORT INFORMATION Not regulated 15. REGULATORY INFORMATION Chemical Name TSCA DSL CHINA AICS EINECS/EL INCS No. SODIUM CARBONATE Present X X X PENTASODIUM TRIPHOSPHATE Present X X X SODIUM SILICATE Present X X X Sodium Dichloroisocyanurate Dihydrate Present X X X U.S. Regulations: SODIUM CARBONATE New Jersey Right To Know Not Listed. PENTASODIUM TRIPHOSPHATE New Jersey Right To Know Not Listed. SODIUM SILICATE New Jersey Right To Know Not Listed. Sodium Dichloroisocyanurate Dihydrate New Jersey Right To Know Anhydrate Listed. sn 1694 WHMIS (Canada) WHMIS Hazard Class D2B Toxic materials 16. OTHER INFORMATION National Fire Protection Association (U.S.A.): HMIS (U.S.A.): Health Hazard 2 Fire Hazard 0 Reactivity 0 PERSONAL PROTECTION D Reason for revision: New product Page 6 of 7

7 Prepared by: Regulatory, Safety and Environmental Services RSE Dishwashing Reckitt Benckiser Produktions GmbH Benckiserplatz 1 D Ludwigshafen am Rhein Germany Phone: +49 (0) Fax: +49 (0) Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Page 7 of 7