1 Spatial distribution of copper, organic matter and ph in agricultural soils affected by mining activities R. Aguilar 1, C. Hormazábal 1, H. Gaete 2, A. Neaman 1,3,* 1 Laboratorio de Suelos y Análisis Foliar, Facultad de Agronomía, Pontificia Universidad Católica de Valparaíso, Casilla 4-D, Quillota, Chile. 2 Departamento de Biología y Ciencias Ambientales, Facultad de Ciencias, Universidad de Valparaíso, Gran Bretaña 1111, Playa Ancha, Valparaíso, Chile. 3 Centro Regional de Estudios en Alimentos Saludables (CREAS), Región de Valparaíso. * Corresponding author: Phone: , Fax: Abstract The Aconcagua River Basin, located in north-central Chile, is an important agricultural region of the country. However, several copper mining industries are also located in this basin. A total of 103 topsoil samples were collected at varying distances from mining industries. There were no statistically significant differences between the sampling areas with regard to organic matter content and copper concentration. However, the sampling areas were significantly different with regard to soil ph. Soils of the Putaendo sampling area exhibited the lowest ph values (mean of 6.3), while the highest ph values (mean of 7.1) were measured in the Catemu Chagres sampling area. In the sampling areas where mining activities were absent, the total copper concentrations ranged from mg kg -1. These concentrations are a result of the geological setting and/or of applications of copper-containing fungicides. High copper concentrations (above 700 mg kg -1, with a maximum of 4000 mg kg -1 ) were generally observed near mining activities or in areas where mining activities were located nearby and upstream. In these sampling areas, the copper concentrations differed by an order of magnitude in nearby locations. These high and heterogeneously-distributed copper concentrations most likely resulted from either modern or former mining activities. Keywords: trace elements, metals, agriculture, mining, smelting. 125
2 126 R. Aguilar et al. 1. Introduction The Aconcagua River Basin (ARB) is located in north-central Chile in the Valparaíso Region, between 32º30 and 33º07 latitude south (Figure 1), with an area of ~7600 km 2. The ARB is one of the most important agricultural regions of Chile (ODE- PA-CIREN, 2002; IGM, 2003). However, Chile is the foremost copper producer in the world (Comisión Chilena del Cobre, and several important copper mining industries are located in the ARB. The most important of these industries are the El Soldado (near Nogales) and Andina complexes (near Saladillo, in the high Andes, ~3500 m above sea level). These complexes include mines and ore concentration/leaching plants. In addition, there are several smaller mines, concentration/leaching plants, and mine dumps distributed throughout the basin, and a copper smelter at Chagres (near the town of Catemu) (Arancibia, 2002; Lara and Romo, 2002). Figure 1. Location of the Aconcagua River Basin. The study was limited to arable soils located on landforms with slopes of less than 15%.
3 Distribution of Coper, organic matter and ph 127 The environmental problems historically associated with copper mining are widely known, particularly in relation to the contamination of agricultural soils by metals (González et al., 1984; Ginocchio, 2000; De Gregori et al., 2003). Copper is the main contaminant in the soils of copper mining areas in Chile (Goecke et al., 2011). Copper is an essential micronutrient to all organisms but is toxic at certain concentrations (Mc- Bride, 1994; Adriano, 2001). Environmental (or ecological) risk is defined as the potential for adverse effects on living organisms associated with pollution of the environment by effluents, emissions, wastes, or accidental chemical releases; energy use; or the depletion of natural resources (U.S. Environmental Protection Agency, Terms of Environment: Glossary, Abbreviations and Acronyms, It is well known that the total concentration of a metal in a soil is not sufficient to predict the potential ecological risk that it represents (McBride, 1994; Sauvé et al., 1998; ISO 17402, 2008). Ecological risk is more related to the bioavailability of the metal that, in turn, is related to the chemical form in which it is found in the soil (Adriano, 2001). The National Research Council (2003) defines bioavailability as the fraction of the total element that is available to the receptor organism. Although the total metal concentration in the soil is not a good indicator of the elements bioavailability, total concentrations are still used by legislations in many countries (Ewers, 1991). In some cases, legislations consider soil properties that affect metal bioavailability. For instance, the Council of the European Communities (2009) and the UK (1989) consider the soil ph for maximum concentrations of metals in soils on which sewage sludge is applied. Chile currently does not have any legislation on the maximum permissible concentrations of metals in soils. Any future legislation should distinguish between soils where metals are present but do not represent a risk from those that, at similar total concentrations of metals, do represent significant ecological risks (Ávila et al., 2009). In other words, future legislation should consider soil properties that affect metal bioavailability, such as soil ph and organic matter content (Adriano, 2001; Sauvé, 2003; Kabata-Pendias, 2004). To establish the maximum permissible concentrations of copper in soils, its bioavailability can be assessed by exposing organisms, e.g., plants, microorganisms, and invertebrates, to soil to monitor the effects of bioavailable copper (ISO 17402, 2008). In such types of experiments, care should be taken so that soils have wide ranges of copper concentration, ph, and organic matter content. However, little data are available on the spatial distribution of these soil characteristics in agricultural soils of the ARB. Therefore, the main objective of the present study was to determine the spatial distribution of copper, ph, and organic matter in the agricultural soils of the ARB. Additionally, for metal bioavailability tests with organisms, it is important to sample soils with different sources of contamination because different types of mine wastes have different solubilities (Ginocchio et al., 2006). Therefore, the second objective of the present study was to estimate the possible sources of contamination. The information generated from this study will form the basis for choosing locations for soil sampling in future studies aimed at assessing copper bioavailability. 2. Materials and methods Using a Geographical Information System (GIS) and available GIS databases, the agricultural soils of the ARB were clustered into 8 sampling areas (Table 1). The study was limited to arable soils located on landforms with slopes less than 15% (Figure 1). These boundaries included the agricultural soils that have traditionally been irrigated by gravity.
