Material Safety Data Sheet acc. to ISO/DIS 11014

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1 Page 1/6 1 Identification of the substance/mixture and of the company/undertaking Product details Article number: 2004 Application of the substance / the preparation Halogen-free solvent for dry cleaning in SYSTEMK4 (patent pending) Manufacturer/Supplier: Manufacturer: Chemische Fabrik Kreussler & Co. GmbH Postfach D Wiesbaden Supplier: Kreussler Inc., 8426 Sunstate Street, Tampa, FL 33634, Phone , Fax , Internet: office-tampa@kreussler.com Information department: Abteilung TQM Herr Vogel +49 (0) Stefan.Kopp@kreussler.com Emergency information: +49 (0) Composition/information on ingredients Chemical characterization Description: Halogen-free solvent for dry cleaning in SYSTEMK4 (patent pending) Dangerous components: Void Additional information: For the wording of the listed risk phrases refer to section Hazards identification Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 H227 Combustible liquid. Classification according to Directive 67/548/EEC or Directive 1999/45/EC Not applicable. Information concerning particular hazards for human and environment: The product does not have to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. Classification system: The classification was made according to the latest editions of international substances lists, and expanded upon from company and literature data. Label elements Labelling according to Regulation (EC) No 1272/2008 Hazard pictograms Void Signal word Warning Hazard statements Combustible liquid. Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. In case of fire: Use for extinction: CO2, powder or water spray. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. Labelling according to EU guidelines: Observe the general safety regulations when handling chemicals. The product is not subject to identification regulations according to directives on hazardous materials. (Contd. on page 2)

2 Page 2/6 Classification system: NFPA ratings (scale 0-4) (Contd. of page 1) Health = 0 Fire = 2 Reactivity = 0 HMIS-ratings (scale 0-4) HEALTH FIRE REACTIVITY Health = 0 Fire = 2 Reactivity = 0 4 First aid measures General information: Immediately remove any clothing soiled by the product. After inhalation: Supply fresh air; consult doctor in case of complaints. After skin contact: Rinse with warm water. If skin irritation continues, consult a doctor. After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. After swallowing: Rinse out mouth and then drink plenty of water. If symptoms persist consult doctor. 5 Firefighting measures Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water. For safety reasons unsuitable extinguishing agents: Water Special hazards caused by the material, its products of combustion or resulting gases: In case of fire, the following can be released: Carbon monoxide (CO) Protective equipment: Use normal protective clothing. Additional information Dispose of fire debris and contaminated fire fighting water in accordance with official regulations. 6 Accidental release measures Person-related safety precautions: Particular danger of slipping on leaked/spilled product. Measures for environmental protection: Do not allow to enter sewers/ surface or ground water. Measures for cleaning/collecting: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Additional information: See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. No dangerous substances are released. 7 Handling and storage Handling: Information for safe handling: Keep receptacles tightly sealed. Information about protection against explosions and fires: No special measures required. Storage: Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Information about storage in one common storage facility: Not required. (Contd. on page 3)

3 Page 3/6 Further information about storage conditions: Keep receptacle tightly sealed. Store in dry conditions. (Contd. of page 2) 8 Exposure controls/personal protection Additional information about design of technical systems: No further data; see item 7. Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. Additional information: The lists that were valid during the creation were used as basis. Personal protective equipment: General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Avoid contact with the eyes and skin. Be sure to clean skin thoroughly after work and before breaks. Do not eat, drink, smoke or sniff while working. Apply solvent resistant skin cream before beginning work. Breathing equipment: Not required. Protection of hands: Protective gloves Material of gloves PVC or PE gloves Recommended thickness of the material: 0.5 mm Not suitable are gloves made of the following materials: Leather gloves Strong gloves Eye protection: Tightly sealed goggles Body protection: Solvent resistant protective clothing 9 Physical and chemical properties General Information Appearance: Form: Fluid Color: Colorless Odor: Characteristic Change in condition Melting point/melting range: C (-73 F) Boiling point/boiling range: C (357 F) Flash point: 62 C (144 F) (PMCC) Ignition temperature: 220 C (428 F) Auto igniting: Product is not selfigniting. Danger of explosion: Product does not present an explosion hazard. (Contd. on page 4)

