<Product> HYDROCHLORIC ACID ; HCL, HYDROGEN CHLORIDE, MURIATIC ACID *********************** EMERGENCY PHONE #: ************************

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1 22 APR 2010 <MSDS_ID>300113</MSDS_ID> MATERIAL SAFETY DATA SHEET <Product> HYDROCHLORIC ACID ; HCL, HYDROGEN CHLORIDE, MURIATIC ACID </Product> Part#: MSDS SECTION I SUPPLIER INFORMATION Common Name : HYDROCHLORIC ACID Chemical Name/Chemical Family: NONE LISTED / NONE LISTED Formula/CAS : NONE LISTED / NONE LISTED <Supplier> TRANSCHEM </Supplier>#:8019 Address : 1259 SAFETY ENERGY DR. City, St, Zip: PORT ALLEN LA Phone: *********************** EMERGENCY PHONE #: ************************ Date Issued: Date Entered: Date Revised: SECTION II INGREDIENT INFORMATION CAS#: HYDROGEN CHLORIDE ( %) PEL: 5 PPM, CEILING TLV: 5 PPM, CEILING STEL: NONE LISTED CAS#: NOT LISTED WATER ( %) PEL: NOT LISTED TLV: NOT LISTED STEL: NONE LISTED SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS Boiling Point : CA 230 F, 110 C SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS continued on the next page. Page 1

2 22 APR 2010 MATERIAL SAFETY DATA SHEET Page 2 MSDS Id #: SECTION III PHYSICAL/CHEMICAL CHARACTERISTICS continued from previous page. Specific Gravity (H2O = 1) : Melting Point: NONE LISTED Vapor Pressure (mm Hg): 25.8 (@ 70 F) Vapor Density (Air=1): 1.2 Evaporation Rate (Butyl Acetate=1): NONE LISTED Solubility/Water: COMPLETE (IN ALL PROPORTIONS) **************************** APPEARANCE AND ODOR **************************** CLEAR, COLORLESS, OR SLIGHTLY YELLOW, FUMING LIQUID WITH SHARP, IRRITATING ODOR SECTION IV FIRE AND EXPLOSION HAZARD DATA Flash Point: DOES NOT FLASH. Auto-Ignition: NO DATA LEL: NONE UEL: NONE ************************ HMIS HAZARD CLASSIFICATION SYSTEM ************************ Flammable:0 Health:3 Reactivity:1 Special:H ************************* EXTINGUISHING MEDIA ******************************* NOT APPLICABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE. ********************* SPECIAL FIRE FIGHTING PROCEDURES ********************** SELF-CONTAINED BREATHING APPARATUS WITH FULL FACE PIECE AND PROTECTIVE CLOTHING IF INVOLVED IN A FIRE OF OTHER MATERIALS. ******************** UNUSUAL FIRE AND EXPLOSION HAZARDS ********************* REACTS WITH MANY METALS TO PRODUCE FLAMMABLE HYDROGEN GAS. FLAMMABLE LIMITS (STP): NOT APPLICABLE SECTION V REACTIVITY DATA Stability? STABLE UNDER NORMAL CONDITIONS. SECTION V Page 2 REACTIVITY DATA is continued on the next page.

3 22 APR 2010 MATERIAL SAFETY DATA SHEET Page 3 MSDS Id #: SECTION V REACTIVITY DATA is continued from the previous page. Avoid: NONE LISTED ******************* INCOMPATIBILITY (Materials to Avoid) ******************** ALKALINE MATERIALS. REACTS WITH MANY METALS TO PRODUCE FLAMMABLE HYDROGEN GAS. ******************* HAZARDOUS DECOMPOSITION OR BY-PRODUCTS ****************** HYDROGEN. Polymerization? WILL NOT OCCUR. Avoid: NONE LISTED SECTION VI HEALTH HAZARD DATA *************************** ADDITIONAL INFORMATION **************************** PHYSICAL HAZARDS: NONE HEALTH HAZARDS: INHALATION (TLV), CORROSIVE (SKIN, EYE, RESPIRATORY PASSAGES), HARMFUL (LUNG INJURY). INGREDIENTS NOT PRECISELY IDENTIFIED ARE PROPRIETARY OR NON-HAZARDOUS. ALL INGREDIENTS APPEAR ON THE EPA TSCA INVENTORY. VALUES ARE NOT PRODUCT SPECIFICATIONS. CA = APPROXIMATELY, > = GREATER THAN, < = LESS THAN. ADDITIONAL PHYSICAL DATA PH: <1 % VOLATILE BY VOLUME: 100 NFPA RATING: HEALTH - 3 FIRE - 0 REACTIVITY - 1 REGULATORY INFORMATION TSCA (TOXIC SUBSTANCE CONTROL ACT) REGULATIONS, 40CFR 710: ALL INGREDIENTS ARE ON THE TSCA SECTION 8(B) INVENTORY. SECTION VI Page 3 HEALTH HAZARD DATA is continued on the next page.