4 128 R. Aguilar et al. Table 1. Sampling locations and chemical properties of the studied soils. Different letters in the ph column indicate significant differences between the sampling areas (Tukey test, p < 0.001). There were no differences (ANOVA, p > 0.05) between the sampling areas with regard to organic matter (OM) content and total copper concentration. WGS 1984 Coordinates Sample UTM H19S Crop ph OM, % W S E N Quillota sampling area Total copper, mg kg Fallow Cabbage Fallow Fallow Fallow Median Mean 7.0 ab STD CV, % Nogales sampling area Avocado Bean º Bean Bean Lemon Walnut Lemon Alfalfa Fallow Beans Avocado Cabbage º º Tomato º º Fallow º º Fallow Median Mean 6.8 ab STD CV, %
5 Distribution of Coper, organic matter and ph 129 Continued... Sample Coordinates W S E N WGS 1984 UTM H19S Crop ph OM, % Total copper, mg kg -1 Catemu Llay-Llay sampling area Fallow Peach Lemon Fallow Pears Alfalfa Fallow Corn Onion Grape Fallow Fallow Fallow Median Mean 7.0 ab STD CV, % Catemu Panquehue sampling area 99 70º º Fallow Oat Onion Median Mean 7.1 ab STD CV, % Catemu Ñilhue sampling area Grape Grape Fallow Grape Alfalfa Grape Wheat
6 130 R. Aguilar et al. Continued... Sample Coordinates W S E N WGS 1984 UTM H19S Crop ph OM, % Total copper, mg kg Tobacco Orange Fallow Olive Almond Peach Median Mean 6.6 bc STD CV, % Catemu Chagres sampling area Grape Grape Alfalfa Fallow Fallow Grape Avocado Maize Fallow Alfalfa Alfalfa Fallow Lettuce Grape Alfalfa Bean Bean Artichoke Tomato Bean Alfalfa Tobacco
7 Distribution of Coper, organic matter and ph 131 Continued... Sample Coordinates W S E N WGS 1984 UTM H19S Crop ph OM, % Total copper, mg kg Fallow Pasture Chili Median Mean 7.1 a STD CV, % Putaendo sampling area Tobacco Tobacco Pumpkin Almond Olive Clover Walnut Peach Peach Peach Fallow Fallow Fallow Fallow Median Mean 6.3 c STD CV, % Los Andes sampling area Pumpkin Bean Onion Alfalfa Alfalfa Peach
8 132 R. Aguilar et al. Continued... Sample Coordinates W S E N WGS 1984 UTM H19S Crop ph OM, % Total copper, mg kg Corn Alfalfa º º Watermelon º º Bean º º Grape Fallow Grape Grape Plum Median Mean 6.7 b STD CV, % In each sampling area, locations of mining industries were considered possible sources of soil contamination by copper. A total of 103 topsoil samples (0-20 cm) were collected at varying distances from these industries. The samples were processed by drying them at 60ºC, grinding aggregates in a granite mortar, and sieving them to obtain a fraction of <2 mm. Total copper concentrations in the soils were determined by atomic absorption spectroscopy following digestion of the samples with nitric-perchloric-hydrofluoric acid mixtures (Maxwell, 1968; Jeffery, 1970). The accuracy of the analyses was assessed by including certified reference soils. The deviations in the measured and certified values were less than 10%. A solution of 0.1 M KNO 3 was used as an extractant at a soil:solution ratio of 1:2.5 g/ml for the determination of soil ph. The organic matter content was determined by wet combustion with sodium dichromate and sulphuric acid without heat application (Sadzawka et al., 2006). All analyses were performed in duplicate, and average values are reported in Table 1. The deviations in the values obtained from the duplicate runs were less than 10%. Median, mean, standard deviation (STD), and coefficient of variation (CV, % = STD 100% / mean) were calculated for the ph, organic matter content, and total copper concentration for each sampling area (Table 1). Variance analysis (ANOVA) was used to compare the sampling areas with regard to these soil characteristics. Statistically significant differences were determined using a Tukey test. All of the analyses were performed using the programs Excel 2003 and Minitab Results and discussion 3.1. Spatial distribution of organic matter and ph in the ARB soils There were no differences (ANOVA, p > 0.05) between the sampling areas with regard to organic matter content. The mean values for all areas were in the range of %. The spatial distribution of organic
9 Distribution of Coper, organic matter and ph 133 matter in each area was heterogeneous, exhibiting coefficients of variation of as high as 78% (Table 1). The sampling areas were significantly different with regards to ph (Tukey test, p < 0.001). Soils of the Putaendo sampling area exhibited the lowest ph values (mean of 6.3), while the highest ph values (mean of 7.1) were from the Catemu Chagres sampling area. The spatial distribution of ph in each area was homogeneous, exhibiting coefficients of variation up to 6% (Table 1) Background total copper concentrations in the ARB soils Although the total metal concentration in the soil is not a good indicator of the elements bioavailability, total concentrations are still used by legislations in many countries (Ewers, 1991). For instance, the Canadian Council of Ministers of the Environment (2007) established a total copper concentration of 63 mg kg -1 as a soil quality guideline for agricultural land use. The total copper concentrations were in the range of mg kg -1 in the Quillota sampling area, where the only mining activity is a small-scale mine (Figure 2, Table 2). The spatial distribution of copper was relatively homogeneous, exhibiting a coefficient of variation of 24% (Table 1). In agreement with these findings, De Gregori et al. (2003) reported that the total copper concentrations in three agricultural soils near Quillota were in the range of mg kg -1. Similar concentrations in the range of mg kg -1 were observed along the El Carretón Creek, where the only mining activity is a smallscale mine (Figure 3); at sampling point 7 along the Putaendo River, which is upstream of copper mining activities (Figure 5); and along the Colorado River, where mining activities are absent (Figures 6 and 7). Based on the virtual absence of mining activities in these locations, total copper concentrations in the range of mg kg -1 could be considered to be the background concentrations for the alluvial soil of the ARB. Table 2. Copper mining activities in the Aconcagua River Basin (Arancibia, 2002; Lara and Romo, 2002). Sampling area Large-scale mines/plants Small-scale mines/plants Mining dumps Smelter slag Quillota Nogales Catemu Llay-llay Catemu Panquehue Catemu Ñilhue * Catemu Chagres ** Putaendo Los Andes Blanco River (to the southeast of Los Andes) * Former smelters ** Active smelter
10 134 R. Aguilar et al. Figure 2. Spatial distribution of total soil copper concentrations in the Quillota sampling area.
