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1 ANNEXES
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3 ANNEX 1 CLASSIFICATION AND LABELLING SUMMARY TABLES
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5 Annex 1 CLASSIFICATION AND LABELLING SUMMARY TABLES NOTE: The codifiction of hzrd s is further explined in Annex 3 (Section 1). The hzrd re intended to be used for reference purposes only. They re not prt of the hzrd text nd should not be used to replce it. A1.1 Explosives (see Chpter 2.1 for ifiction criteri) Clssifiction Lbelling Unstble explosive (Trnsport not llowed) Unstble explosive H200 Division 1.1 Explosive; mss explosion hzrd H201 Dnger Division 1.2 Explosive; severe projection hzrd H202 Explosives Division 1.3 Explosive; fire, blst or projection hzrd H203 Division 1.4 Wrning Fire or projection hzrd H204 Division 1.5 pictogrm Dnger My mss explode in fire H205 Division 1.6 pictogrm signl hzrd ne (*) Plce for comptibility group. The pictogrm for Divisions 1.1, 1.2 nd 1.3 is lso ssigned to substnces which hve n explosive subsidiry risk, but without the indiction of the division number nd the comptibility group (see lso Self-rective substnces nd mixtures nd Orgnic peroxides )
6 A1.2 Flmmble gses (including chemiclly unstble gses) (see Chpter 2.2 for ifiction criteri) Clssifiction Lbelling 1 Dnger Extremely flmmble gs H220 Flmmble gses (including chemiclly unstble gses) 2 A (chemiclly unstble gses) B (chemiclly unstble gses) pictogrm dditionl pictogrm dditionl pictogrm t required Wrning Flmmble gs H221 t required t required dditionl signl dditionl signl Additionl hzrd : My rect explosively even in the bsence of ir Additionl hzrd : My rect explosively even in the bsence of ir t elevted pressure nd/or temperture Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in blck insted of white. The bckground colour stys red in both cses. H230 H231 A1.3 Aerosols (see Chpter 2.3 for ifiction criteri) Clssifiction Lbelling Extremely flmmble erosol H222 1 Dnger Pressurized continer: my burst if heted H229 Flmmble erosol H223 Aerosols 2 Wrning Pressurized continer: my burst if heted H229 3 pictogrm Wrning Pressurized continer: my burst if heted H229 Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in blck or white. The bckground colour stys red in the first two cses nd green in the third cse
7 A1.4 Oxidizing gses (see Chpter 2.4 for ifiction criteri) Clssifiction Lbelling code Oxidizing gses 1 Dnger My cuse or intensify fire; oxidizer H270 A1.5 Gses under pressure (see Chpter 2.5 for ifiction criteri) Clssifiction Lbelling Compressed gs Wrning Contins gs under pressure; my explode if heted H280 Gses under pressure Liquefied gs Refrigerted liquefied gs Wrning Wrning Contins gs under pressure; my explode if heted Contins refrigerted gs; my cuse cryogenic burns or injury H280 H281 Dissolved gs Wrning Contins gs under pressure; my explode if heted H280 Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in white insted of blck. The bckground colour stys green in both cses. This pictogrm is not required for toxic or flmmble gses (see lso note to tbles A1.17nd A1.2)
8 A1.6 Flmmble liquids (see Chpter 2.6 for ifiction criteri) Clssifiction Lbelling 1 Dnger Extremely flmmble liquid nd vpour H224 Flmmble liquids 2 Dnger Highly flmmble liquid nd vpour H225 3 Wrning Flmmble liquid nd vpour H226 4 pictogrm t required Wrning Combustible liquid H227 Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in blck insted of white. The bckground colour stys red in both cses. A1.7 Flmmble solids (see Chpter 2.7 for ifiction criteri) Clssifiction Lbelling Flmmble solids 1 Dnger Flmmble solid H228 2 Wrning Flmmble solid H
9 A1.8 Self-rective substnces nd mixtures (see Chpter 2.8 for ifiction criteri) Clssifiction Lbelling Type A (Trnsport my not be llowed) b Dnger Heting my cuse n explosion H240 Type B Selfrective substnces nd mixtures Types C nd D Dnger Heting my cuse fire or explosion H241 Dnger Heting my cuse fire H242 Types E nd F Wrning Heting my cuse fire H242 Type G pictogrm t required signl hzrd ne b For Type B, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, specil provision 181 my pply (Exemption of explosive lbel with competent uthority pprovl. See Chpter 3.3 of the for more detils). My not be cceptble for trnsport in the pckging in which it is tested (See Chpter 2.5, pr of the ). A1.9 Pyrophoric liquids (see Chpter 2.9 for ifiction criteri) Clssifiction Lbelling code Pyrophoric liquids 1 Dnger Ctches fire spontneously if exposed to ir H
