: CO2 Indicator Solutions for Hydrocarbon Detectors

Transcription

1 SECTION: 1. Product and company identification 1.1. Product identifier Product form Name CO2 Indicator Solutions for Hydrocarbon : Substance : CO2 Indicator Solutions for Hydrocarbon Other means of identification : Hydrocarbon detector indicator solutions, part nos , , , Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture 1.3. Details of the supplier of the safety data sheet Praxair, Inc. 39 Old Ridgebury Road Danbury, CT USA T (1-800-PRAXAIR) - F Emergency telephone number : Industrial use. Use as directed. Emergency number : Onsite Emergency: SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification (GHS-US) Skin Irrit. 2 H315 Eye Irrit. 2B H320 CHEMTREC, 24hr/day 7days/week Within USA: , Outside USA: (collect calls accepted, Contract 17729) 2.2. Label elements GHS-US labeling Hazard pictograms (GHS-US) : Signal word (GHS-US) Hazard statements (GHS-US) Precautionary statements (GHS-US) GHS07 : WARNING : H315 - CAUSES SKIN IRRITATION H320 - CAUSES EYE IRRITATION : P264 - Wash exposed skin thoroughly after handling P280 - Wear protective gloves/protective clothing/eye protection/face protection P302+P352 - If on skin: Wash with plenty of water P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P321 - Specific treatment (see First aid measures on this label) P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing and wash before reuse Other hazards Other hazards not contributing to the classification : Asphyxiant in high concentrations. EN (English US) SDS ID: P /10

2 2.4. Unknown acute toxicity (GHS-US) CO2 Indicator Solutions for Hydrocarbon No data available SECTION 3: Composition/information on ingredients 3.1. Substance Name : CO2 Indicator Solutions for Hydrocarbon Name Product identifier % Water (CAS No) > 98 Sodium hydroxide (CAS No) < 0.5 Disodium carbonate (CAS No) < 0.5 Potassium chloride (CAS No) < 0.5 Toluene (CAS No) < 0.5 Xylenol Blue Dye (CAS No) < Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation First-aid measures after skin contact First-aid measures after eye contact First-aid measures after ingestion : Not expected to be a primary route of exposure. : Wash skin with plenty of water. If skin irritation occurs: Get medical advice/attention. : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an ophthalmologist immediately. : No harm expected Most important symptoms and effects, both acute and delayed 4.3. Indication of any immediate medical attention and special treatment needed SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media 5.2. Special hazards arising from the substance or mixture Fire hazard 5.3. Advice for firefighters Firefighting instructions : Use extinguishing media appropriate for surrounding fire. : Not flammable. : CAUTION! Irritating liquid and vapor Special protective equipment for fire fighters No special procedures anticipated. On-site fire brigades must comply with OSHA 29 CFR : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fighters. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures For non-emergency personnel For emergency responders : CAUTION! Irritating liquid and vapor. Do not get on skin, in eyes, or on clothing. Ventilate area of spill, or move leaking container to a well-ventilated area. EN (English US) SDS ID: P /10

3 6.2. Environmental precautions Prevent waste from contaminating the surrounding environment. Prevent soil and water pollution. Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements Methods and material for containment and cleaning up For containment : Use solid absorbent to pick up spilled material Reference to other sections SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Protect containers against physical damage. Do not get in eyes, on skin, or on clothing. Provide readily accessible eye wash stations and safety showers. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work Keep container closed when not in use Conditions for safe storage, including any incompatibilities Storage conditions : Store in a cool, dry, well-ventilated area. Store in an area appropriate for chemical solutions Specific end use(s) None. SECTION 8: Exposure controls/personal protection 8.1. Control parameters ACGIH ACGIH TLV-C (mg/m³) 2 mg/m³ USA OSHA OSHA PEL (TWA) (mg/m³) 2 mg/m³ ACGIH ACGIH TLV-TWA (ppm) 20 ppm USA OSHA OSHA PEL (TWA) (ppm) 200 ppm USA OSHA OSHA PEL (Ceiling) (ppm) 300 ppm 8.2. Exposure controls Appropriate engineering controls Hand protection : Neoprene rubber (HNBR) /. Viton /. Eye protection Respiratory protection : Provide adequate general and local exhaust ventilation. Ensure exposure is below occupational exposure limits (where available). Mechanical (General): Not recommended as a primary ventilation system to control worker's exposure. : Chemical goggles or safety glasses. : When workplace conditions warrant respirator use, follow a respiratory protection program that meets OSHA 29 CFR , ANSI Z88.2, or MSHA 30 CFR (where applicable). Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the respirator has the appropriate protection factor for the exposure level. If cartridge type respirators are used, the cartridge must be appropriate for the chemical exposure (e.g., an organic vapor cartridge). For emergencies or instances with unknown exposure levels, use a self-contained breathing apparatus (SCBA). EN (English US) SDS ID: P /10

