Götaverken Miljö AB at KTH Polish Swedish seminar. 23 May Company Presentation - Flue gas cleaning & energy recovery - Latest technologies:

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1 Götaverken Miljö AB at KTH Polish Swedish seminar 23 May Company Presentation - Flue gas cleaning & energy recovery - Latest technologies: - RESOX sulphur recirculation to improve electricity generation - CUTNOX for reduced NO x production Per Lindgren Manager Sales dpt

2 Group belonging The Babcock & Wilcox Company Babcock & Wilcox Canada Ltd B&W Construction Company, Inc. The Babcock & Wilcox Company Power Division Diamond Power Int l, Inc. B&W Delta Power Service Company Babcock & Wilcox Vølund A/S

3 Parent company - B&W Vølund State-of-the art boilers Steam boilers for saturated and superheated steam Hot-water boilers Boilers for biomass-fired plants Boilers for straw-fired plants Waste-to-Energy boilers

4 B&W Vølund Project management Technology Service Construction Production Engineering Commissioning 2008 Babcock & Wilcox Vølund A/S. All rights reserved..4

5 Reno Nord, Denmark, 2006 Sundsvall, Sweden, 2008

6 Götaverken Miljö in Short 100% Subsidiary of Babcock & Wilcox Vølund A provider of solutions within flue gas cleaning to waste incinerators, energy recovery and other Cleantech applications based on proprietary technologies Development, Engineering & contracting Plant supplier Based in Gothenburg, Sweden Strong focus on development of new technologies

7 References Flue Gas Cleaning Flue gas cleaning plants to more than 40 waste incineration plants in Sweden, Denmark, Germany and Belgium. (excluding plants up-graded with ADIOX technology) Thisted, Denmark Gas cleaning installed in 1991, up-graded with ADIOX 2003 Umeå, Dåvaverket, Sweden Flue gas cleaning, steam turbine and compressor heat pumps Probably one of the most energy-efficient waste incineration plants in the world due to the energy recovery in the flue gas cleaning

8 References ADIOX ADIOX for dioxin removal (and memory effect prevention), installed in gas cleaning systems after approximately 100 waste incinerator lines (May 2011) Tredi Salaise, France Holstebro, Denmark

9 ADIOX Referens installationer 2001 I/S Kraftvarmeværk Thisted, DK 2002 Kolding TAS, DK Dåvaverket, Umeå Energi AB, SE I/S Fasan, Næstved, DK 2003 Halmstad Renhållnings AB, SE Trédi Salaise 1&2, FR DOW Chemicals, DE 2004 SAKAB Kumla, SE DOW Chemicals, DE (several installations) Karlstad Energi AB, SE GSB Schwabach, DE AVR Avira Duiven, NL Sidefage, Bellegarde, FR Bodens energi, SE Elsam A/S, Måbjergværke, DK Taiwan Power Co, No.3 Nuclear Power St.,Taiwan 2005 Wacker Chemie, DE Tredi Saint-Vulbas, FR DOW Chemicals, Canada, DE (several inst.) Stora Enso, FI Sysav, Malmö, SE Trondheim Värmeverk, NO Vestforbrænding, DK 2006 DOW Freeport, USA Vinnolit, DE Valmadrera, IT Tekniska verken, Linköping SE 2007 Tredi Salaise 2, Fr Hydro Pol./Ineos, Stenungsund SE Sönderborg Kraftvärmev. DK Bollnäs, SE Dow Chemicals, Australia SYSAV, Malmö, SE SARP Solamat Merex, FR Acegas, Trieste, IT Wacker Nünchritz DE Tecnocasic, Cagliari, IT 2008 Indaver, Leuven, BE Ineos, Porto Torres, IT Tecnocasic Cagliari, IT Solvin/Solvay DE Wacker Nünchritz, DE Silea Valmadrera, IT StatoilHydro, Notodden, NO Renova, Gothenburg, SE dstl, Salisbury, UK 2009 Seo Kwang Hightec, Korea Karlskoga Kraftvärme, SE Covanta Pittsfield, USA Veolia- Termo Energia Versilia, IT 2010 St Gallen, CH Hexion Spec. Chemicals B.V, NL (Confidential plant), IT Linköping linje 4, SE Kiruna SE 2011 Uvrier, CH Haderslev, DK Aars, DK

10 References Energy Recovery More than 25 flue gas incineration lines have been provided with our condensing systems, several in combination with heat pumps. 25 large heat pumps and chillers, including some of the largest heat pumps in the world. Both absorption and compressor type heat pumps/chillers have been supplied.

