Equilibrium Constants The following equilibrium constants will be useful for some of the problems.

Save this PDF as:
 WORD  PNG  TXT  JPG

Size: px
Start display at page:

Download "Equilibrium Constants The following equilibrium constants will be useful for some of the problems."

Transcription

1 1 CH302 Exam 4 Practice Problems (buffers, titrations, Ksp) Equilibrium Constants The following equilibrium constants will be useful for some of the problems. Substance Constant Substance Constant HCO 2 H K a = H 2 CO 3 K 1 = HNO 2 K a = K 2 = HOCl K a = (COOH) 2 K 1 = HF K a = K 2 = HCN K a = CH 3 COOH K a = H 2 SO 4 K 1 = very large C 6 H 5 NH 2 K b = K 2 = NH 3 K b = HOBr K a = Refer to Equilibrium Constants. The nonionized form of an acid indicator is yellow, and its anion is blue. The K a of this indicator is What will be the approximate ph range over which this indicator changes color? a. 3-5 d b. 4-6 e c Refer to Equilibrium Constants. The equivalence point of the titration of an unknown base with HCl is at ph = What would be the K a for the best choice of an indicator for this titration? a d b e c Refer to Equilibrium Constants. What is the ph at the point in a titration at which ml of M KOH has been added to ml of M HBr? a d b e c Refer to Equilibrium Constants. Which titration curve could describe the titration of a solution of HCl by addition of a solution of KOH? a. b. c.

2 2 d. e. 5.Refer to Equilibrium Constants. Which indicator could be used to titrate aqueous NH 3 with HCl solution? Acid Range Color ph Range Basic Range Color a. pink yellow b. blue yellow c. yellow purple d. colorless red e. none of these indicators 6.Refer to Equilibrium Constants. Calculate the ph of a solution prepared by adding 60.0 ml of M NaOH to 100. ml of M CH 3 COOH solution. a d b e c Refer to Equilibrium Constants. Calculate the ph of a solution resulting from the addition of 50.0 ml of 0.30 M HNO 3 to 50.0 ml of 0.30 M NH 3. a d b e c Refer to Equilibrium Constants. Which of the following titrations could the following curve describe? a. NaOH added to HF d. KOH added to HClO 4 b. HCl added to aqueous NH 3 e. HNO 3 added to NaOH c. CH 3 COOH added to aqueous NH 3 9.Refer to Equilibrium Constants. When a weak base is titrated with a strong acid, the ph at the equivalence point is always. a. 7 b. < 7 c. > 7 d. < 1 e. > Refer to Equilibrium Constants. Consider the titration of a solution of a weak acid by adding a solution of a strong base. Which response includes all the following statements that are true, and no others?

3 3 a. The end-point cannot be detected using an indicator. b. The ph at the equivalence point is c. The solution is buffered before the equivalence point. d. The solution is buffered both before and after the equivalence point. e. Methyl orange (ph color range ) would be a better indicator for this titration than would thymol blue (ph range ). 11.Which of the following solubility product expressions is incorrect? a. = [Ag + ] 2 [S 2- ] b. = [Ca 2+ ][F - ] 2 c. = [Sb 2+ ] 3 [S 3- ] 2 d. = [Cu 2+ ][S 2- ] e. = [Ag + ] 3 [PO 3-4 ] 12.How is the K sp of Ca 3 (PO 4 ) 2 related to s, the molar solubility of Ca 3 (PO 4 ) 2? a. K sp = 4s 5 d. K sp = 54s 4 b. K sp = 27s 3 e. K sp = 108s 5 c. K sp = 18s 5 13.Calculate the solubility product constant for aluminum hydroxide. Its molar solubility is mole per liter at 25 C. a d b e c The solubility of Fe(OH) 2 is g in 2.00 liters at 18 C. What is its K sp at 18 C? a d b e c The solubility of cobalt(iii) hydroxide is 54 pg/100. ml of water at 25 C. Calculate the K sp for cobalt(iii) hydroxide at 25 C. a d b e c The K sp for magnesium arsenate is at 25 C. What is the molar solubility of Mg 3 (AsO 4 ) 2 at 25 C? a M d M b M e M c M 17.Calculate the concentration of OH - ions in a saturated Mn(OH) 2 solution. The solubility product for Mn(OH) 2 is a M d M b M e M c M 18.Calculate the ph in a saturated Mn(OH) 2 solution. The solubility product for Mn(OH) 2 is a. 9.0 d. 9.5 b. 9.2 e. 9.7 c Calculate the concentration of F - ions in saturated CaF 2 solution at 25 C. K sp = a M d M b M e M c M 20.What mass of Zn(OH) 2 is contained in 1.0 liter of saturated solution? K sp =

4 a g d g b g e g c g 21.The solubility product constant for MgF 2 is How many grams of MgF 2 will dissolve in 150 ml of H 2 O at 25 C? a g d g b g e g c g 22.What concentration of aqueous NH 3 is necessary to just start precipitation of Mn(OH) 2 from a M solution MnSO 4? K b for NH 3 is and K sp for Mn(OH) 2 is a M b M c M d M e M 23.If 1.0 liter of solution is to be made M in Mg(NO 3 ) 2 and 0.10 M in aqueous ammonia, how many moles of NH 4 Cl are necessary to prevent the precipitation of magnesium hydroxide? The solubility product for Mg(OH) 2 is , and the ionization constant for aqueous ammonia is a mol b mol c mol d mol e mol 4

