SPAN 80 Material Safety Data Sheet Date(s): : :17:05 Version 10 MSDS#: CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Transcription

1 1. CHEMICAL PRODUCT AD COMPAY IDETIFICATIO Product ame SPA 80 Product Use onionic surfactant Address/Telephone number Uniqema Uniqema Corporate Center 1000 Uniqema Boulevard ew Castle, DE Uniqema Operator (Mon.-Fri., 8:15 AM - 4:30 PM Eastern): (302) Medical Emergency (24 hr.): (888) Transportation Emergency Involving Chemical Spills, Leaks, Fires, or Accidents (24 hr.): (800) Uniqema is an international business of Imperial Chemical Industries PLC. Uniqema operates through ICI affiliated companies in the relevant countries such as ICI Americas Inc., Unichema, a division of Indopco Inc., and Mona Industries Inc. in the USA. 2. COMPOSITIO/IFORMATIO O IGREDIETS Component ame CAS umber % (w/w) OSHA PEL ACGIH TLV Sorbitan monooleate o PEL established o TLV established Ingredients not precisely identified are proprietary or nonhazardous. Values are not product specifications. 3. HAZARDS IDETIFICATIO Emergency Overview Page 1 of 9

2 Color yellow-amber Form 25 C Odor O HAZARDS ARE KOW TO BE ASSOCIATED WITH EXPOSURES TO THIS PRODUCT. Limited toxicity data are available on this specific product; this health hazard assessment is based on the results of screening tests. Routes of Exposure Eye contact Skin contact Inhalation Eye contact Skin contact Inhalation Ingestion o irritation is likely to develop following contact with human eyes. o irritation is likely to develop following contact with human skin. This product will probably not be absorbed through human skin. o irritation is expected to be associated with inhalation of this material. o toxic effects are known to be associated with inhalation of vapors from this material. This material is not likely to cause irritation upon ingestion. o toxic effects are expected following ingestion of this product. 4. FIRST AID MEASURES Eye contact Skin contact Inhalation Immediately flush with plenty of water for at least 15 minutes. If redness, itching, or a burning sensation develops, have eyes examined and treated by medical personnel. Wash material off of the skin with plenty of soap and water. If redness, itching, or a burning sensation develops, get medical attention. Remove victim to fresh air. If a cough or other respiratory symptoms develop, consult medical personnel. Page 2 of 9

3 Ingestion DO OT IDUCE VOMITIG. Give one or two glasses of water to drink and refer to medical personnel or take direction from either a physician or a poison control center. ever give anything by mouth to an unconscious person. 5. FIRE-FIGHTIG MEASURES Flash Point (ºF) Flash Point (ºC) Autoignition Temperature (ºF) Autoignition Temperature (ºC) Flammable Limits Extinguishing Media Special fire-fighting protective equipment Fire and explosion hazards Explosion data Sensitivity to mechanical impact Sensitivity to static discharge > 300 (open cup) >148.9 (open cup) Water fog, alcohol foam, carbon dioxide, dry chemical. A self contained breathing apparatus and suitable protective clothing must be worn in fire conditions. one known. ot applicable. ot applicable. 6. ACCIDETAL RELEASE MEASURES Personal precautions Steps to be taken in case material is released or spilled Refer to section 8 for proper personal protective equipment. Contain spill. Soak up material with absorbent and shovel into a chemical waste container. Wash residue from spill area with water containing detergent and flush to a sewer serviced by a permitted wastewater treatment facility. Page 3 of 9

4 7. HADLIG AD STORAGE Storage Store in original containers. 8. EXPOSURE COTROLS/PERSOAL PROTECTIO Exposure limits OSHA PEL Component ame Exposure limits otes o OSHA PEL assigned. Minimize exposure in accordance with good hygiene practice. ACGIH TLV Component ame Exposure limits otes o ACGIH TLV assigned. Minimize exposure in accordance with good hygiene practice. Engineering controls Eye protection Protective clothing Respiratory protection Other Provide adequate ventilation. Safety glasses with side shields. Impervious gloves. Respiratory protection is not normally needed if controls are adequate. Eyewash and safety shower easily accessible to the work area. 9. PHYSICAL AD CHEMICAL PROPERTIES Color yellow-amber Form 25 C Odor ph Boiling Point (ºF) > 212 Boiling Point (ºC) > 100 Flash Point (ºF) > 300 (open cup) Page 4 of 9

