SAFETY Data Sheet. According to Regulation (EC) No. 1907/2006. Part number: Version : 4 GB / EN

Transcription

1 Print Date: Revsion Date: : Seite 1 von 9 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Commercial Product Name: Frostox SF-D12 PLUS 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture: Radiator anti-freeze 1.3 Details of the supplier of the safety data sheet Company: HAERTOL Chemie GmbH Havelstr Magdeburg Telephone: Telefax : Contact person: Herr Egon Dühring address: info@haertol.de 1.4 Emergency telephone number Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC, 1999/45/EC) Harmful R22: Harmful if swallowed. 2.2 Label elements Labelling according to EC Directives: 1999/45/EC Hazard symbols: R-phrase(s): R22 Harmful if swallowed. Harmful S-phrase(s): S60 This material and its container must be disposed of as hazardous waste. Hazardous components which must be listed on the label: ethanediol Special labelling of certain: Contains epoxy constituents. See information supplied by the mixtures manufacturer. 1/9

2 Print Date: Revsion Date: : Seite 2 von Other hazards 3. Composition/information on ingredients 3.1 Mixtures Hazardous components Chemical Name CAS-No. Classification Classification Concentration EC-No. (67/548/EEC) (1272/2008/EC) [%] Registration number ethanediol Xn; R22 Acute Tox. 4; H302 >= 90 - < ethylhexanoic acid Repr.Cat.3; R63 Repr. 2; H361d >= 2 - < For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section First aid measures 4.1 Description of first aid measures General advice: If inhaled: In case of skin contact: In case of eye contact: If swallowed: In the case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). Move out of dangerous area. Never give anything by mouth to an unconscious person. Take off all contaminated clothing immediately. Remove to fresh air. Keep patient warm and at rest. If symptoms persist, call a physician. Wash off immediately with soap and plenty of water. Remove contact lenses. Rinse immediately with plenty of water an seek medical advice. If swallowed, seek medical advice immediately and show this container or label. If a person vomits when lying on his back, place him in the recovery position. Do NOT induce vomiting. 4.2 Most important symptoms and effects, both acute and delayed 4.3 Indication of any immediate medical attention and special treatment needed 5. Firefighting measures 2/9

3 Print Date: Revsion Date: : Seite 3 von Extinguishing media Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 5.2 Special hazards arising from the substance or mixture Specific hazards during: Build-up of dangerous/toxic fumes possible in cases of fire/high firefighting temperature. Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment for firefighters: In the event of fire, wear self-contained breathing apparatus. Further information: Standard procedure for chemical fires. Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Refer to protective measures listed in sections 7 and 8. Ventilate the area. Remove all sources of ignition. Avoid inhalation of vapour or mist. Avoid contact with skin and eyes. 6.2 Environmental precautions Should not be released into the environment. Avoid subsoil penetration. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3 Methods and materials for containment and cleaning up Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations. 6.4 Reference to other sections see chapter: 7, 8, 11, 12 and Handling and storage 7.1 Precautions for safe handling Advice on safe handling: Avoid contact with skin and eyes. Do not breathe vapours or spray mist. For personal protection see section 8. Advice on protection against fire: Normal measures for preventive fire protection. Keep away from and explosion sources of ignition - No smoking. Dust explosion class: not applicable 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage areas: Store in original container. Keep containers tightly closed in a dry, and containers cool and well-ventilated place. 3/9

4 Print Date: Revsion Date: : Seite 4 von 9 Advice on common storage: Incompatible with oxidizing agents. Keep away from food, drink and animal feedingstuffs. Storage temperature: > -25 C Other data: No decomposition if stored and applied as directed. 7.3 Specific end uses 8. Exposure controls/personal protection 8.1 Control parameters Components CAS-No. Control parameters Basis Update ethanediol TWA: 52 mg/m3, 20 ppm GB EH Sk, STEL: 104 mg/m3, 40 ppm Sk, caustic soda STEL: 2 mg/m3, GB EH Components CAS-No. Control parameters Basis Update ethanediol TWA: 52 mg/m3, 20 ppm 2000/39/EC Other information on limit values: see chapter Exposure controls Engineering measures skin, STEL: 104 mg/m3, 40 ppm skin, Provide sufficient air exchange and/or exhaust in work rooms. Personal protective equipment Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment. Hand protection Material: Remarks: Eye protection: Chloroprene Rubber gloves Choose gloves to protect hands against chemicals depending on the concentration and quantity of the hazardous substance and specific to place of work. For special applications, we recommend clarifying the resistance to chemicals of the aforementioned protective gloves with the glove manufacturer. Safety glasses Skin and body protection: Protective suit 4/9