5 CH302 Exam 4 Practice Problems (buffers, titrations, Ksp) Answer Section 5 MULTIPLE CHOICE 1. ANS: C PTS: 1 TOP: Acid-Base Indicators 2. ANS: D PTS: 1 TOP: Acid-Base Indicators 3. ANS: B PTS: 1 TOP: Strong Acid/Strong Base Titration Curves 4. ANS: B PTS: 1 TOP: Strong Acid/Strong Base Titration Curves 5. ANS: B PTS: 1 6. ANS: B PTS: 1 7. ANS: D PTS: 1 8. ANS: B PTS: 1 9. ANS: B PTS: ANS: C PTS: ANS: C PTS: 1 TOP: Solubility Product Constants 12. ANS: E PTS: 1 TOP: Determination of Solubility Product Constants 13. ANS: E PTS: 1 TOP: Determination of Solubility Product Constants 14. ANS: D PTS: 1 TOP: Determination of Solubility Product Constants 15. ANS: C PTS: 1 TOP: Determination of Solubility Product Constants 16. ANS: C PTS: 1 TOP: Uses of Solubility Product Constants 17. ANS: E PTS: 1 TOP: Uses of Solubility Product Constants 18. ANS: E PTS: 1 TOP: Uses of Solubility Product Constants 19. ANS: B PTS: 1 TOP: Uses of Solubility Product Constants 20. ANS: B PTS: 1 TOP: Uses of Solubility Product Constants 21. ANS: A PTS: 1 TOP: Uses of Solubility Product Constants 22. ANS: D PTS: 1 TOP: Simultaneous Equilibria Involving Slightly Soluble Compounds 23. ANS: E PTS: 1 TOP: Simultaneous Equilibria Involving Slightly Soluble Compounds

CH302 Exam 4 Practice Problems (buffers, titrations, Ksp)

CH302 Exam 4 Practice Problems (buffers, titrations, Ksp) CH302 Exam 4 Practice Problems (buffers, titrations, Ksp) 1 Equilibrium Constants The following equilibrium constants will be useful for some of the problems. Substance Constant Substance Constant HCO

More information

16. What is the H 3 O + concentration of a solution that has an OH concentration of 1 10 3 M? 1) 1 10 4 M 3) 1 10 11 M

16. What is the H 3 O + concentration of a solution that has an OH concentration of 1 10 3 M? 1) 1 10 4 M 3) 1 10 11 M 1. If the [OH ] = 1 10 4 at 298 K for a given solution, the [H + ] of the solution is equal to 1) 1 10 14 3) 1 10 6 2) 1 10 10 4) 1 10 4 2. Based on Reference Table V, which is the strongest base? 1) NO

More information

Chapter 16 Acid-Base Equilibria and Solubility Equilibria

Chapter 16 Acid-Base Equilibria and Solubility Equilibria Chapter 16 Acid-Base Equilibria and Solubility Equilibria Student: NOTE: A table of ionization constants and K a 's is required to work some of the problems in this chapter. 1. In which one of the following

More information

CHAPTER 9. ANS: a. ANS: d. ANS: c. ANS: a. ANS: c

CHAPTER 9. ANS: a. ANS: d. ANS: c. ANS: a. ANS: c CHAPTER 9 1. Which one of the following is the acid in vinegar? a. acetic acid b. citric acid c. muriatic acid d. ascorbic acid 2. Which is a basic or alkaline substance? a. gastric fluid b. black coffee

More information

Titrations. Acid-Base Indicators and Titration Curves. Shapes of Titration Curves. A titration curve is a graphical history of a titration

Titrations. Acid-Base Indicators and Titration Curves. Shapes of Titration Curves. A titration curve is a graphical history of a titration Acid-Base Indicators and Titration Curves Titrations In a titration a solution of accurately known concentration is added gradually added to another solution of unknown concentration until the chemical

More information

Buffer Solutions. Buffer Solutions

Buffer Solutions. Buffer Solutions Chapter 18 Common Ion Effect Buffers and Titration Curves A/B Titrations Salts and Solubility Product The Common Ion Effect and If a solution is made in which the same ion is produced by two different

More information

CHM1 Review for Exam 12

CHM1 Review for Exam 12 Topics Solutions 1. Arrhenius Acids and bases a. An acid increases the H + concentration in b. A base increases the OH - concentration in 2. Strong acids and bases completely dissociate 3. Weak acids and

More information

CHEM 102: Sample Test 5

CHEM 102: Sample Test 5 CHEM 102: Sample Test 5 CHAPTER 17 1. When H 2 SO 4 is dissolved in water, which species would be found in the water at equilibrium in measurable amounts? a. H 2 SO 4 b. H 3 SO + 4 c. HSO 4 d. SO 2 4 e.

More information

CHAPTERS 15 FAKE TEST QUESTIONS. 1. According to the Brønsted Lowry definition, which species can function both as an acid and as a base?

CHAPTERS 15 FAKE TEST QUESTIONS. 1. According to the Brønsted Lowry definition, which species can function both as an acid and as a base? You might need to know the following K values: CHAPTERS 15 FAKE TEST QUESTIONS CH 3 COOH K a = 1.8 x 10 5 Benzoic Acid K a = 6.5 x 10 5 HNO 2 K a = 4.5 x 10 4 NH 3 K b = 1.8 x 10 5 HF K a = 7.2 x 10 4

More information

Name period Unit 9: acid/base equilibrium

Name period Unit 9: acid/base equilibrium Name period Unit 9: acid/base equilibrium 1. What is the difference between the Arrhenius and the BronstedLowry definition of an acid? Arrhenious acids give H + in water BronstedLowry acids are proton

More information

Solubility Equilibria

Solubility Equilibria Chapter 17: Acid-Base Equilibria and Solubility Equilibria Key topics: Common ion effect Buffers Acid-base equilibria Solubility equilibria; complex ion formation The Common Ion Effect If we have two solutes

More information

General Chemistry II Chapter 20

General Chemistry II Chapter 20 1 General Chemistry II Chapter 0 Ionic Equilibria: Principle There are many compounds that appear to be insoluble in aqueous solution (nonelectrolytes). That is, when we add a certain compound to water