11 Unique technologies based on patented designs Well proven: Multistage scrubbers with integrated pump tanks ADIOX for dioxin removal MERCOX for mercury removal Latest: RESOX sulpur recirculation CUTNOX system for NO x minimisation

12 Multistage wet scrubbers Flue gas cleaning for removal of HCl, HF, SO 2, NH 3 and metals in scrubber liquid circulations Flue gas condensation using a heat exchanger in scrubber liquid circulation RESOX: sulpur recirculation for reduced corrosion and higher steam data MERCOX: Hg, Hg(ox), HCl and SO 2 removal in an acid scrubber using H 2 O 2 ADIOX: Dioxin removal in all stages and no Memory effect problems

13 Case studies ongoing projects Helsingborg Filborna, Sweden Multifunctional scrubber including energy recovery by condensation installed after a semi-wet bag filter system (Boiler supplied by av B&W Vølund) Landskrona, Sweden Polishing and condensing scrubber for energy recovery installed after bag house filter (Boiler supplied by B&W Vølund)

14 Öresundskraft Helsingborg Filborna, Sweden Municipal and Industrial Waste 25 tonnes/h 8,5 15 MJ/kg 75 MW (17 MW electricity, 58 MW heat) Nm 3 /h Designed for future BAT emission levels (50% of todays limit values) Very extended energy recovery by flue gas condensation and heat pump Waste incineration will start autumn 2012

15 Filborna Öresunds Kraft 27 t/h 10 MJ/kg

16 Filborna Öresunds Kraft SNCR NO x reduction Semi-wet NID Polishing filter for dioxin and dust ALSTOM supply Energy recovery HCl & NH 3 removal Time shedule Contract June 2010 Start site construction Sept 2011 Commissioning May 2012 Waste firing Aug 2012 SO 2 & HF removal Heat Pump Fjärr värme

17 Helsingborg Filborna Flue gas inlet Direkt Heat exchanger Total Plant Energy production 75 MW (17 MW El. & 58 MW Heat) Steam and 16,5 MW of these from flue gas condensation 6,5 MW Intermediate cooling circuit 10 MW AVP Districy Heating Return

18 Helsingborg Filborna

19 Landskrona Kraft AB, Sweden Co-incineration (plastic/wood/paper, recovered fuel, biofuel) 7-18 MJ/kg 30 MW Nm 3 /h Designed for present EU emission levels Extended energy recovery by flue gas condensation Taking into operationspring/summer 2012

20 Fluegas cleaning/condensing to Landskrona Bag house filter Fan Polishing/condensing scrubber system From Boiler M M CMS District heating Water treatment Water to recipient

21 Flue gas condensation and polishing to Landskrona By-pass arrangement Good access to equipment and service areas Heat Exchanger in high quality material SMO254 Polishing of acids and prevention of dioxin memory effect by ADIOX Corrosionproof installation with scrubber and piping in FRP (Fibre reinforced Plastics)

22 RESOX : sulphur recirculation full scale tests Shulphur Emission Esp Scrubbers Flygaska HCl, HF Hg SO 2 Expected results: - 25% higher electricity production and/or 50% less corrosion - 90% lower dioxin content in flue gas and residues - The recirculation operates without any problems GÖTAVERKEN MILJÖ AB a Babcock & Wilcox Vølund company

23 RESOX : sulphur recirculation full scale tests Chemical analysis of deposits and in flight particles H 2 SO 4 Injection of H 2 SO 4 through 6 nozzles 1000h corrosion test Simulated SH tube at 405 C steam temp. Simulated SH tube at ~500 C steam temp. Chemical analysis of ashes HCl SO 2 Host plant owner:

24 1000 h corrosion rate measurements mm/year Sulphur recirculation enables higher steam data

25 RESOX : sulphur recirculation full scale tests Results of 1000 h test: - Substantially reduced corrosion (> 50%) - Verified potential for increased steam data and thereby approx 25% more electricity produktion - Approximately 25% lower dioxin content in raw gas and in residue products - reduced deposit rate (approximately 1/3) - less chloride in fly ash - Integrate with CUTNOX very interesting 16Mo3 - photos C steamtemperature Referens 16Mo3 Sulphur recirculation 16Mo3

26 CUTNOX combustion Flue gas burnout zone Secondary air 1 MSW Secondary air 2 Two-component jet of gas/water droplets Combustion chamber Solid fuel bed Moving/Reciprocating Grate Primary air Bottom ash Axial mixing & temperature control of the combustion gas above the fuel bed by a free jet of gas/water droplets

27 NOx (mg/nm 3 11 % O2) Water (l/h) CUTNOX Tests at a boiler (14 MW th ) SNCR Secondary air SNCR Secondary air Fuel Test lance Primary air Ash :30 11:00 11:30 12:00 12:30 13:00

28 Conclusions B&W Vølund and Götaverken Miljö are very interested in the Polish market for waste incineration Götaverken Miljös flue gas treatment systems are most efficient and may include very far going energy recovery The ADIOX technology for dioxin removal and dioxin memory effect prevention is highly recognised and most useful in wet scrubbers/condensers RESOX for sulphur recirculation and CUTNOX for NO x minimisation are new efficient technologies for higher efficiency

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