Multiple Choice (10 points each) Identify the letter of the choice that best completes the statement or answers the question.

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1 General Chemistry II Exam 1 (175 pints) (Answer Key) 1A Name Multiple Chice (10 pints each) Identify the letter f the chice that best cmpletes the statement r answers the questin. E 1. Fr a certain prcess at 27 C, G kj and H kj. What is the entrpy change fr this prcess at this temperature? Express yur answer in the frm, S J/K. a J/K d x 10 J/K b J/K e x 10 J/K c J/K G H T S T 27 C K H G ( kj) ( kj) 1.26 kj S T 00K K K kj K kj J J _A 2. Which respnse includes all f the fllwing substances that have H f 0, and n ther substances? I. HCl(g) II. Na(s) III. HCl(aq) IV. F 2 (g) a. II and IV d. I, II, III, and IV b. II e. I, II, and IV c. I and II All elements in their natural standard state have a H f 0. A. Frm the fllwing data at 25 C, 2 NOCl(g) 2 NO(g) +Cl 2 g) H kj 2 NO(g) + O 2 (g) 2 NO 2 g) H kj 2 NO 2 (g) N 2 O (g) H kj Calculate H 0 at 25 C fr the reactin belw. N 2 O (g) + Cl 2 (g) 2 NOCl(g) + O 2 (g) a kj d kj b kj e kj c kj Reverse all reactins and change the sign f the H 0 fr each. 2 NO(g) +Cl 2 (g) 2 NOCl(g) H kj 2 NO 2 (g) 2 NO(g) + O 2 (g) H kj N 2 O (g) 2 NO 2 (g) H kj N 2 O (g) + Cl 2 (g) 2 NOCl(g) + O 2 (g) H kj

2 A. Assuming the gases are ideal, calculate the amunt f wrk dne, in jules, fr the cnversin f 1.00 mle f Ni t Ni(CO) at 75 C in the reactin belw. The value f R is 8.1 J/ml K. Ni(s) + CO(g) Ni(CO) (g) a J d J b J e. - 9 J c J Ni(s) + CO(g) Ni(CO) (g) ml gas 1 ml gas n ( 1 ml gas ml gas) ml gas 8.1 J R ml K T 75 C K w nrt 8.1 J ( ml gas) ( 8K ) ml K J 2A _B 5. Which f the fllwing techniques cannt be used t calculate H rxn? a. Using f Heats f Frmatin f reactants and prducts b. Using melting pints f reactants and prducts c. Hess's Law d. Using bnd energies f reactants and prducts e. Calrimetry C 6. Cnsider the reactin belw at 25 C fr which S J/K. CH (g) + N 2 (g) kj HCN(g) + NH (g) + H Which ne f the fllwing statements describes the reactin? a. Insufficient infrmatin t estimate temperature range f spntaneity b. Spntaneus at relatively lw temperatures nly c. Spntaneus at relatively high temperatures nly d. Spntaneus at all temperatures e. Nnspntaneus at all temperatures Under cnditins f psitive enthalpy and psitive entrpy, the temperature must be relatively high t achieve a negative free energy. answer : G H T S ( + ) ( + )

3 A A 7. At 25 C H kj and G.5 kj fr a reactin. Abve what minimum temperature will this reactin becme spntaneus? a. 0 K d. 2 K b. 50 K e. 298 K c K Answer : This is a tw part answer. 1) Determine S. G H T S kj ( H G ) ml kj S 0.20 T 298 K mlk 2) Determine T by letting G 0. G H T S H 128.9kJ T 0K S kj 0.20 ml K B 8. Which ne f the fllwing thermdynamic quantities is nt a state functin? a. wrk d. internal energy b. free energy e. enthalpy c. entrpy 9. Which respnse includes all the fllwing prcesses that are accmpanied by an increase in entrpy, and nly thse prcesses? I. biling water l g (+ S) II. freezing water l s ( S) III. N 2 (g) + H 2 (g) 2NH (g) ml gas 2 ml gas ( S) IV. Br 2 (l) Br 2 (g) (+ S) a. I and II d. II, III, and IV b. I and IV e. III and IV c. anther ne r anther cmbinatin _B 10. Estimate the enthalpy change fr the reactin belw frm the average bnd energies given. There are tw Cl-Cl and tw C-H bnds in CH 2 Cl 2. Remember that energy is absrbed when bnds are brken and released when they are frmed. CH (g) + 2Cl 2 (g) CH 2 Cl 2 (g) + 2HCl(g) Average Bnd Energies C-H 1 kj/ml Cl-Cl 22 kj/ml H-Cl 2 kj/ml C-Cl 9 kj/ml a kj/ml d kj/ml b. -22 kj/ml e. +51 kj/ml c. +22 kj/ml Answer : reactants ( C H bnds) + 2( Cl Cl bnds) (1 kj ) 1652 kj 2(22 kj ) 8 kj 216kJ prducts 2( C H bnds) + 2( C Cl bnds) + 2( H Cl bnds) 2(1 kj ) 826 kj 2(9 kj ) 678 kj 2(2 kj ) 86 kj 268kJ B. E reactants prducts ( ) ( ) ( 216kJ ) ( 2 kj ) 68 22kJ