More information

AP Chemistry- Acids and Bases General Properties of Acids and Bases. Bases- originally defined as any substance that neutralized an acid

AP Chemistry- Acids and Bases General Properties of Acids and Bases. Bases- originally defined as any substance that neutralized an acid AP Chemistry Acids and Bases General Properties of Acids and Bases Acids Electrolyte Taste Litmus Phenolphthalein React with metals to give off H 2 gas H 2 SO 4 (aq) + Mg (s) MgSO 4 (aq) + H 2 (g) Ionize

More information

Note: (H 3 O + = hydronium ion = H + = proton) Example: HS - + H 2 O H 3 O + + S 2-

Note: (H 3 O + = hydronium ion = H + = proton) Example: HS - + H 2 O H 3 O + + S 2- AcidBase Chemistry Arrhenius acid: Substance that dissolves in water and provides H + ions Arrhenius base: Substance that dissolves in water and provides OH ions Examples: HCl H + and Cl Acid NaOH Na +

More information

Chapter 7 Mixtures of Acids and Bases

Chapter 7 Mixtures of Acids and Bases Chapter 7 Mixtures of Acids and Bases Introduction In Chapter 6, we examined the equilibrium concentrations in solutions of acids and solutions of bases. In this chapter, we continue our discussion of

More information

WEAK ACIDS AND BASES

WEAK ACIDS AND BASES WEAK ACIDS AND BASES [MH5; Chapter 13] Recall that a strong acid or base is one which completely ionizes in water... In contrast a weak acid or base is only partially ionized in aqueous solution... The

More information

V. POLYPROTIC ACID IONIZATION. NOTICE: K a1 > K a2 > K a3 EQUILIBRIUM PART 2. A. Polyprotic acids are acids with two or more acidic hydrogens.

V. POLYPROTIC ACID IONIZATION. NOTICE: K a1 > K a2 > K a3 EQUILIBRIUM PART 2. A. Polyprotic acids are acids with two or more acidic hydrogens. EQUILIBRIUM PART 2 V. POLYPROTIC ACID IONIZATION A. Polyprotic acids are acids with two or more acidic hydrogens. monoprotic: HC 2 H 3 O 2, HCN, HNO 2, HNO 3 diprotic: H 2 SO 4, H 2 SO 3, H 2 S triprotic:

More information

Today. How to solve all acid/base problems (except the ones we ll do next week) Strong Acid Weak Acid Buffer Weak Base Strong Base

Today. How to solve all acid/base problems (except the ones we ll do next week) Strong Acid Weak Acid Buffer Weak Base Strong Base Today How to solve all acid/base problems (except the ones we ll do next week) Strong Acid Weak Acid Buffer Weak Base Strong Base If you re having trouble go step by step 1. Remove the spectator ions (Na

More information

ph: Measurement and Uses

ph: Measurement and Uses ph: Measurement and Uses One of the most important properties of aqueous solutions is the concentration of hydrogen ion. The concentration of H + (or H 3 O + ) affects the solubility of inorganic and organic

More information

KEY. Practice Problems: Applications of Aqueous Equilibria

KEY. Practice Problems: Applications of Aqueous Equilibria Practice Problems: Applications of Aqueous Equilibria KEY CHEM 1B 1. Ammonia (NH 3 ) is a weak base with a K b = 1.8 x 1 5. a) Write the balanced chemical equation for the reaction of ammonia with water.

More information

TOPIC 11: Acids and Bases

TOPIC 11: Acids and Bases TOPIC 11: Acids and Bases ELECTROLYTES are substances that when dissolves in water conduct electricity. They conduct electricity because they will break apart into Ex. NaCl(s)! Na + (aq) + Cl - (aq), and

More information

1. For the equilibrium that exists in an aqueous solution of nitrous acid (HNO 2, a weak acid), the equilibrium constant expression is:

1. For the equilibrium that exists in an aqueous solution of nitrous acid (HNO 2, a weak acid), the equilibrium constant expression is: 1. For the equilibrium that exists in an aqueous solution of nitrous acid (HNO 2, a weak acid), the equilibrium constant expression is: a) K = [H+ ][NO 2 ] [HNO 2 ] b) K = [H+ ][N][O] 2 [HNO 2 ] c) K =

More information

Notes: Acids and Bases

Notes: Acids and Bases Name Chemistry Pre-AP Notes: Acids and Bases Period I. Describing Acids and Bases A. Properties of Acids taste ph 7 Acids change color of an (e.g. blue litmus paper turns in the presence of an acid) React

More information

1. Read P. 368-375, P. 382-387 & P. 429-436; P. 375 # 1-11 & P. 389 # 1,7,9,12,15; P. 436 #1, 7, 8, 11

1. Read P. 368-375, P. 382-387 & P. 429-436; P. 375 # 1-11 & P. 389 # 1,7,9,12,15; P. 436 #1, 7, 8, 11 SCH3U- R.H.KING ACADEMY SOLUTION & ACID/BASE WORKSHEET Name: The importance of water - MAKING CONNECTION READING 1. Read P. 368-375, P. 382-387 & P. 429-436; P. 375 # 1-11 & P. 389 # 1,7,9,12,15; P. 436

More information

Copyright 2009 by Pearson Education, Inc. Upper Saddle River, New Jersey 07458 All rights reserved.