4 22 APR 2010 MATERIAL SAFETY DATA SHEET Page 4 MSDS Id #: SECTION VI HEALTH HAZARD DATA is continued from the previous page. CERCLA AND SARA REGULATIONS, 40CFR 355, 370, AND 372: THIS PRODUCT CONTAINS THE FOLLOWING CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 AND 40CFR 372: CHEMICAL CAS # % HYDROGEN CHLORIDE CA 30 STATE REGULATIONS: CALIFORNIA PROPOSITION 65: NO WARNINGS ARE NECESSARY. ****************************** CARCINOGENICITY ****************************** NTP? NO IARC? NO OSHA? NO NONE LISTED ADDITIONAL INFORMATION ********************* ACUTE AND CHRONIC HEALTH HAZARDS ********************** GENERAL: THE HEALTH HAZARD ASSESSMENT IS BASED ON AN EVALUATION OF THE CHEMICAL COMPOSITION TOGETHER WITH INFORMATION FROM A SEARCH OF THE SCIENTIFIC LITERATURE AND OTHER COMMERCIAL SOURCES. ORAL INGESTION: HARMFUL AND MAY BE FATAL. CAUSES SEVERE IRRITATION OF THE MOUTH, PHARYNX, ESOPHAGUS, AND STOMACH WITH CONSEQUENT PAIN, NAUSEA, AND VOMITING. EYE CONTACT: LIQUID AND VAPOR MAY CAUSE SEVERE BURNS TO EYES. SKIN CONTACT: LIQUID AND VAPOR MAY CAUSE SEVERE BURNS TO EXPOSED SKIN. SKIN ABSORPTION: NOT A SYSTEMIC POISON. SKIN ABSORPTION IS NOT LIKELY TO OCCUR. INHALATION: WARNING PROPERTIES ARE GOOD. INHALATION OF VAPORS MAY CAUSE COUGHING AND DIFFICULT BREATHING, RESULTING IN INFLAMMATION, ULCERATION OF NOSE, ULCERATION OF THROAT. EFFECTS OF OVEREXPOSURE: INHALATION OF VAPORS MAY CAUSE PULMONARY EDEMA, SECTION VI Page 4 HEALTH HAZARD DATA is continued on the next page.

5 22 APR 2010 MATERIAL SAFETY DATA SHEET Page 5 MSDS Id #: SECTION VI HEALTH HAZARD DATA is continued from the previous page. CIRCULATORY SYSTEM COLLASPE, DAMAGE TO UPPER RESPIRATORY SYSTEM. INHALATION OF VAPORS MAY CAUSE COUGHING AND DIFFICULTY IN BREATHING. LIQUID MAY CAUSE SEVERE BURNS TO EYES AND SKIN. INGESTION IS HARMFUL AND MAY BE FATAL. WILL CAUSE SEVERE BURNS TO MOUTH AND STOMACH. ********************* SIGNS AND SYMPTOMS OF EXPOSURE ************************ SEE "ACUTE AND CHRONIC HEALTH HAZARDS". ************ MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE ************* PRE-EXISTING LUNG DISEASE MAY BE AGGRAVATED BY EXPOSURE. ******************** EMERGENCY AND FIRST AID PROCEDURES *********************** CALL A PHYSICIAN! EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND HAVE EYES EXAMINED AND TREATED BY MEDICAL PERSONNEL. SKIN: IMMEDIATELY FLUSH SKIN WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING COMTAMINATED CLOTHING AND FOOTWEAR. IF REDNESS, ITCHING OR A BURNING SENSATION DEVELOPS, GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE WATER, MILK, OR MILK OF MAGNESIA. (NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON). INHALATION: REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING, CLEAR AIRWAY AND START MOUTH-TO-MOUTH ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN AND GET MEDICAL ATTENTION. IF A COUGH OR OTHER RESPIRATORY SYMPTOMS DEVELOP, CONSULT MEDICAL PERSONNEL. NOTE TO PHYSICIAN: MUCOSAL INJURY FOLLOWING INGESTION OF THIS POTENTIALLY CORROSIVE MATERIAL MAY CONTRAINDICATE THE INDUCTION OF VOMITING IN THE TREATMENT OF POSSIBLE INTOXICATION. SIMILARLY, IF GASTRIC LAVAGE IS PERFORMED, INTUBATION SHOULD BE DONE WITH GREAT CARE. IN CASES OF SEVERE ESOPHAGEAL CHEMICAL CORROSION, THE USE OF THERAPEUTIC DOSES OF STEROIDS SHOULD BE CONSIDERED. GENERAL SUPPORTIVE MEASURES WITH SCRUPULOUS MONITORING OF GAS EXCHANGE, ACID-BASE BALANCE, ELECTROLYTES, AND FLUID INTAKE ARE ALSO OF HIGH IMPORTANCE. SECTION VII Page 5 SAFE HANDLING AND USE is continued on the next page.

