Material Safety Data Sheet

Transcription

1 Material Safety Data Sheet Issuing Date: 27Jun2012 Revision Date: 27Jun2012 Version 1 Product ID: PRODUCT AND COMPANY IDENTIFICATION Product Name Recommended use Uses advised against Synonyms Manufacturer Address Emergency telephone Emergency Overview Irritating to eyes Sebastian Trilliance Shampoo Personal Beauty Care Product All other uses The Procter & Gamble Company Sharon Woods Innovation Center Reed Hartman Highway Cincinnati OH pgsds.im@pg.com Transportation (24 HR) CHEMTREC (U.S./ Canada) or Mexico toll free in country: HAZARDS IDENTIFICATION OSHA Regulatory Status This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR ). WHMIS Principle Routes of Exposure General Hazards Not subject to WHMIS classification Skin contact. Eye contact. This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use Page 1 / 9

2 Sebastian Trilliance Shampoo Revision Date: 27Jun COMPOSITION/INFORMATION ON INGREDIENTS CASNo Weight % Poly(oxy1,2ethanediyl), alphasulfoomega(dodecyloxy), sodium salt (1:1) Sulfuric acid monododecyl ester sodium salt (1:1) Propanaminium, aminoN(carboxymethyl)N,Ndimethyl, Ncoco acyl derivs., inner salts 1,2,3Propanetriol Sodium hydroxide < 0.1 Benzyl acetate < FIRST AID MEASURES General advice Eye contact Skin contact Ingestion Inhalation Protection of Firstaiders Most important symptoms/effects, acute and delayed Notes to physician No hazards which require special first aid measures. When symptoms persist or in all cases of doubt seek medical advice. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. If skin problems occur, discontinue use. If symptoms persist, call a physician. Clean mouth with water and afterwards drink plenty of water. Not an expected route of exposure. Use personal protective equipment. None known. Treat symptomatically. 5. FIREFIGHTING MEASURES Flash Point Suitable Extinguishing Media Unsuitable Extinguishing Media Special Hazard Special protective equipment for firefighters Dry chemical, CO 2, water spray or alcoholresistant foam.. None in particular As in any fire, wear selfcontained breathing apparatus and full protective gear. Page 2 / 9

3 Sebastian Trilliance Shampoo Revision Date: 27Jun ACCIDENTAL RELEASE MEASURES Personal precautions Advice for emergency responders Environmental precautions Methods for Containment Methods for Cleaning up Use personal protective equipment. Avoid contact with the skin and the eyes. Use personal protective equipment. Nonhousehold: Should not be released into the environment. Household: Do not discharge product into natural waters without pretreatment or adequate dilution HANDLING AND STORAGE Advice on safe handling Technical measures/storage conditions Keep out of the reach of children. Observe label precautions. Keep out of the reach of children. Keep containers tightly closed in a dry, cool and wellventilated place. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines 1,2,3Propanetriol ACGIH TLV OSHA PEL NIOSH IDLH Mexico OEL TWA: 10 mg/m 3 mist TWA: 15 mg/m 3 mist, total Mexico: TWA 10 mg/m 3 particulate TWA: 5 mg/m 3 mist, respirable fraction (vacated) TWA: 10 mg/m 3 mist, total particulate (vacated) TWA: 5 mg/m 3 mist, respirable fraction IDLH: 10 mg/m 3 Mexico: Ceiling 2 mg/m 3 Ceiling: 2 mg/m 3 Sodium hydroxide Ceiling: 2 mg/m 3 TWA: 2 mg/m 3 (vacated) Ceiling: 2 mg/m 3 Benzyl acetate TWA: 10 ppm British Columbia Alberta Quebec Ontario TWAEV 1,2,3Propanetriol TWA: 10 mg/m 3 TWA: 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 TWA: 10 mg/m 3 mg/m 3 Sodium hydroxide Ceiling: 2 mg/m 3 Ceiling: 2 mg/m 3 Ceiling: 2 mg/m 3 CEV: 2 mg/m 3 Benzyl acetate TWA: 10 ppm TWA: 10 ppm TWA: 61 TWA: 10 ppm mg/m 3 Engineering Measures Not applicable. Personal Protective Equipment Eye Protection Hand Protection Skin and body protection Respiratory protection Thermal hazards Avoid contact with eyes. No special protective equipment required. No special protective equipment required. No special protective equipment required Not applicable. Page 3 / 9