5 Flash Point (ºC) >148.9 (open cup) Autoignition Temperature (ºF) Autoignition Temperature (ºC) Flammable Limits Explosive Properties Oxidizing Properties Vapor Pressure (mmhg) < Vapor Density Specific Gravity ~1 Solubility (water) Insoluble Solubility (other) soluble in:, ethyl acetate, 2-ethoxyethanol, vegetable oil, mineral oil, cottonseed oil, insoluble in:, acetone, ethylene glycol, propylene glycol, slightly soluble in:, lower alcohols, diethylether, 1,4-dioxane, 1,1,1-trichloroethylene Partition Coefficient Dynamic viscosity (mpa.s) ~1000 deg.c) Density (g/ml) Freezing/melting point (ºC) Pour Point (ºF) ~3 Pour Point (ºC) ~-16.1 % Volatile by volume egligible 10. STABILITY AD REACTIVITY Stability Materials to avoid Conditions to avoid Hazardous decomposition products Hazardous polymerization Stable under normal conditions. Strong oxidizing agents. one known. Carbon dioxide, carbon monoxide. Will not occur. 11. TOXICOLOGICAL IFORMATIO Eye contact A 100% suspension of this material was tested. Skin contact Rabbit Draize 7 days Practically nonirritating. 31/08/1971 Page 5 of 9

6 A 100% suspension of this material was tested. A 100% suspension of this material was tested. Rabbit Draize 72 hours onirritating. 31/08/1971 Human Schwartz 14 days onsensitizing. 09/06/1959 Ingestion A 100% suspension of this material was tested. LD50 rat > 39.8 g/kg 14 days Relatively harmless. 23/11/1966 Chronic A chronic ingestion study in animals has shown that repeated doses produce no significant effects. 12. ECOLOGICAL IFORMATIO Persistance & Degradation (OECD 301C) (28 days)98.2 % Toxicity LC50 (96 hour) (static) rainbow trout > 1000 mg/l Effect on Effluent Treatment The product is anticipated to be substantially removed in biological treatment processes. 13. DISPOSAL COSIDERATIOS RCRA (Resource Conservation and Recovery Act) Classification: Specifically Listed ot applicable. Wastes Characteristic Wastes Ignitability ot applicable. Corrosivity ot applicable. Reactivity ot applicable. Toxicity ot applicable. Disposal method Disposal should be in accordance with local, state or national legislation. Page 6 of 9

7 Container disposal Empty container retains product residue. Observe all hazard precautions. Do not distribute, make available, furnish or reuse empty container except for storage and shipment of original product. Remove all product residue from container and puncture or otherwise destroy empty container before disposal. 14. TRASPORT IFORMATIO Department of Transportation: ot regulated. TDG (Transportation of Dangerous Goods): ot regulated. ot classified in RID/ADR - ADR - IMDG - ICAO/IATA-DGR. 15. REGULATORY IFORMATIO Inventory Status EU USA Canada Australia Japan China Korea Philippines Page 7 of 9

8 OSHA Hazard Communication Standard, 29 CFR , Hazard Summary: Health Hazards Physical Hazards one one WHMIS Classification CERCLA and SARA Regulations (40 CFR 355, 370, and 372): This material contains the following chemicals subject to the reporting requirements of SARA 313: SARA 311/312 Hazard Categories: Immediate Delayed Fire Pressure Reactivity oncontrolled (onhazardous). o 313-listed chemicals in this product 16. OTHER IFORMATIO We assigned FPA ratings and HMIS ratings to this product based on the hazards of its ingredient(s). Because the customer is most aware of the application of the product, he must ensure that the proper personal protective equipment (PPE) is provided consistent with information contained in the product MSDS. HMIS Information Health 0 Flammability 1 Page 8 of 9

9 Physical Hazards 0 The HMIS ratings displayed above are from the HMIS III Third Edition. There have been significant changes made to the system. "Physical hazard" stands for physical hazard as defined in the OSHA Hazard Communication Standard and replaces the former code for reactivity. For a more detailed explanation of the system and the ratings, please contact our Product Safety and Regulatory Affairs group. FPA Information Health 0 Flammability 1 Reactivity 0 This information is intended solely for the use of individuals trained in the particular hazard rating system. The following sections contain revisions or new statements: The information herein is given in good faith but no warranty, expressed or implied, is made. (R) is a Registered Trademark of ICI Americas. (TM) is a Trademark of ICI Americas. See also Page 9 of 9