6 22 APR 2010 MATERIAL SAFETY DATA SHEET Page 6 MSDS Id #: SECTION VII SAFE HANDLING AND USE is continued from the previous page. SECTION VII PRECAUTIONS FOR SAFE HANDLING AND USE DOT Classification: NONE LISTED ********* STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED ********* WEAR SKIN, EYE, AND RESPIRATORY PROTECTION DURING CLEAN-UP. STOP LEAK IF YOU CAN DO WITHOUT RISK. CONTAIN SPILL. KEEP OUT OF SEWERS AND DRAINS. SOAK UP AND NEUTRALIZE MATERIAL WITH ABSORBENT SUCH AS SODIUM BICARBONATE, SODA ASH OR LIME. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN, DRY CONTAINER AND COVER, REMOVE FROM AREA. WASH RESIDUE FROM SPILL AREA WITH WATER AND FLUSH TO A SEWER SERVICED BY A WASTEWATER TREATMENT FACILITY. FOR TRANSPORTATION SPILL, CALL CHEMTREC (CHEMICAL TRANSPORTATION EMERGENCY CENTER), (800) ************************** WASTE DISPOSAL METHOD **************************** BECAUSE ITS PH IS 2 OR BELOW, DISCARDED MATERIAL IS A HAZARDOUS WASTE. DISPOSE OF IN A FACILITY PERMITTED FOR HAZARDOUS WASTE. EPA HAZARDOUS WASTE NUMBER: DOO2 (CORROSIVE WASTE) CONTAINER DISPOSAL: EMPTY CONTAINER RETAINS HAZARDOUS RESIDUE. OBSERVE ALL HAZARD PRECAUTIONS. DO NOT DISTRIBUTE, MAKE AVAILABLE, FURNISH OR REUSE EMPTY CONTAINER EXCEPT FOR STORAGE AND SHIPMENT OF ORIGINAL PRODUCT. REMOVE HAZARDOUS RESIDUE AND PUNCTURE OR OTHERWISE DESTROY EMPTY CONTAINER BEFORE DISPOSAL. ************** PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE ************** PREVENT EYE AND SKIN CONTACT. OBSERVE TLV/PEL LIMITATIONS. AVOID BREATHING VAPORS OR AEROSOLS. ***************************** OTHER PRECAUTIONS ***************************** NONE LISTED SECTION VIII CONTROL MEASURES SECTION VIII CONTROL MEASURES is continued on the next page. Page 6

7 22 APR 2010 MATERIAL SAFETY DATA SHEET Page 7 MSDS Id #: SECTION VIII CONTROL MEASURES is continued from the previous page. ************************ RESPIRATORY PROTECTION ***************************** IF NEEDED, USE MSHA/NIOSH RESPIRATOR APPROVED FOR ACID GASES. ******************************** VENTILATION ******************************** Local Exhaust: USE LOCAL EXHAUST TO KEEP EXPOSURES TO A MINIMUM. Special Exhaust: NONE LISTED Mechanical Exhaust: NONE LISTED Other: NONE LISTED ****************************** OTHER PROTECTION ***************************** Gloves: SEE BELOW "CLOTHING/EQUIP" Eye Protection: CHEMICAL TIGHT GOGGLES; FULL FACESHIELD IN ADDITION IF SPLASHING IS POSSIBLE. ******************************* CLOTHING ************************************ TAKE ALL PRECAUTIONS TO AVOID SKIN CONTACT. OUTSIDE CLOTHING OF ACID RESISTANT FABRICS ARE RECOMMENDED. RUBBER GLOVES AND BOOTS (RUBBERS OVER LEATHER), APRONS AND ARM COVERS SHOULD BE WORN FOR PROTECTION AGAINST ACCIDENTAL CONTACT. ADDITIONAL PROTECTION, SUCH AS FULL BODY SUIT, MAY BE REQUIRED DEPENDING ON CONDITIONS. OTHER PROTECTIVE EQUIPMENT: SAFETY SHOWER AND EYEWASH STATION IN WORK AREA. ************************** WORK/HYGIENE PRACTICES *************************** ALWAYS USE GOOD HYGIENE PRACTICES. ************************* MISCELLANEOUS INFORMATION ************************* THE INFORMATION HEREIN IS GIVEN IN GOOD FAITH BUT NO WARRANTY, EXPRESSED OR IMPLIED, IS MADE. CONSULT ORIGINAL MSDS ADDITIONAL INFORMATION. THIS IS THE END OF THE MSDS Id #300113