4 Sebastian Trilliance Shampoo Revision Date: 27Jun2012 Hygiene measures None under normal use condtions. Environmental Exposure Controls See Section PHYSICAL AND CHEMICAL PROPERTIES Physical C Appearance Odor liquid viscous liquid. Mild, Characteristic Property Values Note ph VALUE Melting/freezing point Boiling point/boiling range Flash Point Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit Vapor pressure Vapor density Relative density Water solubility Solubility in other solvents Partition coefficient: noctanol/water Autoignition temperature. Decomposition temperature. Viscosity of Product cp Bulk Density log Pow Sulfuric acid monododecyl ester sodium salt (1:1) 1.6 1,2,3Propanetriol 1.76 Benzyl acetate STABILITY AND REACTIVITY Reactivity Stability Hazardous Polymerization Hazardous Reactions Conditions to Avoid Materials to Avoid None under normal use conditions. Stable under normal conditions. Hazardous polymerization does not occur. None under normal processing. None under normal processing. None in particular. Hazardous Decomposition Products None under normal use. Page 4 / 9

5 Sebastian Trilliance Shampoo Revision Date: 27Jun2012 Product Information Acute Toxicity 11. TOXICOLOGICAL INFORMATION Principle Routes of Exposure Inhalation Skin contact Ingestion Eye contact Skin contact. Eye contact. No known effect based on information supplied. No known effect based on information supplied. No known effect based on information supplied. Irritating to eyes. LD50 Oral LD50 Dermal LC50 Inhalation Poly(oxy1,2ethanediyl), 1600 mg/kg ( Rat ) alphasulfoomega(dodecyloxy), sodium salt (1:1) Sulfuric acid monododecyl ester 1288 mg/kg ( Rat ) 580 mg/kg ( Rabbit ) 3900 mg/m 3 ( Rat ) 1 h sodium salt (1:1) 1Propanaminium, 4900 mg/kg ( Rat ) 3aminoN(carboxymethyl)N,N dimethyl, Ncoco acyl derivs., inner salts Sulfuric acid sodium salt (1:2) mg/kg (rat) 1,2,3Propanetriol mg/kg (rat) mg/kg ( Rat ) Sodium hydroxide 1350 mg/kg ( Rabbit ) Benzyl acetate 2490 mg/kg ( Rat ) 5 g/kg ( Rabbit ) Chronic Toxicity Corrosivity Sensitization Neurological Effects Reproductive Toxicity Mutagenic Effects Developmental Toxicity Teratogenicity Carcinogenicity The product contains no substances known to be hazardous to health in concentrations which need to be taken into account. There are no known mutagenic chemicals in this product. Contains no ingredients above reportable quantities listed as a carcinogen. Page 5 / 9