11 Distribution of Coper, organic matter and ph 135 Figure 3. Spatial distribution of total soil copper concentrations in the Nogales sampling area.
12 136 R. Aguilar et al. Figure 4. Spatial distribution of total soil copper concentrations in the Catemu Llay-Llay, Catemu Panquehue, Catemu Ñilhue, and Catemu Chagres sampling areas.
13 Distribution of Coper, organic matter and ph 137 Figure 5. Spatial distribution of total soil copper concentrations in the Putaendo sampling area.
14 138 R. Aguilar et al. Figure 6. Spatial distribution of total soil copper concentrations in the Los Andes sampling area.
15 Distribution of Coper, organic matter and ph 139 Figure 7. Locations of mines and mine dumps of the Andina mining complex outside of the study area.
16 140 R. Aguilar et al. Nonetheless, the natural copper concentrations in the soils of the ARB are expected to be greater than the average soil copper concentrations from the rest of the world due to its geological setting. In agreement with this claim, we note that the total copper concentration of world soils averages 30 mg kg -1 (Adriano, 2001). Thus, international legislations for the assessment of the degree of soil contamination should not be applied to Chile because of its natural abundance in the soils. It could also be argued that the relatively high total soil copper concentrations in the above-mentioned locations are a result of applications of copper-containing fungicides. For example, Pietrzak and McPhail (2004) reported that the use of copper-based fungicides in Victoria (Australia) has increased the total copper concentration in some vineyard soils to 250 mg kg -1 compared to background concentrations of approximately 10 mg kg -1. To estimate the effect of fungicides on soil copper concentrations, we assumed the following hypothetical conditions: a recommended rate equivalent of up to 3 kg copper per fungicide application (AFIPA, ), 4 applications per year over 40 years, a soil depth of 20 cm, a soil bulk density of 1200 kg m -3, and the absence of the leaching of copper from the soil. Based on data from preliminary experiments, approximately 50% of the copper sprayed on crops accumulates in the soil, while the rest is retained by the crops themselves (Sergio González, INIA La Platina, personal communication). Under these conditions, fungicides would contribute to soil copper concentrations of up to 100 mg kg -1. However, more experiments are necessary to determine the percentage of fungicide retention by the crops. Nonetheless, the contribution of copper-containing fungicides to the soil copper concentrations is expected to be similar at all sampling locations because the application of fungicides is not attributed to a specific crop or crop type; rather, it is a very common practise for several vegetable and fruit crops in Chile (AFIPA, ). For this reason, we propose that, independent of the sources of soil copper from the above-mentioned locations, the total copper concentrations in the range of mg kg -1 should be considered to be the background soil concentration Spatial distribution of copper in the ARB soils The spatial distribution of copper concentrations in the soils of the ARB could predominantly be influenced either by mining activities or the geological processes of erosion and transport of copper-rich rocks. For example, Schalscha and Ahumada (1998) and Gaete et al. (2007) reported that copper in the Aconcagua River waters was present not only in a soluble form but also as a suspended solid phase. If the copper concentrations in the alluvial soils of the ARB were controlled by geological processes, we would expect to observe a homogeneous distribution of the soil copper concentrations in nearby locations. In contrast, a heterogeneous distribution of copper concentrations would be indicative of anthropogenic impacts. In the following discussion, the effects of copper mining activities (Table 2) and the erosion of copper-rich rocks on copper distribution throughout the soils will be evaluated separately for each sampling area. There were no differences (ANOVA, p > 0.05) between the sampling areas with regard to the total copper concentration. To simplify the following discussion, the concentration/leaching plants will be referred to as mines.