4 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state Color Odor Odor threshold ph Relative evaporation rate (butyl acetate=1) Relative evaporation rate (ether=1) Melting point Freezing point Boiling point Flash point Auto-ignition temperature Decomposition temperature Flammability (solid, gas) Vapor pressure Relative vapor density at 20 C Relative density Density CO2 Indicator Solutions for Hydrocarbon : Liquid : Blue : Slight aromatic hydrocarbon : 7-9 (approximate) : Low : 0.0 C (32 F) : 0 C (32 F) : 100 C (212 F) : 0.02 bar ( psia) (at 20 C (68 F)) : (water = 1) (at 20 C (68 F)) : g/cm³ (at 20 C) Solubility : Water: 100 % Log Pow Log Kow Viscosity, kinematic Viscosity, dynamic Explosive properties Oxidizing properties Explosion limits : Not applicable. : Not applicable. : Not applicable. : Not applicable. : Not applicable. : None Other information SECTION 10: Stability and reactivity Reactivity Chemical stability Possibility of hazardous reactions Conditions to avoid Incompatible materials Hazardous decomposition products Stable under normal conditions. May occur. Heat. EN (English US) SDS ID: P /10

5 SECTION 11: Toxicological information Information on toxicological effects CO2 Indicator Solutions for Hydrocarbon Acute toxicity CO2 Indicator Solutions for Hydrocarbon LD50 oral rat > 90 ml/kg Water ( ) LD50 oral rat LD50 dermal rabbit ATE US (dermal) > 90 ml/kg 1350 mg/kg mg/kg body weight Disodium carbonate ( ) LD50 oral rat 4090 mg/kg LC50 inhalation rat (mg/l) 2300 mg/m³ (Exposure time: 2 h) ATE US (oral) mg/kg body weight Potassium chloride ( ) LD50 oral rat ATE US (oral) LD50 oral rat LD50 dermal rabbit LC50 inhalation rat (mg/l) LC50 inhalation rat (ppm) ATE US (oral) ATE US (dermal) ATE US (vapors) ATE US (dust, mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory or skin sensitization Germ cell mutagenicity Carcinogenicity IARC group Reproductive toxicity Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Aspiration hazard 2600 mg/kg mg/kg body weight mg/kg body weight mg/kg mg/l/4h ppm/1h mg/kg body weight mg/kg body weight mg/l/4h mg/l/4h : CAUSES SKIN IRRITATION. ph: 7-9 (approximate) : CAUSES EYE IRRITATION. ph: 7-9 (approximate) 3 - Not classifiable SECTION 12: Ecological information Toxicity LC50 fish mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static]) EN (English US) SDS ID: P /10