4 A _D 11. Hw much heat is given ff in the frmatin f 5.0 grams f Fe 2 O (s) at 25 C and 1.00 atm pressure by the fllwing reactin? The mlar mass f irn(iii) xide is g/ml. Fe(s) + O 2 (g) 2Fe 2 O (s) H (kj/ml) a kj d kj b. 90. kj e kj c. 151 kj H n( prducts) n( reactants) rxn [ 2( 82.2 kj ) ] [ 0 0] + 168kJ 5.0gFeO 2 1 mlfeo 2 1 mlrxn 168kJ 159.7g FeO 2 2 mlfeo 2 1 mlrxn 180.6kJ _A 12. Which ne f the fllwing statements is nt crrect? a. When H fr a reactin is negative, the reactin is never spntaneus. b. When G fr a reactin is negative, the reactin is spntaneus. c. When G fr a reactin is psitive, the reactin is nnspntaneus. d. When G fr a reactin is zer, the system is at equilibrium. Mst reactins exthermic, and as a result, the change in entrpy is psitive. A negative change in enthalpy and psitive change in entrpy will result in a negative free energy and a spntaneus reactin. _E 1. Which statement cncerning sign cnventins fr E q + w is false? a. Fr heat absrbed by the system, q is psitive. b. Fr an expansin, w is negative. c. When energy is released by the reacting system, E is negative. d. Fr wrk dne by the system, w is negative. e. If E is psitive, energy can be written as a prduct in the equatin fr the reactin. If the change in internal energy f a system is psitive, then the system gained energy and r had wrk dne n it by the surrundings. In terms f a chemical reactin, this means the reactants added heat r had wrk dne n it (such as gases ging t liquids) during the reactin prcess.

5 Prblem Yu must shw yur wrk fr the fllwing questins and it must lgically lead t yur answer t receive full credit fr a questin. The calculatins and answers shuld be shwn with the crrect units and significant figures. 5A 1. (5 ttal pints) A g sample f ethanl, C 2 H 5 OH, was burned in a bmb calrimeter whse heat capacity had been determined t be 2.71 kj/ C. The temperature f.000 x 10 grams f water rse frm 2.28 C t C. The mlar mass f ethanl is 6.07 g/ml. a) (20 pints) Determine the H fr the reactin in jules per gram f ethanl. b) (10 pints) Determine the H fr the reactin in kiljules per mle f ethanl. c) (10 pints) What is the E fr the reactin at cnstant pressure? d) (5 pints) Is wrk dne by r n the system? C 2 H 5 OH (l) + O 2 (g) 2 CO 2 (g) + H 2 O (l) J a) q mc T ; calrimeter cnstant ; T ( ) C 1.91 C C.18 J J q ( g) ( 1.91 C) ( 1.91 C) J + g C C q H J H ( remember, the rxn is exthermic) g EtOH J 6.07 g EtOH 1 kj kj b) g EtOH ml EtOH 10 J ml c) E q + w n ( 2 ml gas ml gas) 1 ml gas w nrt 8.1J ( 1 ml gas) (298 K ) J 2.8 kj ml K E q + w kj ( 2.8 kj ) ml kj ml d) Wrk is dne n the system by the surrundings.

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