Copyright 2009 by Pearson Education, Inc. Upper Saddle River, New Jersey 07458 All rights reserved. Sample Exercise 17.1 Calculating the ph When a Common Ion is Involved What is the ph of a solution made by adding 0.30 mol of acetic acid and 0.30 mol of sodium acetate to enough water to make 1.0 L of

More information

Buffer Solutions. Buffer Solutions

Buffer Solutions. Buffer Solutions Buffer Solutions ph of solution adding 0.10 M HCl to 100 ml water HCl added ph 0 ml 7.00 2 ml 2.71 5 ml 2.32 10 ml 2.04 20 ml 1.78 50 ml 1.48 7 6 5 4 3 2 1 0 10 20 30 40 50 ml of 0.10 M HCl added Buffer

More information

Auto-ionization of Water

Auto-ionization of Water 2H 2 O H 3 O + + OH Hydronium ion hydroxide ion Q: But how often does this happen? This is the fundamental concept of all acid-base chemistry In pure water, how much of it is water and how much is ions?

More information

Name: Per: Date: Unit 11 - Acids, Bases and Salts Chemistry Accelerated Chemistry I Define each of the following: 1. Acidic hydrogens.

Name: Per: Date: Unit 11 - Acids, Bases and Salts Chemistry Accelerated Chemistry I Define each of the following: 1. Acidic hydrogens. Name: Per: Date: Unit 11 - Acids, Bases and Salts Chemistry Accelerated Chemistry I Define each of the following: 1. Acidic hydrogens 2. Binary acids 3. Oxyacids 4. Carboxylic acid 5. Amines Name the following

More information

Q.1 Classify the following according to Lewis theory and Brønsted-Lowry theory.

Q.1 Classify the following according to Lewis theory and Brønsted-Lowry theory. Acid-base A4 1 Acid-base theories ACIDS & BASES - IONIC EQUILIBRIA 1. LEWIS acid electron pair acceptor H, AlCl 3 base electron pair donor NH 3, H 2 O, C 2 H 5 OH, OH e.g. H 3 N: -> BF 3 > H 3 N BF 3 see

More information

Acid and Base Multiple Choice

Acid and Base Multiple Choice Acid and Base Multiple Choice January 1999 21. Consider the following acidbase equilibrium: HCO 3 + H 2 O H 2 CO 3 + OH In the reaction above, the BrönstedLowry acids are A. H 2 O and OH B. HCO 3 and OH

More information

AMHS AP Chemistry Multiple Choice questions

AMHS AP Chemistry Multiple Choice questions 1 Aqueous Equilibria: Buffers & Titrations AMHS AP Chemistry Multiple Choice questions Name Common-Ion Effect 1) The ph of a solution that contains 0.818 M acetic acid (K a = 1.77x10-5 ) and 0.172 M sodium

More information

Chapter 16: Acid-Base Equilibria

Chapter 16: Acid-Base Equilibria Chapter 16: Acid-Base Equilibria In the 1 st half of this chapter we will focus on the equilibria that exist in aqueous solutions containing: weak acids polyprotic acids weak bases salts use equilibrium

More information

CHEM 101/105 Aqueous Solutions (continued) Lect-07

CHEM 101/105 Aqueous Solutions (continued) Lect-07 CHEM 101/105 Aqueous Solutions (continued) Lect-07 aqueous acid/base reactions a. a little bit more about water Water is a polar substance. This means water is able to "solvate" ions rather well. Another

More information

ph of strong acid and base

ph of strong acid and base ph of strong acid and base What does strong mean in terms of acids and bases? Solubility. Basically, if you say an acid or base is strong, then it dissociates 100% in water. These types of situations are

More information

ionic substances (separate) based on! Liquid Mixtures miscible two liquids that and form a immiscible two liquids that form a e.g.

ionic substances (separate) based on! Liquid Mixtures miscible two liquids that and form a immiscible two liquids that form a e.g. Unit 7 Solutions, Acids & Bases Solution mixture + solvent - substance present in the amount solute - in the solvent solvent molecules solute particles ionic substances (separate) based on! Liquid Mixtures

More information

QUESTION (2012:3) (a) (i) Complete the table below showing the conjugate acids and bases. CO 3 H 2 O OH HCN CN -

QUESTION (2012:3) (a) (i) Complete the table below showing the conjugate acids and bases. CO 3 H 2 O OH HCN CN - QUESTION (2012:3) (i) Complete the table below showing the conjugate acids and bases. Conjugate acid Conjugate base - HCO 3 2 CO 3 H 2 O OH HCN CN - (ii) HPO 4 2 (aq) Write equations for the reactions

More information

Acid/base Definitions. Acid/Base Definitions. Acid / Base Chemistry. Acid/Base Definitions. Identifying Acids and Bases

Acid/base Definitions. Acid/Base Definitions. Acid / Base Chemistry. Acid/Base Definitions. Identifying Acids and Bases Acids Identifying Acids and Bases Acid (anhydrides) contains H+ ions as the cation, with and other element as the anion Non-metal oxide H2SO4 HI P2O5 Bases Base (anhydrides) Contains OH- as the anion Combined

More information

UNIT (6) ACIDS AND BASES

UNIT (6) ACIDS AND BASES UNIT (6) ACIDS AND BASES 6.1 Arrhenius Definition of Acids and Bases Definitions for acids and bases were proposed by the Swedish chemist Savante Arrhenius in 1884. Acids were defined as compounds that

More information

1. Identify the Bronsted-Lowry acids and bases and the conjugate acid base pairs in the following reactions.

1. Identify the Bronsted-Lowry acids and bases and the conjugate acid base pairs in the following reactions. Exercise #1 Brønsted-Lowry s and Bases 1. Identify the Bronsted-Lowry acids and bases and the conjugate acid base pairs in the following reactions. (a) HCl(aq) + H 2 O(l) H 3 O + (aq) + Cl (aq) (b) H 2

More information

Lecture 6. Classes of Chemical Reactions

Lecture 6. Classes of Chemical Reactions Lecture 6 Classes of Chemical Reactions Lecture 6 Outline 6.1 The Role of Water as a Solvent 6.2 Precipitation Reactions 6.3 Acid-Base Reactions 1 Electron distribution in molecules of H 2 and H 2 O The

More information

Answer the following questions on notebook paper, to be collected and graded for correctness.

