POTENTIAL TO EMIT SUMMARY FIBERIGHT, LLC HAMPDEN, MAINE
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1 POTENTIAL TO EMIT SUMMARY FIBERIGHT, LLC HAMPDEN, MAINE s (Ton/Year) Thermal Flare Oxidizer Boiler#1 Boiler #2 Scrubber #1 Scrubber #2 Total Carbon Monoxide (CO) Oxides of Nitrogen (Nox) Sulfur Dioxide (SO2) Particulate Matter (PM) Particulate Matter < 10 µm (PM10) Particulate Matter < 2.5 µm (PM2.5) Volatile Organic Compounds ammonia HAPS Hazardous Air s (Ton/Year) Flare Tox Boiler#1 Boiler #2 Scrubber #1 Scrubber #2 Total acetaldehyde acrolein arsenic benzene beryllium cadmium chromium cobalt dichlorobenzene formaldehyde hydrochloric acid lead manganese methanol mercury* (lb/yr) n-hexane napthalene nickel phenanthrene toluene
2 Feed gas rate (SCFM) 1200 Gas Recovery rate 90% Feed Gas SO2 Concentration (ppm) 500 SO2 MW SCF /lbmol 386 Gas Density SCF/lb 379 Operational days per year Days venting gas (process upset) 36.5 Gas flared Annual Total (SCF) 63,072,000 Flare Potential to Emit (ton/year) Carbon Monoxide (CO) 6.91 Oxides of Nitrogen (Nox) 1.52 Sulfur Dioxide (SO2) 2.67 Particulate Matter (PM) 0.54 Particulate Matter < 10 µm (PM10) 0.54 Particulate Matter < 2.5 µm (PM2.5) 0.54 Volatile Organic Coumpounds 0.17 ammonia 0.10 HAPS 0.06 Emissions Factors Emission Factor Units Source Carbon Monoxide (CO) 3.10E-01 lb/mmbtu manufacturer emissions factor Oxides of Nitrogen (Nox) 6.80E-02 lb/mmbtu manufacturer emissions factor Sulfur Dioxide (SO2) Calculated based on 500 ppm H2S in raw biogas Particulate Matter (PM) 1.70E-05 lb/cu ft Burned SCC , landfill flare, WebFire Particulate Matter < 10 µm (PM10) 1.70E-05 lb/cu ft Burned SCC , landfill flare, WebFire Particulate Matter < 2.5 µm (PM2.5) 1.70E-05 lb/cu ft Burned SCC , landfill flare, WebFire Volatile Organic Coumpounds 5.5 lb/mm cu ft Burned SCC , boiler ammonia 3.2 lb/mm cu ft Burned SCC , boiler HAPS lb/mm cu ft Burned SCC , boiler Feed Gas Btu/SCF 707 Sales Gas Btu/SCF 990 Tail Gas Btu/SCF 111 SO 2 Tail Gas (TG) (ton/yr)= lb mol H 2 S 10 6 mol(tg) *lb mol SO 2 SO 2 Digester Gas(ton/yr)= lb mol H 2 S 10 6 mol(dg) *lb mol SO 2 Fiberight, LLC Flare Potential to Emit lb mol H 2 S * lb SO 2 lb mol TG TG * *scf * ton lb mol SO scf TG Year 2,000 lb lb mol H 2 S * lb SO 2 lb mol DG DG * *scf * ton lb mol SO scf DG Year 2,000 lb
3 Fiberight, LLC Thermal Oxidizer Potential to Emit Biogas tailings rate (SCFM) 386 Supplemental digester gas Flow rate (scfm) 26 Tailings SO2 Concentration (ppm) 1600 Total supplemental BTU Input (Mmbtu/hr) 3.7 Feed Gas SO2 Concentration (ppm) 500 SO2 MW Gas Density SCF/lb 379 Anticipated PSA down time 90% Normal Operations days per year Days venting gas (process upset) 36.5 Tail Gas combusted Annual Total (SCF) 182,593,440 Feed Gas Combusted Annual Total (SCF) 12,299,040 Flare Potential to Emit (ton/year) Carbon Monoxide (CO) 2.90 Oxides of Nitrogen (Nox) 1.45 Sulfur Dioxide (SO2) Particulate Matter (PM) 1.55 Particulate Matter < 10 µm (PM10) 1.55 Particulate Matter < 2.5 µm (PM2.5) 1.55 Volatile Organic Coumpounds 0.50 ammonia 0.29 HAPS 0.18 Emissions Factors Emission Factor Units Source Carbon Monoxide (CO) 2.00E-01 lb/mmbtu manufacturer emissions factor Oxides of Nitrogen (Nox) 1.00E-01 lb/mmbtu manufacturer emissions factor Sulfur Dioxide (SO2) Calculated based on 1,600 ppm H2S in tailings and 500 ppm H2S