6 Disodium carbonate ( ) LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 Potassium chloride ( ) LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia 2 LC50 fish 1 EC50 Daphnia 1 LC50 fish 2 EC50 Daphnia mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) 265 mg/l (Exposure time: 48 h - Species: Daphnia magna) mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) 1060 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static]) 825 mg/l (Exposure time: 48 h - Species: Daphnia magna) mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) 83 mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) mg/l (Exposure time: 48 h - Species: Daphnia magna [Static]) 12.6 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) 11.5 mg/l (Exposure time: 48 h - Species: Daphnia magna) Persistence and degradability CO2 Indicator Solutions for Hydrocarbon Persistence and degradability No ecological damage caused by this product Bioaccumulative potential CO2 Indicator Solutions for Hydrocarbon Log Pow Not applicable. Log Kow Not applicable. Bioaccumulative potential No ecological damage caused by this product. Disodium carbonate ( ) BCF fish 1 (no bioaccumulation) Log Pow Mobility in soil CO2 Indicator Solutions for Hydrocarbon Mobility in soil No data available Other adverse effects Effect on ozone layer : None. SECTION 13: Disposal considerations Waste treatment methods Waste disposal recommendations : Place into lab packs for pickup by a licensed hazardous waste disposal service or use other authorized means. Do not pour down drains, into sewers, or otherwise release into the environment. SECTION 14: Transport information In accordance with DOT Additional information Other information Not regulated for transport : No supplementary information available. EN (English US) SDS ID: P /10

7 Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted. Transport by sea Air transport SECTION 15: Regulatory information US Federal regulations CO2 Indicator Solutions for Hydrocarbon Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on United States SARA Section 313 SARA Section Emission Reporting 1.0 % International regulations CANADA CO2 Indicator Solutions for Hydrocarbon Water ( ) Disodium carbonate ( ) Potassium chloride ( ) EU-Regulations CO2 Indicator Solutions for Hydrocarbon Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances) EN (English US) SDS ID: P /10

8 National regulations CO2 Indicator Solutions for Hydrocarbon Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Japanese ENCS (Existing & New Chemical Substances) inventory Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Japanese Poisonous and Deleterious Substances Control Law Japanese Pollutant Release and Transfer Register Law (PRTR Law) Listed on the Canadian IDL (Ingredient Disclosure List) US State regulations CO2 Indicator Solutions for Hydrocarbon () No Developmental Toxicity Reproductive Toxicity - Reproductive Toxicity - Male No No No Water ( ) No No No No No No No No Disodium carbonate ( ) No No No No Potassium chloride ( ) No No No No Male Male Male Male EN (English US) SDS ID: P /10

9 No Yes Yes No Xylenol Blue Dye ( ) No No No No Male Male U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Revision date Other information : 5/17/ :00:00 AM : When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an industrial hygienist or other trained person when you evaluate the end product. Before using any plastics, confirm their compatibility with this product. Praxair asks users of this product to study this SDS and become aware of the product hazards and safety information. To promote safe use of this product, a user should (1) notify employees, agents, and contractors of the information in this SDS and of any other known product hazards and safety information, (2) furnish this information to each purchaser of the product, and (3) ask each purchaser to notify its employees and customers of the product hazards and safety information. The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and the conditions of use are not within the control of Praxair, Inc., it is the user's obligation to determine the conditions of safe use of the product. Praxair SDSs are furnished on sale or delivery by Praxair or the independent distributors and suppliers who package and sell our products. To obtain current SDSs for these products, contact your Praxair sales representative, local distributor, or supplier, or download from If you have questions regarding Praxair SDSs, would like the document number and date of the latest SDS, or would like the names of the Praxair suppliers in your area, phone or write the Praxair Call Center (Phone: PRAXAIR/ ; Address: Praxair Call Center, Praxair, Inc., P.O. Box 44, Tonawanda, NY ). PRAXAIR and the Flowing Airstream design are trademarks or registered trademarks of Praxair Technology, Inc. in the United States and/or other countries. EN (English US) SDS ID: P /10

10 NFPA health hazard NFPA fire hazard NFPA reactivity : 0 - Exposure under fire conditions would offer no hazard beyond that of ordinary combustible materials. : 0 - Materials that will not burn. : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health Flammability Physical : 0 Minimal Hazard - No significant risk to health : 0 Minimal Hazard : 0 Minimal Hazard SDS US (GHS HazCom 2012) - Praxair This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product. EN (English US) SDS ID: P /10