17 Distribution of Coper, organic matter and ph 141 Nogales sampling area In the Nogales sampling area (Figure 3), the spatial distribution of copper was very heterogeneous, exhibiting a coefficient of variation of 217% (Table 1), which is indicative of anthropogenic impacts. The highest (up to 4000 mg kg -1 ) total copper concentrations were observed in the northern section along the El Cobre Creek. Most likely, these high copper concentrations resulted from the destruction of the mining reservoir during the earthquake of 1965 (Folchi, 2003). As a result of this catastrophic event, approximately 6,500,000 m 3 of water-saturated mining wastes were dumped into the El Cobre Creek (Figure 3). These mining wastes have affected an area approximately 8 km long that extended to the town of El Melón (Folchi, 2003). Along the El Litre Creek, the total copper concentrations were greater than those that were observed along the El Carretón Creek, despite the fact that mining activities have been virtually absent along both creeks (Figure 3). Most likely, the higher copper concentrations along the former creek were also a result of the 1965 earthquake. (Table 2). Likewise, the spatial distribution of copper was relatively homogeneous, exhibiting coefficients of variation of 24-25% (Table 1). Catemu Ñilhue sampling area The relatively high copper concentrations near Ñilhue (Table 1, Figure 4) most likely resulted from an old smelter that was established in this locality in 1841 (Huidobro, 1861; Folchi, 2001). A separate and more recent La Poza smelter at Ñilhue was created at the beginning of the 20 th century (Folchi, 2006). Neither of the smelters has remained, but two smelter slag dumps near Ñilhue serve as evidence for the former smelting activities. The relatively high copper concentrations along the Catemu Creek probably resulted from the erosion of material from the mine and smelter slag dumps that are located in the upstream part of the creek. In agreement with this postulation, the highest measured copper concentration (2400 mg kg -1 ) was observed near the smelter slag dump. The copper concentrations near the mine dump to the west of Catemu were also relatively high (Figure 4). Catemu Llay-Llay sampling area Catemu Chagres sampling area In the Catemu Llay-Llay sampling area (Figure 4), the total copper concentrations ranged from mg kg -1. One exception was a sample collected near the El Sauce mine dump with a measured copper concentration of 750 mg kg -1 (Figure 4, Table 1). Catemu Panquehue sampling area In the Catemu Panquehue sampling area (Figure 4), the total copper concentrations were similar to those in the Quillota sampling area, in agreement with the virtual absence of mining activities in both areas In the Catemu Chagres sampling area, the highest (up to 900 mg kg -1 ) total copper concentrations were observed to the northeast and to the southwest of the smelter (Table 1, Figure 4). This corresponds with the predominant northeast and southwest wind directions in the area (Empresa Melón, 2005). In addition, some erosion of the smelter slag that was deposited near the river could have contributed to the high copper concentrations to the southwest of the smelter, downstream from the Aconcagua River. In the Catemu Chagres sampling area, the spatial distribution of copper was very heterogeneous,
18 142 R. Aguilar et al. exhibiting a coefficient of variation of 223 % (Table 1), which is indicative of anthropogenic impacts. If the copper concentrations in the soils of the Catemu Chagres sampling area would have been controlled by geological processes, we would expect copper concentrations to not exceed those measured in the Catemu Panquehue sampling area that is located upstream and nearby. This, however, was not the pattern revealed by our data (Table 1, Figure 4). We therefore concluded that the relatively high and heterogeneously-distributed copper concentrations in the Catemu Chagres sampling area most likely resulted from the smelting activities. The smelter at Chagres was constructed in However, effective actions to mitigate its atmospheric emissions were not performed until 1991 (Folchi, 2006). Putaendo sampling area In the Putaendo sampling area (Figure 5), the total copper concentrations were similar to those in Quillota (Figure 2). We therefore concluded that smallscale mining in the Putaendo sampling area (Table 2) had a minor impact on the soil copper concentrations. Sánchez and Enríquez (1996) similarly reported the limited environmental impacts of small-scale mining on soils and water quality. Los Andes sampling area In the northeastern part of the Los Andes sampling area, along the El Cobre Creek, the relatively high copper concentrations most likely resulted from the activities of two small-scale mines (Figure 6). However, the copper concentrations in this location were considerably greater than those in the Putaendo sampling area, where a great number of small-scale mines are present (Figure 5, Table 2). This difference was probably due to the distance between the sampling locations and the mining activities. In the Putaendo sampling area, mines were situated at relatively large distances from the study area boundary, which corresponded to landforms with slopes of less than 15%. In contrast, in the Los Andes sampling areas, mines were situated in close proximity to the study area boundary and the sampling locations. In the eastern part of the Los Andes sampling area, where the confluence of the Juncal and Colorado Rivers gives rise to the Aconcagua River (Figures 6 and 7), total copper concentrations differed by an order of magnitude in locations in close proximity (Table 1). The samples collected along the Colorado River, where mining activities are absent, exhibited considerably smaller copper concentrations than the samples collected along the Aconcagua River, downstream of the confluence of the Juncal and Colorado Rivers. In the latter samples, the relatively high copper concentrations suggested that they resulted from the large-scale mining activities of the Andina complex located upstream along the Blanco River, the main tributary of the Juncal River (Figure 7, Table 2). Total decontamination of the mining effluents of the Andina complex did not occur until the construction of a decontamination plant in 2001 (CODELCO División Andina, 2001). Additional studies are necessary to establish a pattern for the soil copper distributions in the region of the Colorado and Juncal River confluence and the effects of mining activities. In other locations along the Aconcagua River in the Los Andes sampling area (Figure 6, Table 1), the relatively high concentrations could be due either to the natural abundance of copper in the soil or to contamination from upstream mining industries.