10 A1.10 Pyrophoric solids (see Chpter 2.10 for ifiction criteri) Clssifiction Lbelling code Pyrophoric solids 1 Dnger Ctches fire spontneously if exposed to ir H250 A1.11 Self-heting substnces nd mixtures (see Chpter 2.11 for ifiction criteri) Clssifiction Lbelling Selfheting substnces nd mixtures 1 Dnger Self-heting; my ctch fire H251 2 Wrning Self-heting in lrge quntities; my ctch fire H252 A1.12 Substnces nd mixtures, which in contct with wter, emit flmmble gses (see Chpter 2.12 for ifiction criteri) Clssifiction Lbelling Substnces nd mixtures, which in contct with wter, emit flmmble gses 1 Dnger 2 Dnger 3 Wrning In contct with wter releses flmmble gses which my ignite spontneously In contct with wter releses flmmble gses In contct with wter releses flmmble gses H260 H261 H261 Under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the symbol, number nd border line my be shown in blck insted of white. The bckground colour stys blue in both cses
11 A1.13 Oxidizing liquids (see Chpter 2.13 for ifiction criteri) Clssifiction Lbelling 1 Dnger My cuse fire or explosion; strong oxidizer H271 Oxidizing liquids 2 Dnger My intensify fire; oxidizer H272 3 Wrning My intensify fire; oxidizer H272 A1.14 Oxidizing solids (see Chpter 2.14 for ifiction criteri) Clssifiction Lbelling 1 Dnger My cuse fire or explosion; strong oxidizer H271 Oxidizing solids 2 Dnger My intensify fire; oxidizer H272 3 Wrning My intensify fire; oxidizer H
12 A1.15 Orgnic peroxides (see Chpter 2.15 for ifiction criteri) Clssifiction Lbelling Type A (Trnsport my not be llowed) b Dnger Heting my cuse n explosion H240 Type B Dnger Heting my cuse fire or explosion H241 Orgnic peroxides Types C nd D Dnger Heting my cuse fire H242 Types E nd F Wrning Heting my cuse fire H242 b Type G pictogrm t required signl hzrd ne For Type B, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, specil provision 181 my pply (Exemption of explosive lbel with competent uthority pprovl. See Chpter 3.3 of for more detils). My not be cceptble for trnsport in the pckging in which it is tested (See Chpter 2.5, pr of the ). A1.16 Corrosive to metls (see Chpter 2.16 for ifiction criteri) Clssifiction Lbelling code Corrosive to metls 1 Wrning My be corrosive to metls H
13 A1.17 Acute toxicity (see Chpter 3.1 for ifiction criteri) Clssifiction Lbelling 1 Orl Ftl if swllowed H300 Derml Dnger Ftl in contct with skin H310 Inhltion Ftl if inhled H330 Acute toxicity Orl Ftl if swllowed H300 Derml Dnger Ftl in contct with skin H310 Inhltion Ftl if inhled H330 Orl Toxic if swllowed H301 Derml Dnger Toxic in contct with skin H311 Inhltion Toxic if inhled H331 Orl Hrmful if swllowed H302 Derml t required Wrning Hrmful in contct with skin H312 Inhltion Hrmful if inhled H332 5 Orl Derml pictogrm t required Wrning My be hrmful if swllowed My be hrmful in contct with skin H303 H313 Inhltion My be hrmful if inhled H333 For gses, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, replce the number 6 in the bottom corner of the pictogrm by 2. A1.18 Skin corrosion/irrittion (see Chpter 3.2 for ifiction criteri) Clssifiction Lbelling 1 Dnger Cuses severe skin burns nd eye dmge H314 Skin corrosion/irrittion 2 t required Wrning Cuses skin irrittion H315 3 pictogrm t required Wrning Cuses mild skin irrittion H316 Applies to some uthorities
14 A1.19 Serious eye dmge/eye irrittion (see Chpter 3.3 for ifiction criteri) Clssifiction Lbelling 1 t required Dnger Cuses serious eye dmge H318 Serious eye dmge/eye irrittion 2/2A t required Wrning Cuses serious eye irrittion H319 2B pictogrm t required Wrning Cuses eye irrittion H320 A1.20 Respirtory sensitizer (see Chpter 3.4 for ifiction criteri) Clssifiction Lbelling 1 t required Dnger My cuse llergy or sthm symptoms or brething difficulties if inhled H334 Respirtory sensitiztion 1A t required Dnger My cuse llergy or sthm symptoms or brething difficulties if inhled H334 1B t required Dnger My cuse llergy or sthm symptoms or brething difficulties if inhled H334 Sub-ctegories my be pplied where dt re sufficient nd where required by competent uthority