in raw biogas Particulate Matter (PM) 1.70E-05 lb/cu ft Burned SCC , landfill flare, WebFire Particulate Matter < 10 µm (PM10) 1.70E-05 lb/cu ft Burned SCC , landfill flare, WebFire Particulate Matter < 2.5 µm (PM2.5) 1.70E-05 lb/cu ft Burned SCC , landfill flare, WebFire Volatile Organic Coumpounds 5.5 lb/mm cu ft Burned SCC , boiler ammonia 3.2 lb/mm cu ft Burned SCC , boiler HAPS lb/mm cu ft Burned SCC , boiler Feed Gas Btu/SCF 707 Sales Gas Btu/SCF 990 Tail Gas Btu/SCF 111 SO 2 Tail Gas (TG) (ton/yr)= lb mol H 2 S 10 6 mol(tg) *lb mol SO 2 lb mol H 2 S * lb SO 2 lb mol TG TG * *scf * ton lb mol SO scf TG Year 2,000 lb SO 2 Digester Gas(ton/yr)= lb mol H 2 S 10 6 mol(dg) *lb mol SO 2 lb mol H 2 S * lb SO 2 lb mol DG DG * *scf * ton lb mol SO scf DG Year 2,000 lb
4 Fiberight, LLC Boiler #1 Potential to Emit Heat Input (mmbtu/hr) Total Gas fired (MMBtu) 1016 Btu/Scf Natural Gas 1020 Natural Gas (scf) Annual Hours of operation 8322 PHS (btu/lb) (dry) 8464 Ton/Year Carbon Monoxide (CO) Oxides of Nitrogen (Nox) Sulfur Dioxide (SO2) Particulate Matter (PM) 5.94 Particulate Matter < 10 µm (PM10) 4.36 Particulate Matter < 2.5 µm (PM2.5) 3.96 Volatile Organic Coumpounds 2.58 ammonia 0.00 HAPS 5.3 Emissions Factors Biomass (PHS) Emission Factor (lb/mmbtu) Emission Factor (lb/hr) Source Carbon Monoxide (CO) Emisison factors provided by manufaturer Oxides of Nitrogen (Nox) Emisison factors provided by manufaturer (AP ) Sulfur Dioxide (SO2) Based on PHS data, uncontrolled 22.2 lb/hr; controlled to 3.3 lb/hr Particulate Matter (PM) Emisison factors provided by manufaturer Particulate Matter < 10 µm (PM10) Emisison factors provided by manufaturer (AP ) Particulate Matter < 2.5 µm (PM2.5) Emisison factors provided by manufaturer (AP ) Volatile Organic Coumpounds Emisison factors provided by manufaturer (AP ) Emissions Factors Natural Gas / Bio-methane Emission Factor (lb/10 6 scf) Total lb/yr Source Carbon Monoxide (CO) Emisison factors provided by manufaturer (AP ) Oxides of Nitrogen (Nox) Emisison factors provided by manufaturer (AP ) Sulfur Dioxide (SO2) Emisison factors provided by manufaturer (AP ) Particulate Matter (PM) Emisison factors provided by manufaturer (AP ) Particulate Matter < 10 µm (PM10) Emisison factors provided by manufaturer (AP ) Particulate Matter < 2.5 µm (PM2.5) Emisison factors provided by manufaturer (AP ) Volatile Organic Coumpounds Emisison factors provided by manufaturer (AP ) Controls Hydrated Lime injection - SO2 control 85%, HCl control 95% Carbon Injection- Mercury control 95% Baghouse for PM, Vendor performance guarantee to 0.03 lb/mmbtu, assumed 90% control for heavy metals. SNCR for Nox, Manufacturer performance guarantee reduced EF from 0.22 lb/mmbtu to 0.10 lb/mmbtu
5 Fiberight, LLC Boiler #1 Potential to Emit HAPS EMISSIONS (PHS) HAP lb/mmbtu Ton/yr acetaldehyde 8.300E AP-42 acrolein 4.00E AP-42 antimony 7.90E calculated based on PHS contaminant data arsenic 7.90E calculated based on PHS contaminant data benzene 4.20E AP-42 beryllium 1.10E calculated based on PHS contaminant data cadmium 4.10E AP-42 chromium 2.10E calculated based on PHS contaminant data cobalt 6.50E calculated based on PHS contaminant data dichlorobenzene 0.00E AP-42 formaldehyde 4.40E AP-42 hydrochloric acid 1.90E calculated based on PHS contaminant data lead 4.80E calculated based on PHS