Answer the following questions on notebook paper, to be collected and graded for correctness. nswer the following questions on notebook paper, to be collected and graded for correctness. 1. Name the following binary acids: a. HCl hydrochloric acid b. HF hydrofluoric acid c. H 2 S hydrosulfuric

More information

Experiment 16-Acids, Bases and ph

Experiment 16-Acids, Bases and ph Definitions acid-an ionic compound that releases or reacts with water to form hydrogen ion (H + ) in aqueous solution. They taste sour and turn litmus red. Acids react with certain metals such as zinc,

More information

Chapter 16 Acid-Base Equilibria

Chapter 16 Acid-Base Equilibria Chapter 16 AcidBase Equilibria Acids and bases are found in many common substances and are important in life processes. Group Work: Make a list of some common acids and bases. How do we know which is which?

More information

6) Which compound is manufactured in larger quantities in the U.S. than any other industrial chemical?

6) Which compound is manufactured in larger quantities in the U.S. than any other industrial chemical? MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) Which statement concerning Arrhenius acid-base theory is not correct? A) Acid-base reactions must

More information

CHEM 10123/10125, Exam 2

CHEM 10123/10125, Exam 2 CHEM 10123/10125, Exam 2 March 7, 2012 (50 minutes) Name (please print) Please box your answers, and remember that significant figures, phases (for chemical equations), and units do count! 1. (13 points)

More information

Stoichiometry and Aqueous Reactions (Chapter 4)

Stoichiometry and Aqueous Reactions (Chapter 4) Stoichiometry and Aqueous Reactions (Chapter 4) Chemical Equations 1. Balancing Chemical Equations (from Chapter 3) Adjust coefficients to get equal numbers of each kind of element on both sides of arrow.

More information

AP*Chemistry Solubility Equilibria

AP*Chemistry Solubility Equilibria AP*Chemistry Solubility Equilibria SOLUBILITY EQUILIBRIA (K sp, THE SOLUBILITY PRODUCT) Saturated solutions of salts are another type of chemical equilibria. Remember those solubility rules? The fine print

More information

Chemistry 212 EXAM 2 February 17, 2004 KEY

Chemistry 212 EXAM 2 February 17, 2004 KEY 1 Chemistry 212 EXAM 2 February 17, 2004 100_ (of 100) KEY Name Part 1: Multiple Choice. (1 point 4. The equilibrium constant for the each, circle only one answer, reaction 1. For the equilibrium that

More information

Test 12: Review questions

Test 12: Review questions Name: Wednesday, April 16, 2008 Test 12: Review questions 1. Which reaction represents the process of neutralization? 1. Mg(s) + 2HCl(aq) MgCl 2(aq) + H 2(g) 2. HCl(aq) + KOH(aq) KCl(aq) + H2O(l) 3. Pb(NO

More information

Chemistry 12 Review Sheet on Unit 3 Solubility of Ionic Substances

Chemistry 12 Review Sheet on Unit 3 Solubility of Ionic Substances Chemistry 12 Review Sheet on Unit 3 Solubility of Ionic Substances 1. Identify each of the following as ionic or molecular substances: a) NaCl (aq)... b) CH 3 COOH (aq)... c) CCl 4(l)... d) HNO 3(aq)...

More information

For weak bases alone in water: [H + ] = K a

For weak bases alone in water: [H + ] = K a General Chemistry II Jasperse Buffers/Titrations/Solubility. Extra Practice Problems 1 General Types/Groups of problems: Buffers General p1 Titration Graphs and Recognition p10 What Kind of Solution/pH

More information

Chapter 19: Acids and Bases Homework Packet (50 pts) Name: Score: / 50

Chapter 19: Acids and Bases Homework Packet (50 pts) Name: Score: / 50 Chapter 19: Acids and Bases Homework Packet (50 pts) Topic pg Section 19.1 1-3 Section 19.2 3-6 Section 19.3 6-7 Section 19.4 8 Naming Acids 9 Properties of Acids/Bases 10-11 Conjugate Acid/Base Pairs

More information

2) The equilibrium constant is given for two of the reactions below. Determine the value of the missing equilibrium constant. AB(g) + A(g) A2B(g) K c

2) The equilibrium constant is given for two of the reactions below. Determine the value of the missing equilibrium constant. AB(g) + A(g) A2B(g) K c 1) Which of the following statements is FALSE? A) When K >> 1, the forward reaction is favored and essentially goes to completion. B) When K

More information

HNO 3(aq) + NO (g) b) (1 pt) Would the equilibrium in reaction (b) be shifted to the right by raising or lowering the temperature?

HNO 3(aq) + NO (g) b) (1 pt) Would the equilibrium in reaction (b) be shifted to the right by raising or lowering the temperature? ) To make nitric acid (HN 3 ), in industry, the following process is used: NH 3(g) + 2(g) N (g) + H 2 (g) (a) N (g) + 2(g) N 2 (g) ΔH > 0 (b) N 2(g) + H 2 (l) HN 3(aq) + N (g) (c) a) (3 pts) Balance each

More information

AP Review: Predicting Reactions (Question 4) Answers

AP Review: Predicting Reactions (Question 4) Answers AP Review: Predicting Reactions (Question 4) Answers For each of the following three reactions, in part (i) write a balanced equation for the reaction and in part (ii) answer the question about the reaction.