19 Distribution of Coper, organic matter and ph Conclusions There were no statistically significant differences between the sampling areas with regard to organic matter content and copper concentrations. However, the sampling areas differed significantly with regard to ph. In the areas where mining activities were absent, the total copper concentrations ranged from mg kg -1. High copper concentrations (above 700 mg kg -1, with a maximum of 4000 mg kg -1 ) were generally observed near mining activities or in areas where mining activities were located nearby and upstream. In these areas, the copper concentrations differed by an order of magnitude in nearby locations. Acknowledgments This study was funded by the Fondo Nacional de Desarrollo Científico y Tecnológico (FONDECYT), project We thank Leví Mansur, Marco Cisternas, Jason Stuckey, Mauricio Folchi, and Sergio González for helpful comments. References Adriano, D.C Trace Elements in Terrestrial Environments: Biogeochemistry, Bioavailability, and Risk of Metals. 2nd ed. Springer-Verlag, New York, NY, 867 p. AFIPA Manual Fitosanitario. Asociación Nacional de Fabricantes e Importadores de Productos Fitosanitarios Agrícolas (AFIPA), Santiago, Chile, 1213 p. Arancibia, V., Ubicación geográfica, construcción, abandono y forestación de los tranques de relave de la V Región. Facultad de Recursos Naturales, Pontificia Universidad Católica de Valparaíso, Valparaíso, Chile, 139 p. Ávila, G., Gaete, H., Sauvé, S., Neaman, A Organic matter reduces copper toxicity for the earthworm Eisenia fetida in soils from mining areas in central Chile. Chilean Journal of Agricultural Research 69, Canadian Council of Ministers of the Environment, Canadian soil quality guidelines for the protection of environmental and human health: Summary tables. Available at: ca/assets/pdf/rev_soil_summary_tbl_7.0_e.pdf CODELCO División Andina, Limpieza Aguas Mina Andina. Estudio de Impacto Ambiental. Servicio de Evaluación Ambiental. Available at: Council of the European Communities, Corrigendum to the Council Directive 86/278/EEC of 12 June 1986 on the protection of the environment, and in particular of the soil, when sewage sludge is used in agriculture. Document number 31986L0278R(01), available at europa.eu/rech_celex.do De Gregori, I., Fuentes, E., Rojas, M., Pinochet, H., Potin-Gautier, M Monitoring of copper, arsenic and antimony levels in agricultural soils impacted and non-impacted by mining activities, from three regions in Chile. Journal of Environmental Monitoring 5, Empresa Melón Declaración de impacto ambiental del proyecto de explotación minera Ñilhue. Agenda 1. Carried out by Knight Piésold Consulting. Available at the Comisión Nacional del Medio Ambiente (CONAMA), Chile, 113 p. Ewers, U Standards, guidelines and legislative regulations concerning metals and their compounds. In: Merian, E. (ed.), Metals and their Compounds in the Environment: Occurrence, Analysis, and Biological Relevance. VCH, Weinheim, pp:
20 144 R. Aguilar et al. Folchi, M La insustentabilidad de la industria del cobre en Chile: Los hornos y los bosques durante el siglo XIX. Revista Mapocho 49, Available at: BOSQUES.pdf Folchi, M., El beneficio del cobre por vía húmeda y su impacto en el medio ambiente: Chile, Simposio de Historia Ambiental Americana. Departamento de Ciencias Históricas, Facultad de Filosofía y Humanidades, Universidad de Chile, de julio de Available at: Folchi, M., Historia ambiental de las labores de beneficio en la minería de cobre en Chile, siglos XIX y XX. Tesis de doctorado, Departamento de Economía y de Historia Económica, Universidad Autónoma de Barcelona, 727 p. Gaete, H., Aránguiz, F., Cienfuegos, G., Tejos, M Metales pesados y toxicidad de aguas del río Aconcagua en Chile. Quim. Nova 30, Ginocchio, R Effects of a copper smelter on a grassland community in the Puchuncaví Valley, Chile. Chemosphere 41, Ginocchio, R., Sanchez, P., de la Fuente, L.M., Camus, I., Bustamante, E., Silva, Y., Urrestarazu, P., Torres, J.C., Rodriguez, P.H Agricultural soils spiked with copper mine wastes and copper concentrate: Implications for copper bioavailability and bioaccumulation. Environ. Toxicol. Chem. 25, Goecke, P., Ginocchio, R., Mench, M., Neaman, A Amendments promote the development of Lolium perenne in soils affected by historical copper smelting operations. Int. J. of Phytoremediat. 13, González, S., Bergqvist, E., Ite, R Contaminación con metales pesados del área vecina a una fundición de cobre. Catemu, V Región. Agr. Téc. (Chile) 44, Huidobro, G Metalurgia del cobre en la provincia de Aconcagua. Anales de la Universidad de Chile XIX, IGM Atlas Geográfico para la Educación Instituto Geográfico Militar de Chile, Santiago, Chile, 208 p. ISO Soil quality - Requirements and guidance for the selection and application of methods for the assessment of bioavailability of contaminants in soil and soil materials. International Organization for Standardization, Genève, Switzerland, 35 p. Jeffery, P.G Chemical Methods of Rock Analysis. 1st ed. Pergamon Press, Oxford, 509 p. Kabata-Pendias, A Soil-plant transfer of trace elements - An environmental issue. Geoderma 122, Lara, L., Romo, L Atlas de Faenas Mineras: Minas y Plantas de las Regiones V, VI y XIII. Servicio Nacional de Geología y Minería, Santiago, Chile, 143 p. Maxwell, J.A Rock and Mineral Analysis. Interscience Publishers, New York, 584 p. McBride, M.B Environmental Chemistry of Soils. Oxford University Press, New York, 406 p. National Research Council Bioavailability of contaminants in soils and sediments: Processes, tools and applications. Commission on Bioavailability of Contaminants in Soils and Sediments. National Academy Press, Washington, D.C., USA, 420 p. ODEPA-CIREN Catastro Frutícola V Región, Principales Resultados. Oficina de Estudios y Políticas Agrarias (ODEPA), Centro de Información de Recursos Naturales (CIREN), Santiago, Chile, 41 p.