15 A1.21 Skin sensitizer (see Chpter 3.4 for ifiction criteri) Clssifiction Lbelling 1 t required Wrning My cuse n llergic skin rection H317 Skin sensitiztion 1A t required Wrning My cuse n llergic skin rection H317 1B t required Wrning My cuse n llergic skin rection H317 Sub-ctegories my be pplied where dt re sufficient nd where required by competent uthority. A1.22 Germ cell mutgenicity (see Chpter 3.5 for ifiction criteri) Clssifiction Lbelling Germ cell mutgenicity 1 (both 1A nd 1B) t required Dnger 2 t required Wrning My cuse genetic defects (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) Suspected of cusing genetic defects (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) H340 H341 A1.23 Crcinogenicity (see Chpter 3.6 for ifiction criteri) Clssifiction Lbelling Crcinogenicity 1 (both 1A nd 1B) t required Dnger My cuse cncer (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) H350 2 t required Wrning Suspected of cusing cncer (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) H
16 A1.24 Toxic to reproduction (see Chpter 3.7 for ifiction criteri) Reproductive toxicity Clssifiction Lbelling 1 (both 1A nd 1B) t required Dnger 2 t required Wrning Additionl for effects on or vi lcttion pictogrm t required signl My dmge fertility or the unborn child (stte specific effect if known) (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) Suspected of dmging fertility or the unborn child (stte specific effect if known) (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) My cuse hrm to brest-fed children H360 H361 H362 A1.25 Specific trget orgn toxicity following single exposure (see Chpter 3.8 for ifiction criteri) Clssifiction Lbelling Specific trget orgn toxicity single exposure 1 t required Dnger 2 t required Wrning 3 t required Wrning Cuses dmge to orgns (or stte ll orgns ffected, if known) (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) My cuse dmge to orgns (or stte ll orgns ffected, if known) (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) My cuse respirtory irrittion or My cuse drowsiness or dizziness H370 H371 H335 H
17 A1.26 Specific trget orgn toxicity following repeted exposure (see Chpter 3.9 for ifiction criteri) Clssifiction Lbelling Specific trget orgn toxicity repeted exposure 1 t required Dnger 2 t required Wrning Cuses dmge to orgns (stte ll orgns ffected, if known) through prolonged or repeted exposure (stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) My cuse dmge to orgns (stte ll orgns ffected, if known) through prolonged or repeted exposure(stte route of exposure if it is conclusively proven tht no other routes of exposure cuse the hzrd) H372 H373 A1.27 Aspirtion hzrd (See chpter 3.10 for ifiction criteri) Clssifiction Lbelling Aspirtion hzrd 1 t required Dnger My be ftl if swllowed nd enters irwys H304 2 t required Wrning My be hrmful if swllowed nd enters irwys H305 A1.28 () ous to the qutic environment, short-term (cute) (see Chpter 4.1 for ifiction criteri) Clssifiction Lbelling ous to the qutic environment, short-term (Acute) Acute 1 Wrning Very toxic to qutic life H400 Acute 2 Acute 3 pictogrm pictogrm t required t required signl signl Toxic to qutic life Hrmful to qutic life For Ctegory 1, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the pictogrm is not required if the substnce presents ny other hzrds covered by. If no other hzrd is presented, this pictogrm is required s mrk in ddition to the Clss 9 lbel. H401 H
18 A1.28 (b) ous to the qutic environment, long-term (chronic) (see Chpter 4.1 for ifiction criteri) Clssifiction Lbelling Chronic 1 Wrning Very toxic to qutic life with long lsting effects H410 ous to the qutic environment, long-term (Chronic) Chronic 2 Chronic 3 Chronic 4 pictogrm pictogrm t required t required signl signl signl Toxic to qutic life with long lsting effects Hrmful to qutic life with long lsting effects My cuse long lsting hrmful effects to qutic life For ctegories 1 nd 2, under the UN Recommendtions on the Trnsport of Dngerous Goods, Model, the pictogrm is not required if the substnce presents ny other hzrds covered by. If no other hzrd is presented, this pictogrm is required s mrk in ddition to the Clss 9 lbel. H411 H412 H413 A1.29 to the ozone lyer (see Chpter 4.2 for ifiction criteri) Clssifiction Lbelling code ous to the ozone lyer 1 t required Wrning Hrms public helth nd the environment by destroying ozone in the upper tmosphere H
Copyright@United Nations, 2015. All rights reserved ANNEXES
ANNEXES ANNEX CLASSIFICATION AND LABELLING SUMMARY TABLES Annex CLASSIFICATION AND LABELLING SUMMARY TABLES NOTE: The codifiction of hzrd s is further explined in Annex 3 (Section ). The hzrd re intended
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