* * * Section 1 - Chemical Product and Company Identification * * * * * * Section 2 - Composition / Information on Ingredients * * *

Transcription

1 * * * Section 1 - Chemical Product and Company Identification * * * Chemical Name: Anti-freeze/water mixture Product Use: Extinguishing Fires Synonyms: Water portable fire extinguisher Manufacturer Information UTC Aerospace Systems Phone: Airport Drive, NW Wilson, NC Emergency #: (3E Company) Site Code: * * * Section 2 - Composition / Information on Ingredients * * * CAS # Component Percent Water Potassium acetate Ethylene glycol Carbon dioxide 0.53 Component Information/Information on Non-Hazardous Components Component Analysis No information is available. * * * Section 3 - Hazards Identification * * * Substance Preparation Classification Not classified. Emergency Overview WARNING! The pressurized release of this product will cause injury. The liquid itself is mildly irritating. Potential Health Effects: Eyes The pressurized release of this product will cause injury to the eyes. Potential Health Effects: Skin The pressurized release of this product will cause injury to the skin. The liquid itself is mildly irritating to the skin. Potential Health Effects: Ingestion Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. Potential Health Effects: Inhalation Inhalation is not a likely route of entry. * * * Section 4 - First Aid Measures * * * First Aid: Eyes If eyes come into contact with pressurized product get immediate medical attention. Gently rinse eyes with cool water until medical attention arrives. First Aid: Skin For skin contact, flush with large amounts of water. If irritation persists, get medical attention. First Aid: Ingestion If the material is swallowed, get immediate medical attention or advice. First Aid: Inhalation If inhaled, immediately remove the affected person to fresh air. Page 1 of 6 Print Date: 7/18/2014

2 * * * Section 5 - Fire Fighting Measures * * * Flash Point: Not applicable Method Used: Not applicable Upper Flammable Limit (UFL): Not applicable Lower Flammable Limit (LFL): Not applicable Auto Ignition: Not applicable Flammability Classification: Not applicable Rate of Burning: Not applicable General Fire Hazards Product itself is not flammable. Hazardous Combustion Products Irritating and/or toxic gases may be emitted upon the product's decomposition. Extinguishing Media Use methods for the surrounding fire. The use of water as an extinguishing media may not be effective for liquid fires (especially those which are insoluble in water and float on water such as hydrocarbons), certain hot metals and electrical fires. Fire Fighting Equipment/Instructions Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing apparatus, protective clothing and face mask. Use water to cool fire-exposed containers and to protect personnel. * * * Section 6 - Accidental Release Measures * * * Containment Procedures Stop the flow of material, if this is without risk. Clean-Up Procedures Evacuate the area promptly. Ventilate the contaminated area. Use appropriate respiratory equipment. Absorb spill with inert material. Shovel material into appropriate container for disposal. Evacuation Procedures Persons not wearing appropriate protective equipment should be excluded from area of spill until clean-up has been completed. Special Procedures Regulations vary. Consult local authorities before disposal. * * * Section 7 - Handling and Storage * * * Handling Procedures Do not get into contact with the eyes or skin. Inspect extinguisher to insure container integrity. Do not mix with other extinguishing agents. Storage Procedures Store in accordance with all current regulations and standards. Keep from away incompatible substances. Protect from physical damage. Specific Use Fire extinguishing agent. * * * Section 8 - Exposure Controls / Personal Protection * * * Substance Exposure Limits Carbon dioxide ( ) ACGIH: Austria: Belgium: Denmark: Finland: Germany: 30,000 ppm STEL 5000 ppm TWA ppm STEL (60 min); mg/m3 STEL (60 min) 5000 ppm MAK; 9000 mg/m3 MAK ppm VLE; mg/m3 VLE 5000 ppm VLE; 9131 mg/m3 VLE 5000 ppm TWA; 9100 mg/m3 TWA 5000 ppm MAK; 9100 mg/m3 MAK 10,000 ppm Peak; 18,200 mg/m3 Peak Page 2 of 6 Print Date: 7/18/2014