RESEARCH 252 CHILEAN J. AGRIC. RES. - VOL. 69 - Nº 2-2009 Organic matter reduces copper toxicity for the earthworm Eisenia fetida in soils from mining areas in Central Chile Gonzalo Ávila 1, Hernán Gaete
Water resources management at the mining industry in Chile Alejandra P. Acuña *, Reinaldo Peñailillo Environmental Group, Golder Associates S.A., Santiago, Chile, Project Engineer, 56-2 26162347, email@example.com
Antamina Closure Plan: A Top Level Practice Eng. Antonio Mendoza, M.Sc., MBA Environmental Manager 2010 Content Evolution of Environmental Regulation Closure Process Antamina Closure Evolution of Environmental
NEED TO KNOW CALIFORNIA AGRICULTURAL WATER USE: KEY BACKGROUND INFORMATION Author: Heather Cooley INTRODUCTION Water plays a substantial and vital role in California s agricultural sector. Given the long-term
SoCo Policy Seminar, Brussels, 28 May 2009 1 SoCo: European Overview on soil degradation processes related to agriculture by E. Rusco, L. Montanarella, B. Marechal JRC IES Land management and Natural Hazards
Referencias Capítulo 1 Agencia para la Protección Ambiental de los EEUU (EPA), Título 40 del Código Federal de Regulaciones, Sección 70.2 http://www.gpo.gov/fdsys/pkg/cfr-2009-title40-vol15/xml/cfr-2009-
Understanding the Soil Test Report Page 1 of 7 Crops absorb the nutrients required from soil in order to grow, so ensuring that your soil is meeting the crops needs is critical. Having the proper level
DEVELOPMENT OF A COMPUTER SYSTEM WITH MOBILE DEVICES FOR THE SUSTAINABLE DEVELOPMENT AND PRODUCTION PROJECTS EVALUATION Ing. M.Sc. Vladimir Cáceres Salazar 1 Agronomist, M.Sc. Computer Science. M.Sc Sustainable
USING GIS AND REMOTE SENSING TO MONITOR ARSENIC DISPERSAL FROM A GATSUURT MINING AREA, MONGOLIA GANDOLJIN.N 1, BATBILEG.B 2, ENKHDUL.T 3, DARJAA.TS 4 1, 2 NUM-ITC-UNESCO Laboratory for Remote Sensing and
Environmental Pollution 132 (24) 395 41 www.elsevier.com/locate/envpol Soil pollution by a pyrite mine spill in Spain: evolution in time J. Aguilar*, C. Dorronsoro, E. Fernández, J. Ferna ndez, I. Garcı
About and the Toxic Site Identification Program is a New York based not-for-profit organization that partners with governments, NGOs and community groups to solve life-threatening pollution problems in
Celia Y. Chen, Ph.D Dartmouth College Research Professor Department of Biological Sciences Class of '78 Life Sciences Center HB 6044 Hanover, NH 03755 (603)646 2376 Celia.firstname.lastname@example.org Dr. Celia Chen
Origins and causes of river basin sediment degradation and available remediation and mitigation options Feedback from the Riskbase workshop Corinne Merly 1, Olivier Cerdan 1, Laurence Gourcy 1 Emmanuelle
Greater Nanticoke Area School District Science/Technology Standards 5 th Grade Standard 3.1 Unifying Themes CS 3.1.7A Explain the parts of a simple system and their relationship to each other 1. Describe
2010 International Conference on Biology, Environment and Chemistry IPCBEE vol.1 (2011) (2011) IACSIT Press, Singapore Soil Acidity Ranking, Soil Sensitivity and Vulnerability to Acid Deposition in the
Daniel González Roubillard E- Mail: email@example.com Web Site: www.a2b-eng.com Civil Constructor Claims & Contract Consultant 30 years of professional experience in the engineering and construction
CURRICULUM VITAE Robert J. Barros, Profesor Adjunto Departamento de Humanidades Universidad de San Andrés Vito Dumas 284 1644 Victoria, Argentina (54-11)-4725-7004 e-mail: firstname.lastname@example.org I. Education
Environmental Impacts of Lead Pellets at Shooting Ranges in Florida Lena Q. Ma, Ming Chen, and Willie G. Harris Soil & Water Science Department University of Florida Acknowledgment Principle investigators
Engineering and Innovation for the Industry and Mining. ENVIRONMENTAL AND SOCIAL Metaproject in its 20 year history totals more than 1000 successful projects to his credit, with an average of 50 projects
CHAPTER 7 Conclusions 7.1 Environmental conclusions The conclusions in this section incorporate the work that was carried out to examine the chemical characteristics of each of the mine sites and their
Modelación y Cartografía Digital de Suelos en Australia Elisabeth Bui CSIRO Land and Water Australia tiene una larga historia en los inventarios de los recursos de la tierra y en los métodos de evaluación
International Journal of Environmental, Chemical, Ecological, Geological and Geophysical Engineering Vol:3, No:1, 29 Bioleaching of Heavy Metals from Sewage Sludge Using Indigenous Iron-Oxidizing Microorganisms:
JARA - Sustainable tourism and environmental restoration in territory affect for the mining action LIFE02 ENV/E/000199 Project description Environmental issues Beneficiaries Administrative data Read more
A Comparative Guide to the Chile-United States Free Trade Agreement and the Dominican Republic-Central America-United States Free Trade Agreement A STUDY BY THE TRIPARTITE COMMITTEE Chapter Six: Sanitary
A Preliminary Analysis of the Scientific Production of Latin American Computer Science Research Groups Juan F. Delgado-Garcia, Alberto H.F. Laender and Wagner Meira Jr. Computer Science Department, Federal
LEONEL SIERRALTA J. Av. San Carlos de Apoquindo 0755, Las Condes, Santiago, Cel: +569 93099512 email@example.com; firstname.lastname@example.org EDUCATION PhD Ecology, Pontificia Universidad Catolica de Chile, 1989-1991.
PERSONAL INFORMATION Name, Surname: María Inés, Barbero CURRENT EMPLOYMENT 2006- Present Universidad de Buenos Aires, Facultad de Ciencias Económicas Full Professor of Economic History 2007- Present Universidad
Journal of Soil Contamination, 8(6):653 665 (1999) Lead Distribution and Mobility in a Soil Embankment Used as a Bullet Stop at a Shooting Range Thomas Astrup, Jens K. Boddum, and Thomas H. Christensen*
1 Proposed Terms of Reference for EIA studies Base line data collection will be collected for the Post-Monsoon season 2016 (September to November 2016) in study area and 10 kms radius from project site.
KEY POINTS Fluorides are very common in the environment. Reviews of the literature and environmental impact assessments have found no evidence of any adverse environmental effects resulting from water.