contaminant data manganese 1.60E calculated based on PHS contaminant data methanol 0.00E AP-42 mercury* (lb/yr) 3.50E calculated based on PHS contaminant data n-hexane 0.00E AP-42 napthalene 9.70E AP-42 nickel 3.30E calculated based on PHS contaminant data phenanthrene 7.00E AP-42 toluene 9.20E AP-42 Source of EF AP HAPS EMISSIONS (Natural Gas) HAP lb/10 6 scf Ton/yr arsenic 2.00E AP-42 benzene 2.10E AP-42 beryllium 1.20E AP-42 cadmium 1.10E AP-42 chromium 1.30E AP-42 cobalt 8.40E AP-42 dichlorobenzene 1.20E AP-42 formaldehyde 7.50E AP-42 lead 5.00E AP-42 manganese 3.80E AP-42 mercury* (lb/yr) 2.60E AP-42 n-hexane 1.80E AP-42 napthalene 6.10E AP-42 nickel 2.10E AP-42 phenanthrene 1.70E AP-42 toluene 3.40E AP-42
6 MW Antimony % 0.03 Arsenic % 0.00 Beryllium % 0.00 Cadmium % 0.01 Chlorine % 1.16 Chromium % 0.09 Cobalt % 0.01 Lead % 0.88 Manganese % 0.22 Mercury % 0.82 Nickel % 0.07 Selenium % 0.00 Sulfur (dry basis) % Mercury emissions reported in lb/year MW Fuel Usage (lb/hr dry) Contaminant in fuel (%) Uncontrolled Emission Rate (lb/hr) Uncontrolled Control efficiency Emission Rate (ton/yr) (%) Annual Emissions (Tons) Q f = Fuel flow rate (lb/hr) MWp = Molecular weight of pollutant emitted (lb/lb-mole) MWf = Molecular weight of pollutant in fuel (lb/lb-mole) Emissions = Q f * ( concentration in fuel % / 100)* (WM p /MW f )
7 Fiberight, LLC Boiler #2 Potential to Emit Heat Input (mmbtu/hr) Total Gas fired (MMBtu) 1016 Btu/Scf Natural Gas 1020 Natural Gas (scf) Annual Hours of operation 4750 PHS (btu/lb) (dry) 8464 Ton/Year Carbon Monoxide (CO) Oxides of Nitrogen (Nox) Sulfur Dioxide (SO2) 7.92 Particulate Matter (PM) 3.39 Particulate Matter < 10 µm (PM10) 2.49 Particulate Matter < 2.5 µm (PM2.5) 2.26 Volatile Organic Coumpounds 1.47 ammonia 0.00 HAPS 3.0 Emissions Factors Biomass (PHS) Emission Factor (lb/mmbtu) Emission Factor (lb/hr) Source Carbon Monoxide (CO) Emisison factors provided by manufaturer Oxides of Nitrogen (Nox) Emisison factors provided by manufaturer (AP ) Sulfur Dioxide (SO2) Based on PHS data, uncontrolled 22.2 lb/hr; controlled to 3.3 lb/hr Particulate Matter (PM) Emisison factors provided by manufaturer Particulate Matter < 10 µm (PM10) Emisison factors provided by manufaturer (AP ) Particulate Matter < 2.5 µm (PM2.5) Emisison factors provided by manufaturer (AP ) Volatile Organic Coumpounds Emisison factors provided by manufaturer (AP ) Emissions Factors Natural Gas / Bio-methane Emission Factor (lb/10 6 scf) Total lb/yr Source Carbon Monoxide (CO) Emisison factors provided by manufaturer (AP ) Oxides of Nitrogen (Nox) Emisison factors provided by manufaturer (AP ) Sulfur Dioxide (SO2) Emisison factors provided by manufaturer (AP ) Particulate Matter (PM) Emisison factors provided by manufaturer (AP ) Particulate Matter < 10 µm (PM10) Emisison factors provided by manufaturer (AP ) Particulate Matter < 2.5 µm (PM2.5) Emisison factors provided by manufaturer (AP ) Volatile Organic Coumpounds Emisison factors provided by manufaturer (AP ) Controls Hydrated Lime injection - SO2 control 85%, HCl control 95% Carbon Injection- Mercury control 95% Baghouse for PM, Vendor performance guarantee to 0.03 lb/mmbtu, assumed 90% control for heavy metals. SNCR for Nox, Manufacturer performance guarantee reduced EF from 0.22 lb/mmbtu to 0.10 lb/mmbtu