More information

Acids and Bases. Chapter 16

Acids and Bases. Chapter 16 Acids and Bases Chapter 16 The Arrhenius Model An acid is any substance that produces hydrogen ions, H +, in an aqueous solution. Example: when hydrogen chloride gas is dissolved in water, the following

More information

CHEM 102 CLASS NOTES Prof. Upali Siriwardane, Chemistry Program, Louisiana Tech University, Ruston, LA CHAPTER 17 KEY CONCEPTS

CHEM 102 CLASS NOTES Prof. Upali Siriwardane, Chemistry Program, Louisiana Tech University, Ruston, LA CHAPTER 17 KEY CONCEPTS CHEM 102 CLASS NOTES Prof. Upali Siriwardane, Chemistry Program, Louisiana Tech University, Ruston, LA 71272 CHAPTER 17 KEY CONCEPTS ph for buffer solutions concentration of ions in buffer solutions ph

More information

Solubility Product Constant

Solubility Product Constant Solubility Product Constant Page 1 In general, when ionic compounds dissolve in water, they go into solution as ions. When the solution becomes saturated with ions, that is, unable to hold any more, the

More information

If we write these equations in ionic form, in each case the net ionic equation is the same; H 3 O + (aq) + OH - (aq) H 2H 2 O(l)

If we write these equations in ionic form, in each case the net ionic equation is the same; H 3 O + (aq) + OH - (aq) H 2H 2 O(l) CHEM 1105 ACIDS AND BASES 1. Early Definitions Taste: Effect on Indicators: Neutralization: acids - sour; bases - bitter acids turn blue litmus red; bases turn red litmus blue phenolphthalein is colourless

More information

2. Write a balanced chemical equation which corresponds to the following equilibrium constant expression. 1/2 3/ 2

2. Write a balanced chemical equation which corresponds to the following equilibrium constant expression. 1/2 3/ 2 Practice Problems for Chem. 1B Exam 1 F2011 These represent the concepts covered for exam 1. There may be some additional net ionic equations from chem. 1A. This is not the exact exam! Sections 16.1-16.3

More information

Q.1 Classify the following according to Lewis theory and Brønsted-Lowry theory.

Q.1 Classify the following according to Lewis theory and Brønsted-Lowry theory. Acid-base 2816 1 Acid-base theories ACIDS & BASES - IONIC EQUILIBRIA LEWIS acid electron pair acceptor H +, AlCl 3 base electron pair donor NH 3, H 2 O, C 2 H 5 OH, OH e.g. H 3 N: -> BF 3 > H 3 N + BF

More information

Worksheet 23 Strong Acid/Strong Base Titrations

Worksheet 23 Strong Acid/Strong Base Titrations Worksheet 2 Strong Acid/Strong Base Titrations A. Initial ph This is always determined based solely on the initial concentration of the acid or base being titrated. Every mole of acid or base will produce

More information

Chemistry 106 Fall 2007 Exam 3 1. Which one of the following salts will form a neutral solution on dissolving in water?

Chemistry 106 Fall 2007 Exam 3 1. Which one of the following salts will form a neutral solution on dissolving in water? 1. Which one of the following salts will form a neutral solution on dissolving in water? A. NaCN B. NH 4 NO 3 C. NaCl D. KNO 2 E. FeCl 3 2. Which one of the following is a buffer solution? A. 0.10 M KCN

More information

Chapter 17. How are acids different from bases? Acid Physical properties. Base. Explaining the difference in properties of acids and bases

Chapter 17. How are acids different from bases? Acid Physical properties. Base. Explaining the difference in properties of acids and bases Chapter 17 Acids and Bases How are acids different from bases? Acid Physical properties Base Physical properties Tastes sour Tastes bitter Feels slippery or slimy Chemical properties Chemical properties

More information

Review for Solving ph Problems:

Review for Solving ph Problems: Review for Solving ph Problems: Acid Ionization: HA H 2 O A - H 3 O CH 3 COOH H 2 O CH 3 COO - H 3 O Base Ionization: B H 2 O BH OH - 1) Strong Acid complete dissociation [H ] is equal to original [HA]

More information

Name: Class: Date: 2 4 (aq)

Name: Class: Date: 2 4 (aq) Name: Class: Date: Unit 4 Practice Test Multiple Choice Identify the choice that best completes the statement or answers the question. 1) The balanced molecular equation for complete neutralization of

More information

CHEM 36 General Chemistry EXAM #3 April 17, 2002

CHEM 36 General Chemistry EXAM #3 April 17, 2002 CHEM 36 General Chemistry EXAM #3 April 17, 2002 Name: Anne Sir Kei INSTRUCTIONS: Read through the entire exam before you begin. Answer all of the questions. For questions involving calculations, show

More information

Acids and Bases. When an acid loses a proton, the resulting species is its conjugate base. For example, NH 3 + H +

Acids and Bases. When an acid loses a proton, the resulting species is its conjugate base. For example, NH 3 + H + Acids and Bases Definitions An acid is a proton donor, e.g. HCl. For example, consider the reaction between HCl and H 2 O. HCl + H 2 O H 3 O + + Cl - Acid In this reaction, HCl donates a proton to H 2

More information

We were able to use the RICE expression to determine the ph for the autodissociation of water H 2 O H + + OH - with [H + ] = K w 0.

We were able to use the RICE expression to determine the ph for the autodissociation of water H 2 O H + + OH - with [H + ] = K w 0. 1 Lecture 10: The Strong Acid/Strong Base Equilibrium Calculation After an entire lecture on water with nothing added, you must be pumped to know that in this lecture something will actually be added to

More information

Aqueous Ions and Reactions

Aqueous Ions and Reactions Aqueous Ions and Reactions (ions, acids, and bases) Demo NaCl(aq) + AgNO 3 (aq) AgCl (s) Two clear and colorless solutions turn to a cloudy white when mixed Demo Special Light bulb in water can test for

More information

Acid/Base Definition. Acid/Base Reactions. Major vs. Minor Species. Terms/Items you Need to Know. you need to memorize these!!