4 Page 4/6 Explosion limits: Lower: 0.63 Vol % Upper: 23.6 Vol % Vapor pressure at 20 C (68 F): 20 hpa (15 mm Hg) Density at 20 C (68 F): g/cm³ (6.968 lbs/gal) Solubility in / Miscibility with Water: Not miscible or difficult to mix. ph-value: Slightly alkaline Solvent content: Organic solvents: 100 % (Contd. of page 3) 10 Stability and reactivity Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. Materials to be avoided: Dangerous reactions Reacts with strong acids and oxidizing agents. Dangerous products of decomposition: Aldehyde Carbon monoxide 11 Toxicological information Acute toxicity: LD/LC50 values that are relevant for classification: Acute oral toxicity: >2000mg/kg (Rats) calculated from data of constituent parts. Primary irritant effect: on the skin: No irritant effect. on the eye: No irritating effect. Sensitization: No sensitizing effects known. Additional toxicological information: The product is not subject to classification according to internally approved calculation methods for preparations: When used and handled according to specifications, the product does not have any harmful effects according to our experience and the information provided to us. 12 Ecological information Information about elimination (persistence and degradability): Other information: The product is biodegradable. Additional ecological information: General notes: Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. The product may not be released into the environment without control. 13 Disposal considerations Product: Recommendation: Dispose of in accordance with local, state, and federal Regulations. (Contd. on page 5)

5 Page 5/6 Uncleaned packagings: Recommendation: Disposal must be made according to official regulations. (Contd. of page 4) 14 Transport information DOT regulations: Hazard class: - Land transport ADR/RID (cross-border): ADR/RID class: - Maritime transport IMDG: IMDG Class: - Marine pollutant: No Air transport ICAO-TI and IATA-DGR: ICAO/IATA Class: - UN "Model Regulation": - 15 Regulatory information Sara Section 355 (extremely hazardous substances): None of the ingredient is listed. Section 313 (Specific toxic chemical listings): TSCA (Toxic Substances Control Act): All ingredients are listed. Proposition 65 Chemicals known to cause cancer: Chemicals known to cause reproductive toxicity for females: Chemicals known to cause reproductive toxicity for males: Chemicals known to cause developmental toxicity: Cancerogenity categories EPA (Environmental Protection Agency) IARC (International Agency for Research on Cancer) NTP (National Toxicology Program) TLV (Threshold Limit Value established by ACGIH) MAK (German Maximum Workplace Concentration) NIOSH-Ca (National Institute for Occupational Safety and Health) (Contd. on page 6)

6 Page 6/6 OSHA-Ca (Occupational Safety & Health Administration) Canadien Substances Listings: Canadien Domestic Substances List (DSL): All ingredients are listed. Canadien Ingredient disclosure list (limit 0.1%) All ingredients are listed. Canadien Ingredient disclosure list (limit 1%) Chemical safety assessment A Chemical Safety Assessment has not been carried out. (Contd. of page 5) 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. The information of Items 4 through 8 and 10 through 12 partially refers not to the use and the proper application of the product (see Directions for Use/Product Information) but to the release of larger quantities in the case of accidents and irregularities. The information exclusively describes the safety requirements of the product(s) and is based on the present state of our experience. Non-ionic tensides can have varying characteristics and classifications despite same CAS-No. Department issuing MSDS: Abteilung TQM Herr Vogel +49 (0) 611/ Contact: Herr Vogel Abbreviations and acronyms: ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals ACGIH: American Conference of Governmental Industrial Hygienists NFPA: National Fire Protection Association () HMIS: Hazardous Materials Identification System () LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent

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