8 Fiberight, LLC Boiler #2 Potential to Emit HAPS EMISSIONS (PHS) HAP lb/mmbtu Ton/yr acetaldehyde 8.300E AP-42 acrolein 4.00E AP-42 antimony 7.90E calculated based on PHS contaminant data arsenic 7.90E calculated based on PHS contaminant data benzene 4.20E AP-42 beryllium 1.10E calculated based on PHS contaminant data cadmium 4.10E AP-42 chromium 2.10E calculated based on PHS contaminant data cobalt 6.50E calculated based on PHS contaminant data dichlorobenzene 0.00E AP-42 formaldehyde 4.40E AP-42 hydrochloric acid 1.90E calculated based on PHS contaminant data lead 4.80E calculated based on PHS contaminant data manganese 1.60E calculated based on PHS contaminant data methanol 0.00E AP-42 mercury* (lb/yr) 3.50E calculated based on PHS contaminant data n-hexane 0.00E AP-42 napthalene 9.70E AP-42 nickel 3.30E calculated based on PHS contaminant data phenanthrene 7.00E AP-42 toluene 9.20E AP-42 Source of EF AP HAPS EMISSIONS (Natural Gas) HAP lb/10 6 scf Ton/yr arsenic 2.00E AP-42 benzene 2.10E AP-42 beryllium 1.20E AP-42 cadmium 1.10E AP-42 chromium 1.30E AP-42 cobalt 8.40E AP-42 dichlorobenzene 1.20E AP-42 formaldehyde 7.50E AP-42 lead 5.00E AP-42 manganese 3.80E AP-42 mercury* (lb/yr) 2.60E AP-42 n-hexane 1.80E AP-42 napthalene 6.10E AP-42 nickel 2.10E AP-42 phenanthrene 1.70E AP-42 toluene 3.40E AP-42
9 Antimony % 0.02 Arsenic % 0.00 Beryllium % 0.00 Cadmium % 0.00 Chlorine % 0.66 Chromium % 0.05 Cobalt % 0.00 Lead % 0.50 Manganese % 0.13 Mercury % 0.47 Nickel % 0.04 Selenium % 0.00 Sulfur (dry basis) % Mercury emissions reported in lb/year Q f = Fuel flow rate (lb/hr) MW MW MWp = Molecular weight of pollutant emitted (lb/lb-mole) MWf = Molecular weight of pollutant in fuel (lb/lb-mole) Fuel Usage (lb/hr dry) Emissions = Q f * ( concentration in fuel % / 100)* (WM p /MW f ) Contaminant in fuel (%) Uncontrolled Emission Rate (lb/hr) Uncontrolled Control efficiency Emission Rate (ton/yr) (%) Annual Emissions (Tons)
10 Operating Rate (Tons MSW/year) Operating Hours 8760 Capture Efficiency 90% Control Efficiency 95% VOC Emission (lb/hour) VOC Emission (Ton/Year) 2.89 Fiberight, LLC Scrubber #1 Potential to Emit ppmv Ton/year acetaldehyde acrolein arsenic benzene beryllium cadmium chromium cobalt dichlorobenzene formaldehyde hydrochloric acid lead manganese methanol mercury n-hexane napthalene nickel phenanthrene toluene VOC Emission Factor Organic Compounds Rumpke Landfill lb/hr Ohio EPA Permit #P MSW Received at Rumpke ton/yr Ohio EPA Permit #P ; PTE Annual MSW Fiberight ME ton/yr Maximum planned annual receipts Organics to Scrubber lb/hr Ratio (185000/ )* = Reference VOC Concentration 835 ppm
11 Operating Rate (Tons MSW/year) Operating Hours 8760 Capture Efficiency 90% Control Efficiency 95% VOC Emission (lb/hour) VOC Emission (Ton/Year) 2.89 Fiberight, LLC Scrubber #2 Potential to Emit ppmv Ton/year acetaldehyde acrolein arsenic benzene beryllium cadmium chromium cobalt dichlorobenzene formaldehyde hydrochloric acid lead manganese methanol mercury n-hexane napthalene nickel phenanthrene toluene VOC Emission Factor Organic Compounds Rumpke Landfill lb/hr Ohio EPA Permit #P MSW Received at Rumpke ton/yr Ohio EPA Permit #P ; PTE Annual MSW Fiberight ME ton/yr Maximum planned annual receipts Organics to Scrubber lb/hr Ratio (185000/ )* = Reference VOC Concentration 835 ppm
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