Acid/Base Definition. Acid/Base Reactions. Major vs. Minor Species. Terms/Items you Need to Know. you need to memorize these!! Acid/Base Reactions some covalent compounds have weakly bound H atoms and can lose them to water (acids) some compounds produce OH in water solutions when they dissolve (bases) acid/base reaction are very

More information

14-Jul-12 Chemsheets A

14-Jul-12 Chemsheets A www.chemsheets.co.uk 14-Jul-12 Chemsheets A2 009 1 BRONSTED-LOWRY ACIDS & BASES Bronsted-Lowry acid = proton donor (H + = proton) Bronsted-Lowry base = proton acceptor (H + = proton) Bronsted-Lowry acid-base

More information

Titration curves. Strong Acid-Strong Base Titrations

Titration curves. Strong Acid-Strong Base Titrations Titration curves A titration is a procedure for carrying out a chemical reaction between two solutions by the controlled addition from a buret of one solution (the titrant) to the other, allowing measurements

More information

Lecture 6: Lec4a Chemical Reactions in solutions

Lecture 6: Lec4a Chemical Reactions in solutions Lecture 6: Lec4a Chemical Reactions in solutions Zumdahl 6 th Ed, Chapter 4 Sections 1-6. 4.1 Water, the Common Solvent 4.2 The Nature of Aqueous Solutions: Strong and Weak Electrolytes 4.3 The Composition

More information

Spring 2009 CH302 Practice Exam 2 Answer Key

Spring 2009 CH302 Practice Exam 2 Answer Key Spring 2009 CH302 Practice Exam 2 Answer Key 1. What would be the ph of a solution prepared by dissolving 120.1 g of CH 3 COOH and 82 g of NaCH 3 COO in 1 L of water? Acetic acid has a K a of 1.8 x 10

More information

Types of Reactions. What are Acids &Bases? Chapter 15. Acids & Bases. Definition? a) Arrhenius. b) Bronsted-Lowry. c) Lewis

Types of Reactions. What are Acids &Bases? Chapter 15. Acids & Bases. Definition? a) Arrhenius. b) Bronsted-Lowry. c) Lewis Chapter 15. Acids & Bases Acid/Base Definitions Types of Acids/bases Polyprotic Acids The Ion Product for Water The ph and Other p Scales Aqueous Solutions of Acids and Bases Hydrolysis The Common Ion

More information

Reactions in solution. A subset of chemical reactions

Reactions in solution. A subset of chemical reactions Reactions in solution A subset of chemical reactions Learning objectives Define solution and its components Distinguish among strong, weak and non-electrolyte Identify strong acids and strong bases Apply

More information

Chapter 14: Acids and Bases

Chapter 14: Acids and Bases Ch 14 Page 1 Chapter 14: Acids and Bases Properties of Acids Sour taste React with some metals Turns blue litmus paper red React with bases Some Common Acids HCl, hydrochloric acid H 2 SO 4, sulfuric acid

More information

Determination of K a and Identification of an Unknown Weak Acid

Determination of K a and Identification of an Unknown Weak Acid 1 Determination of K a and Identification of an Unknown Weak Acid Introduction Purpose: To determine the molar mass and acid dissociation constant K a for an unknown weak acid and thereby identify the

More information

Solubility of Salts - Ksp. Ksp Solubility

Solubility of Salts - Ksp. Ksp Solubility Solubility of Salts - Ksp We now focus on another aqueous equilibrium system, slightly soluble salts. These salts have a Solubility Product Constant, K sp. (We saw this in 1B with the sodium tetraborate

More information

UNIT 14 - Acids & Bases

UNIT 14 - Acids & Bases COMMON ACIDS NOTES lactic acetic phosphoric citric malic PROPERTIES OF ACIDS 1. 1. PROPERTIES OF BASES 2. 2. 3. 3. 4. 4. 5. 5. NAMING ACIDS NOTES Binary acids (H + one element) Practice: 1. hydro- - HF

More information

Chapter 17. The best buffer choice for ph 7 is NaH 2 PO 4 /Na 2 HPO 4. 19)

Chapter 17. The best buffer choice for ph 7 is NaH 2 PO 4 /Na 2 HPO 4. 19) Chapter 17 2) a) HCl and CH 3 COOH are both acids. A buffer must have an acid/base conjugate pair. b) NaH 2 PO 4 and Na 2 HPO 4 are an acid/base conjugate pair. They will make an excellent buffer. c) H

More information

Chem 321 Lecture 13 - Acid-Base Titrations 10/10/13

Chem 321 Lecture 13 - Acid-Base Titrations 10/10/13 Student Learning Objectives Chem 321 Lecture 13 - Acid-Base Titrations 10/10/13 Indicators A common end point for acid-base titrations is the color change associated with an acid-base indicator. An acid-base

More information

AP* Chemistry Solubility Equilibrium

AP* Chemistry Solubility Equilibrium AP* Chemistry Solubility Equilibrium SOLUBILITY EQUILIBRIA (The Solubility-Product Constant, K sp ) We ve got good news and we ve got bad news Which do you want first? The good news: Solubility equilibrium

More information

Chemical equilibria Buffer solutions

Chemical equilibria Buffer solutions Chemical equilibria Buffer solutions Definition The buffer solutions have the ability to resist changes in ph when smaller amounts of acid or base is added. Importance They are applied in the chemical

More information

Chapter 15: Acids, Bases, and Salts. 15.1: Acids and Bases

Chapter 15: Acids, Bases, and Salts. 15.1: Acids and Bases Chapter 15: Acids, Bases, and Salts Name: 15.1: Acids and Bases Define an Acid: Define a Base: Ex of an acid in aqueous solution: Ex of a base in aqueous solution: List some of the properties of acids

More information

MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question.

MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. A.P. Chemistry Practice Test: Ch. 14, Acids and Bases Name MULTIPLE CHOICE. Choose the one alternative that best completes the statement or answers the question. 1) The conjugate base of HSO4 - is A) H2SO4

More information

Experiment # 6 Determining the percent composition of a mixture by acid-base

Experiment # 6 Determining the percent composition of a mixture by acid-base Experiment # 6 Determining the percent composition of a mixture by acid-base Objective Determine the percent composition of a mixture of sodium carbonate (Na 2 CO 3 ), sodium bicarbonate (NaHCO 3 ) and

More information

(100%ionization) O + ] ][H 3 = [CO 2! 3 HCO 3 = [H 2 CO 3 ][OH! ] O + ][OH " ] = [H 3

(100%ionization) O + ] ][H 3 = [CO 2! 3 HCO 3 = [H 2 CO 3 ][OH! ] O + ][OH  ] = [H 3 Page 1 of 5 Chem201 Winter 2006 I. Introduction EQUILIBRIUM CALCULATIONS A. Equilibria in aqueous solutions are usually more complicated than the "simple" cases we have discussed so far. B. Multiple equilibria

More information

Acids and Bases: A Brief Review

Acids and Bases: A Brief Review Acids and : A Brief Review Acids: taste sour and cause dyes to change color. : taste bitter and feel soapy. Arrhenius: acids increase [H ] bases increase [OH ] in solution. Arrhenius: acid base salt water.

More information

CHEMISTRY 101 EXAM 3 (FORM A) DR. SIMON NORTH

CHEMISTRY 101 EXAM 3 (FORM A) DR. SIMON NORTH CHEMISTRY 101 EXAM 3 (FORM A) DR. SIMON NORTH 1. When considering conjugate acids and bases, (2 points) a) Strong acids have strong conjugate bases. b) Strong bases have strong conjugate acids. c) Weak

More information

CHEMISTRY 101 EXAM 3 (FORM B) DR. SIMON NORTH

CHEMISTRY 101 EXAM 3 (FORM B) DR. SIMON NORTH 1. Is H 3 O + polar or non-polar? (1 point) a) Polar b) Non-polar CHEMISTRY 101 EXAM 3 (FORM B) DR. SIMON NORTH 2. The bond strength is considerably greater in HF than in the other three hydrogen halides

More information

Worksheet 4-2 Bronsted Acids and Equilibria

Worksheet 4-2 Bronsted Acids and Equilibria Worksheet 42 Bronsted Acids and Equilibria Worksheet 42 Bronsted Acids and Equilibria Name Date Due Hand In With Corrections by 1. Write the formula for a proton 2. Write the formula for a hydrated proton

More information

Ch 8.5 Solution Concentration Units % (m/m or w/w) = mass of solute x 100 total mass of solution mass of solution = mass solute + mass solvent

Ch 8.5 Solution Concentration Units % (m/m or w/w) = mass of solute x 100 total mass of solution mass of solution = mass solute + mass solvent 1 Ch 8.5 Solution Concentration Units % (m/m or w/w) = mass of solute x 100 total mass of solution mass of solution = mass solute + mass solvent % (v/v) = volume of solute x 100 volume of solution filled

More information

Review of Basic Concepts, Molarity, Solutions, Dilutions and Beer s Law

Review of Basic Concepts, Molarity, Solutions, Dilutions and Beer s Law Review of Basic Concepts, Molarity, Solutions, Dilutions and Beer s Law Aqueous Solutions In Chemistry, many reactions take place in water. This is also true for Biological processes. Reactions that take

More information

For weak bases alone in water: [H + ] = K a

For weak bases alone in water: [H + ] = K a General Chemistry II Jasperse Buffers/itrations/Solubility. Extra Practice Problems 1 General ypes/groups of problems: Buffers General p1 itration Graphs and Recognition p10 What Kind of Solution/pH at

More information

An acid is a substance that produces H + (H 3 O + ) Ions in aqueous solution. A base is a substance that produces OH - ions in aqueous solution.

An acid is a substance that produces H + (H 3 O + ) Ions in aqueous solution. A base is a substance that produces OH - ions in aqueous solution. Chapter 8 Acids and Bases Definitions Arrhenius definitions: An acid is a substance that produces H + (H 3 O + ) Ions in aqueous solution. A base is a substance that produces OH - ions in aqueous solution.

More information

Talk in. Arrhenius Acid- Base Definition and ph

Talk in. Arrhenius Acid- Base Definition and ph Talk in. Arrhenius Acid Base Definition and ph When we think of acids, we typically think of the Arrhenius definition. Svante Arrhenius (18591927) Arrhenius Acid = Any compound that increases the hydronium

More information

3. Which of the following describes a conjugate acid-base pair for the following equilibrium? CN - (aq) + CH 3 NH 3 + (aq) H 2 CO 3 (aq) + H 2 O (l)

3. Which of the following describes a conjugate acid-base pair for the following equilibrium? CN - (aq) + CH 3 NH 3 + (aq) H 2 CO 3 (aq) + H 2 O (l) Acids, Bases & Redox 1 Practice Problems for Assignment 8 1. A substance which produces OH ions in solution is a definition for which of the following? (a) an Arrhenius acid (b) an Arrhenius base (c) a

More information

Module Seven Including Liquids and Solutions in Stoichiometric Calculations. Chem 170. Stoichiometric Calculations. Module Seven

Module Seven Including Liquids and Solutions in Stoichiometric Calculations. Chem 170. Stoichiometric Calculations. Module Seven Chem 170 Stoichiometric Calculations Module Seven Including Liquids and Solutions in Stoichiometric Calculations DePauw University Department of Chemistry and Biochemistry Page 1 Introduction to Module

More information