5 Print Date: Revsion Date: : Seite 5 von 9 Hygiene measures: Environmental exposure controls General advice: Handle in accordance with good industrial hygiene and safety practice. General industrial hygiene practice. When using do not eat, drink or smoke. Avoid contact with skin, eyes and clothing. Wash hands before breaks and at the end of workday. Wash contaminated clothing before re-use. Should not be released into the environment. Avoid subsoil penetration. If the product contaminates rivers and lakes or drains inform respective authorities. 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance: liquid Colour: Odour: No information available. Odour Threshold: Flash point: > 100 C Ignition temperature: Lower explosion limit: Upper explosion limit: Explosive properties: In use, may form flammable/explosive vapour-air mixture. Flammability (solid, gas): Oxidizing properties: Autoignition temperature: Burning number: Molecular Weight: ph: 8,1 at 20 C Concentration: 10,00 g/l Vapour pressure: Density: 1,1 g/cm3 at 20 C Bulk density: Water solubility: completely miscible Partition coefficient: n-octanol/water: Solubility in other solvents: Viscosity, dynamic: Viscosity, kinematic: Flow time : Impact Sensitivity: Relative vapour density: Surface tension: Evaporation rate: Minimum ignition energy: Acid number: Refraction index: Miscibility in water: Solvent separation test: 9.2 Other information None known. 5/9

6 Print Date: Revsion Date: : Seite 6 von Stability and reactivity 10.1 Reactivity 10.2 Chemical stability The product is chemically stable Possibility of hazardous reactions Stability: Stable under recommended storage conditions Conditions to avoid Keep away from heat and sources of ignition Incompatible materials Materials to avoid: Strong oxidizing agents 10.6 Hazardous decomposition products Hazardous decomposition products: Build-up of dangerous/toxic fumes possible in cases of fire/high temperature. Thermal decomposition: 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity: Harmful if swallowed. Acute inhalation toxicity: Acute dermal toxicity: Acute toxicity (other routes of administration): Skin corrosion/irritation Serious eye damage/eye irritation Respiratory or skin sensitization Sensitisation: Germ cell mutagenicity 6/9

7 Print Date: Revsion Date: : Seite 7 von 9 Genotoxicity in vitro: Carcinogenicity: Reproductive toxicity 2-ethylhexanoic acid: Note: Some evidence of adverse effects on sexual function and fertility, and/or on development, based on animal experiments., Suspected of damaging the unborn child. Teratogenicity STOT - single exposure STOT - repeated exposure ethanediol : Exposure routes: Ingestion Target Organs: Kidney Shown to produce significant health effects in animals at concentrations of >10 to 100 mg/kg bw. Aspiration hazard Aspiration toxicity: Neurological effects Toxicology Assessment Toxicology, Metabolism, Distribution: Acute effects : 12. Ecological information 12.1 Toxicity Toxicity to fish: LC50 : > 100 mg/l Note: Information given is based on data on the components and the ecotoxicology of similar products. Toxicity to bacteria: EC50 : > 100 mg/l Note: Information given is based on data on the components and the ecotoxicology of similar products Persistence and degradability Biodegradability : Note: Readily biodegradable. 7/9

8 Print Date: Revsion Date: : Seite 8 von Bioaccumulative potential 12.4 Mobility in soil 12.5 Results of PBT and vpvb assessment 12.6 Other adverse effects Adsorbed organic bound: Remarks: halogens (AOX) not included Additional ecological information: The product should not be allowed to enter drains, water courses or the soil. 13. Disposal considerations 13.1 Waste treatment methods Advice on disposal and packaging : Disposal: In accordance with local and national regulations. Waste codes should be assigned by the user based on the application for which the product was used. The following Waste Codes are only suggestions: Waste Code (EWC): Waste Key (unused product): , other organic solvents, washing liquids and mother liquors Waste key (used product): , other organic solvents, washing liquids and mother liquors Disposal of uncleaned packaging : Waste key (uncleaned packaging): , packaging containing residues of or contaminated by dangerous substances 14. Transport information ADR Not dangerous goods RID Not dangerous goods IATA Not dangerous goods IMDG Not dangerous goods Special precautions for user see chapter: 6, 7 and 8 8/9

9 Print Date: Revsion Date: : Seite 9 von Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture VOC: 0 % Directive 96/82/EC: Update: 2003 Directive 96/82/EC does not apply 15.2 Chemical Safety Assessment 16. Other information Full text of R-phrases referred to under sections 2 and 3 R22 R63 Harmful if swallowed. Possible risk of harm to the unborn child. Full text of H-Statements referred to under sections 2 and 3. H302 Harmful if swallowed. H361d Suspected of damaging the unborn child. Other information Sk skin Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. Identifies the possibility of significant uptake through the skin The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. 9/9