6 Sebastian Trilliance Shampoo Revision Date: 27Jun2012 Ecotoxicity 12. ECOLOGICAL INFORMATION Acute Toxicity Toxicity to algae Toxicity to fish Toxicity to microorganisms Sulfuric acid monododecyl ester sodium salt (1:1) 1Propanaminium, 3aminoN(carboxymethyl) N,Ndimethyl, Ncoco acyl derivs., inner salts EC50 72 h = 53 mg/l LC50 96 h Desmodesmus mg/l Pimephales subspicatus EC50 96 promelas static LC50 h mg/l 96 h mg/l Desmodesmus Pimephales promelas subspicatus EC50 96 static LC50 96 h 22.1 h = 117 mg/l 22.8 mg/l Pseudokirchneriella Pimephales promelas subcapitata EC50 96 h static LC50 96 h mg/l 8.5 mg/l Pseudokirchneriella Oncorhynchus mykiss subcapitata static static LC50 96 h = 4.62 mg/l Oncorhynchus mykiss flowthrough LC50 96 h = 4.2 mg/l Oncorhynchus mykiss LC50 96 h = 7.97 mg/l Brachydanio rerio flowthrough LC50 96 h mg/l Brachydanio rerio semistatic LC50 96 h mg/l Lepomis macrochirus static LC50 96 h mg/l Lepomis macrochirus flowthrough LC50 96 h = 4.5 mg/l Lepomis macrochirus LC50 96 h mg/l Pimephales promelas static LC50 96 h mg/l Pimephales promelas semistatic LC50 96 h mg/l Pimephales promelas LC50 96 h mg/l Poecilia reticulata semistatic LC50 96 h mg/l Poecilia reticulata static LC50 96 h = 1.31 mg/l Cyprinus carpio semistatic EC50 72 h mg/l Desmodesmus subspicatus EC50 96 h = 0.55 mg/l Desmodesmus subspicatus LC50 96 h mg/l Brachydanio rerio LC50 96 h = 2 mg/l Brachydanio rerio semistatic Toxicity to daphnia and other aquatic invertebrates EC50 48 h = 1.8 mg/l Daphnia magna = 53 mg/l EC mg/l EC50 = 117 mg/l EC mg/l EC50 EC50 48 h = 6.5 mg/l Daphnia magna mg/l EC50 = 0.55 mg/l EC50 Toxicity to other organisms Page 6 / 9

7 Sebastian Trilliance Shampoo Revision Date: 27Jun2012 Sulfuric acid sodium salt (1:2) LC50 96 h mg/l Pimephales promelas LC50 96 h > 6800 mg/l Pimephales promelas static LC50 96 h mg/l Lepomis macrochirus static LC50 96 h = mg/l Lepomis macrochirus 1,2,3Propanetriol LC50 96 h ml/l Oncorhynchus mykiss static Sodium hydroxide LC50 96 h = 45.4 mg/l Oncorhynchus mykiss static EC50 96 h = 630 mg/l Daphnia magna EC50 48 h = 2564 mg/l Daphnia magna EC50 24 h > 500 mg/l Daphnia magna Persistence and degradability Bioaccumulative potential.. Mobility. Other adverse effects 13. DISPOSAL CONSIDERATIONS Waste from Residues / Unused Products Contaminated packaging Nonhousehold: Should not be released into the environment. Household: Do not discharge product into natural waters without pretreatment or adequate dilution. Dispose of in accordance with local regulations. 14. TRANSPORT INFORMATION DOT TDG MEX IATA ICAO IMDG/IMO U.S. Federal Regulations 15. REGULATORY INFORMATION Page 7 / 9

8 Sebastian Trilliance Shampoo Revision Date: 27Jun2012 SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Yes no no no no CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302): Hazardous Substances RQs Extremely Hazardous RQ Substances RQs Sodium hydroxide 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ Food and Drug Administration (FDA) The product described in this Material Safety Data Sheet is regulated under the Federal Food, Drug, and Cosmetics Act and is safe to use as per directions on container, box or accompanying literature (where applicable). Clean Air Act, Section 112 Hazardous Air Pollutants (HAPs) (see 40 CFR 61) This product does not contain any substances regulated as hazardous air pollutants (HAPS) under Section 112 of the Clean Air Act Amendments of Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR and 40 CFR ): CWA Reportable CWA Toxic Pollutants Quantities Sodium hydroxide 1000 lb U.S. State Regulations CWA Priority Pollutants CWA Hazardous Substances X California Proposition 65 This product is not subject to warning labeling under California Proposition 65 U.S. State Regulations Sulfuric acid sodium salt (1:2) Sodium hydroxide Pennsylvania X X International Regulations Canada WHMIS Hazard Class Not subject to WHMIS classification This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by the CPR. This product is regulated by the Food and Drug Administration of Health Canada and is therefore exempt from the requirements of CEPA. Page 8 / 9

9 Sebastian Trilliance Shampoo Revision Date: 27Jun2012 International Inventories TSCA Exempt DSL Exempt NDSL Exempt Perfumes contained with the products comply with appropriate IFRA guidance. Legend TSCA United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL Canadian Domestic Substances List/NonDomestic Substances List 16. OTHER INFORMATION Issuing Date: Revision Date: 27Jun Jun2012 Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of MSDS Page 9 / 9