VENERO CLARO TEST SITE (SPAIN) Location The Arroyo Cabrera is a torrential stream, tributary of the Alberche River in the Tagus Basin (Central Iberian Peninsula). It is formed from the confluence of several
Costs of air pollution from European industrial facilities 2008 2012 an updated assessment Summary In 2012, air pollution from European industrial facilities cost at least EUR 59 billion (and up to EUR
THE FIVE CITIES OF BUENOS AIRES: POVERTY AND INEQUALITY IN URBAN ARGENTINA Michael Cohen Director, Graduate Program in International Affairs, New School University, New York, USA Darío Debowicz Economist,
Environmental Role of Poplar and Willow Drusilla Riddell-Black Lupus Science United Kingdom Environmental roles include Buffer zones Riparian zone protection Slope stabilisation Flooding reduction Carbon
Land resources and sustainable intensification of agriculture in Europe by Winfried E.H. Blum RISE Foundation Brussels and Institute of Soil Research, University of Natural Resources and Life Sciences,
ANALYSIS OF A ANTROPIC INFLUENCES IN A FLOODPLAN M.C.S. Pereira 1&2 ; J.R.S. Martins 1 ; R.M. Lucci 2 and L.F.O.L, Yazaki 2 1. Escola Politécnica da Universidade de São Paulo, Brazil 2. Fundação Centro
International Journal of Environmental Research and Development. ISSN 2249-3131 Volume 4, Number 2 (2014), pp. 99-104 Research India Publications http://www.ripublication.com/ijerd.htm Characterization
Emission Inventory in Medellín (Colombia) city. An Approximation * By M.V. Toro *1, L.V. Cremades *2, R. Quiceno 1, J. Ramirez 1, C. Zuluaga 1, N. Moussiopoulos *3. 1. Universidad Pontificia Bolivariana
USO DE LA ENERGÍA EN LA AGRICULTURA USE OF THE ENERGY IN AGRICULTURE Fabrication and evaluation of a Solar Grain Dryer Fabricación y evaluación de una Secadora Solar de Granos Yanoy Morejón Mesa 1, Toshiyuki
WILLOCHRA BASIN GROUNDWATER STATUS REPORT 2009-10 SUMMARY 2009-10 The Willochra Basin is situated in the southern Flinders Ranges in the Mid-North of South Australia, approximately 50 km east of Port Augusta
LIMNOLOGY, WATER QUALITY PA RANI ET E R S, AN D c 0 IV D IT I 0 N S AND ECOREGIONS Water Quality Parameters Nutrients are important parameters because phosphorous and nitrogen are major nutrients required
CURRICULUM VITAE Octubre 2014 Robert J. Barros Departamento de Ciencias Sociales Universidad de San Andrés Vito Dumas 284 1644 Victoria, Argentina (54-11)-4725-7004 e-mail: email@example.com I. Education
C L A U D I O S U Á R E Z - A U T H I È V R E 2 5 1 5 B A T H U R S T S T R E E T S U I T E 1 0 0 9, T O R O N T O, ON, M 6 B 2 Z 1, C A N A D A. T E L : ( 4 1 6 ) 8 5 4 2 9 4 5, c l a u d i o. s u a r
CURRICULUM VITAE Julio Florentino del Corral Cuervo 26 th September, 2008 Personal Data Birth Date: 23/11/1980 Personal Adress: Proffesional Adress: Homepage: E-mail adress: C/ Electra 17, 1º Izquierda,
Journal of Geographic Information System, 2012, 4, 62-70 http://dx.doi.org/10.4236/jgis.2012.41009 Published Online January 2012 (http://www.scirp.org/journal/jgis) GIS Database Template for Environmental
Bioremediation Introduction In the twentieth century, the ever increase in the global human population and industrialization led to the exploitation of natural resources. The increased usage of heavy metals
LIQUID WASTE TREATMENT FACILITY MENDIS ROAD, HUDSON CREEK DRAFT GUIDELINES FOR A PUBLIC ENVIRONMENTAL REPORT Introduction The purpose of this Public Environmental Report (PER) is to provide the Government
ReUseWaste WP6.3 Assessment of soil quality effects and nutrient availability of manure ash and biochar based biofertilisers Athanasios Pantelopoulos Faculty of Science Department of Plant and Environmental
Translated from Spanish Water resources 1. The issue of water resources At the present time, sustainable standards for the development and use of water resources are not maintained in many parts of the
WATER TREATMENT PROCESSES Effluent Primary treatment Secondary Treatment runoff Tertiary treatment Water Treatment Processes PRIMARY TREATMENT to prepare the wastewater for biological treatment Purpose
Comparative study of visual impact on agricultural constructions and windfarms in Spain * I.Cañas 1 ; C. Lago 2 ; L. García 3 ; M. Ruiz 3 ; F. Maseda 4. ( 1 ) Dr. Ingeniero Agrónomo. E.T.S.Ingenieros Agrónomos.Universidad
Portable X-ray fluorescence Spectroscopy Michael A. Wilson Research Soil Scientist USDA-NRCS National Soil Survey Center Lincoln, NE OBJECTIVES Background of the method Features of the instrument Applications
5 December 2015 Status of the World s Soil Resources The Intergovernmental Technical Panel on Soils (ITPS), the main scientific advisory body to the Global Soil Partnership (GSP) hosted by the Food and
8 S. Bobar and all: Interaction of water/sedminet as a factor of lead distribution in the waters of Neretva INTERACTION OF WATER/SEDMINET AS A FACTOR OF LEAD DISTRIBUTION IN THE WATERS OF NERETVA S. Bobar,
Investment & projects We assigned US$ 3.34 billion to our investment portfolio in. We are the company that invests the most in Chile. Between and 2019 we will transfer over US$ 20.0 billion into our investment
JOURNAL PUBLICATION IN CHILE, COLOMBIA, AND VENEZUELA: UNIVERSITY RESPONSES TO GLOBAL, REGIONAL, AND NATIONAL PRESSURES AND TRENDS by Jorge Enrique Delgado Doctor in Dentistry, Pontificia Universidad Javeriana,
DESCRIPTION PARTICIPATING INSTITUTIONS ARGENTINA Climate Change Portfolio ENVIRONMENTAL SOCIAL IMPACTS CONTACT Context: Highly qualified population; availability of natural resources; diversified and modern
Codelco s Mining Resources: History and Strategy José Pesce Rosenthal Mineral Resources and Development Vice-President J-SUMMIT2 May 2015 DISCLAIMER This presentation does not constitute an offer to any
Climate Change: A Local Focus on a Global Issue Newfoundland and Labrador Curriculum Links 2010-2011 HEALTH Kindergarten: Grade 1: Grade 2: Know that litter can spoil the environment. Grade 3: Grade 4:
Adaptación de MoProSoft para la producción de software en instituciones académicas Adaptation of MoProSoft for software production in academic institutions Gabriela Alejandra Martínez Cárdenas Instituto
Preliminary Estimate Distribution of Exide s Lead Emissions in Soil Department of Toxic Substances Control Kate Burger, P.G., Ph.D Senior Engineering Geologist Clean-up August 13,2015 1 Preface Goal: Assess
MINING AND WATER POLLUTION Water is essential to life on our planet. A prerequisite of sustainable development must be to ensure uncontaminated streams, rivers, lakes and oceans. There is growing public
Amherst County Public Schools AP Environmental Science Curriculum Pacing Guide College Board AP Environmental Science Site REV: 8/12 1 st 9 weeks AP Objectives Energy Resources and Consumption A. Energy
WATER QUALITY MANAGEMENT FOR ECOLOGICAL RESTORATION IN ANYANG STREAM Yu, M.J., Cho, Y.M. 2, Lee, S.K. 3 Environmental Engineering, University of Seoul, Jennong-dong, Dongdaemun-gu, Seoul, Korea. 2 Department
Physical flow accounts: principles and general concepts Julian Chow United Nations Statistics Division 1 st Sub-Regional Course on SEEA 23-27 September 2013 Malaysia SEEA Conceptual Framework Outside territory
THE KILL DATE AS A MANAGEMENT TOOL TO INCREASE COVER CROPS BENEFITS IN WATER QUALITY & NITROGEN RECYCLING María ALONSO-AYUSO José Luis GABRIEL Miguel QUEMADA Technical University of Madrid (Spain) INDEX
TÍTULO DEL TRABAJO Dynamics of Typha latifolia population in a free water surface flow constructed wetland in Estonia NOMBRE DE AUTORES Martin Maddison* and Ülo Mander NOMBRE Y DIRECCIÓN DE LAS INSTITUCIONES
9 Water sustainability of agribusiness activities in South Africa 9.1 Water challenges 9.1.1 Water availability South Africa is a water scarce country where the demand for water is in excess of natural
A User s Guide for the Ambient Water Quality Guidelines for Cadmium What is a Water Quality Guideline? The British Columbia Ministry of Environment develops ambient water quality guidelines (WQGs) to assess
Observatory monitoring framework indicator data sheet Environmental impact: Water Indicator DA3: Nitrate and phosphate levels in rivers The EU Water Framework Directive has resulted in the need to change
NICARAGUA Tilapia fish farming (Orechromys spp) in Floating cages in Ometepe Island, Lake Cocibolca Case: Tilapia fish farming (Oreochromys spp) in floating cages in Ometepe Island, Lake Cocibolca. Municipality
Curriculum Vitae 1 Personal Information Name : Miguel Ángel Vargas Román. Date of Birth : 27th October 1971. Citizenship: Chilean. Address : 253 Manuel Rodríguez Sur, Santiago, Chile Fone : +56-2-6762252.
A SOIL TESTING SERVICE FOR FARMERS IN THAILAND, USING MOBILE LABORATORIES Narong Chinabut Office of Science for Land Development Land Development Department, Ministry of Agriculture and Cooperatives, Bangkok
CURRICULUM VITAE JAIME ALFREDO ARIAS FARIAS EDUCATION 1952 Escuela Primaria N 2; Los Andes 1953 1956 Instituto Chacabuco, Hermanos Maristas, Los Andes. 1957 1961 Instituto Rafael Ariztía, Hermanos Maristas,
Division Andina, Codelco, Chile Benjamin Allen-Gdanitz Division Andina, Codelco, Los Andes, Chile Introduction As part of the BEng Mining Engineering course at Camborne School of Mines (CSM) it is necessary
November 3, 2009 Facts About Drinking Water in the Petroecuador-Texpet Concession: Claims of Impacts by Petroleum Are False Case of Maria Aguinda et al. vs. Chevron Corp. The Plaintiffs attorneys in the
Soil quality testing Soil Core A soil core is useful when conducting the following tests for soil quality. It allows you to see and test soil properties that you otherwise would not have access to. You
Environmental policy for the clean up and remediation of contaminated sites/brownfields in Mexico Ing Eduardo Enrique González Hernández Ing. Eduardo Enrique González Hernández General Director for Comprehensive
Nombres: ANTONIO CÉSAR Apellidos: GALDÁMEZ SILVA Contacto (Opcional): AGALDAMEZ@UCHILE.CL Título Profesional o Grado Académico (incluya el año de obtención): PROFESOR DE QUÍMICA, UMCE (1997) Estudios de
UNDP/GEF Danube Regional Project Preparation of Reference Materials for Analytical Quality Control in the Water Laboratories Report on Homogeneity Tests of the Second Sediment Reference Materials October,
The ECN Concept for Quality Assurance of Compost The ECN Quality Assurance Scheme 1 Targets and Structure of ECN-QAS 2 Quality Assurance Organisations 3 The ECN-QAS for Compost The ECN - Quality Assurance
WASTEWATER TREATMENT OBJECTIVES The student will do the following: 1. Define wastewater and list components of wastewater. 2. Describe the function of a wastewater treatment plant. 3. Create a wastewater
ENVIRONMENTAL IMPACT OF FOOD PRODUCTION AND CONSUMPTION Palaniappa Krishnan Bioresources Engineering Department, University of Delaware, USA Keywords: Soil organisms, soil fertility, water quality, solar
PERSONAL INFORMATION EDUCATION Name: Diego Saravia Tamayo. Email: firstname.lastname@example.org Phone: (56) (2) 2 388-2298 (work) Home: (56) (2) 2 813-3257 (home). Ph.D. Economics, University of Maryland at College
Soil Erosion and Control Erosion is by water and wind. Crudely, about 2/3 is by water and 1/3 by wind. The loss of topsoil means loss of soil fertility. Plant growth is reduced and the soil is even more