3 Greece: Ireland: Netherlands: Portugal: Spain: Sweden: United Kingdom: 5000 ppm STEL; mg/m3 STEL ppm STEL; mg/m3 STEL 5000 ppm MAC; 9000 mg/m3 MAC 5000 ppm TWA ppm VLA-EC; mg/m3 VLA-EC 5000 ppm VLA-ED; 9150 mg/m3 VLA-ED 5000 ppm LLV; 9000 mg/m3 LLV ppm STV; mg/m3 STV 5000 ppm TWA; 9150 mg/m3 TWA 15,000 ppm STEL; 27,400 mg/m3 STEL Engineering Controls Ventilation is not normally required. PERSONAL PROTECTIVE EQUIPMENT Personal Protective Equipment: Eyes/Face Wear safety goggles and face shield. Personal Protective Equipment: Skin Use of impervious gloves and boots are recommended. Use of protective clothing. Personal Protective Equipment: Respiratory Under normal conditions, respirator is not normally required. Personal Protective Equipment: General * * * Section 9 - Physical & Chemical Properties * * * Appearance: Clear to cloudy Odor: Odorless Physical State: Liquid ph: Slightly acidic Vapor Pressure: Not available Vapor Density: Not available Boiling Point: Not available Melting Point: Not available Solubility (H2O): Soluble Specific Gravity: Not available * * * Section 10 - Chemical Stability & Reactivity Information * * * Chemical Stability This is a stable material. Chemical Stability: Conditions to Avoid Protect container from heat and physical damage. Incompatibility Strong oxidizing agents and water reactive material. Hazardous Decomposition Irritating and/or toxic gases may be emitted upon the product's decomposition. Hazardous Polymerization Will not occur. * * * Section 11 - Toxicological Information * * * Acute and Chronic Toxicity This product is mildly irritating. B: Component Analysis - LD50/LC50 Potassium acetate ( ) Oral LD50 Rat: 3250 mg/kg Page 3 of 6 Print Date: 7/18/2014

4 Carcinogenicity B: Substance Carcinogenicity None of the substances in this preparation are listed by IARC, Austria, Belgium, Denmark, France, Germany, Ireland, Luxembourg, Netherlands, Spain, or United Kingdom. * * * Section 12 - Ecological Information * * * Ecotoxicity B: Component Analysis - Ecotoxicity - Aquatic Toxicity No ecotoxicity data are available for this product's components. Mobility Persistence & Degradation Bioaccumulation Other Adverse Effects * * * Section 13 - Disposal Considerations * * * Waste Disposal Instructions Dispose according to national, regional and local regulations. * * * Section 14 - Transportation Information * * * IATA Information ICAO Information IMDG Information ADR Information RID Information Containers must be shipped with the appropriate safety caps. * * * Section 15 - Regulatory Information * * * European Union Regulatory Information Not classified. S9 Keep container in a well-ventilated place. Page 4 of 6 Print Date: 7/18/2014

5 A: Component Analysis - Inventory Component CAS # EEC CAN TSCA Water EINECS DSL Yes Potassium acetate EINECS DSL Yes Ethylene glycol EINECS DSL Yes Carbon dioxide EINECS DSL Yes B: Seveso II Directive - Qualifying Quantities No information is available. * * * Section 16 - Other Information * * * MSDS History MSDS History: New MSDS, 8/12/2004 Revision A: 7/10/2013 renumbered, contact information updated and reviewed Key/Legend TSCA = Toxic Substance Control Act; ACGIH = American Conference of Governmental Industrial Hygienists; IARC = International Agency for Research on Cancer; NTP = National Toxicology Program; IATA = International Air Transport Association; IMO = International Maritime Organization; ADR/RID = European Agreement of Dangerous Goods by Road/Rail; DFG = Deutsche Forschungsgemeinschaft; MAC/MAK = Maximum Concentration Value in the Workplace; TWA = Time Weighted Average; STEL = Short-term Exposure Limit; EINECS = European Inventory of Existing Commercial Chemical Substances; EEC = European Economic Community; VLA/VLE = Work Exposure Threshold; OEL = Occupational Exposure Limit; NA = Not Applicable or Not Available. Other Information The information herein is presented in good faith and believed to be accurate as of the effective date given. However, no warranty, expressed or implied, is given. It is the buyer's responsibility to ensure that its activities comply with Federal, State or provincial, and local laws. Contact: UTC Aerospace Systems (UTAS), Materials Engineering Contact Phone: End of Sheet Page 5 of 6 Print Date: 7/18/2014

6 REV: A REVISIONS LTR DESCRIPTION DATE BY APPD A Release 14/05/28 PA DWG NO: SH: 1 PROPRIETARY INFORMATION COPYRIGHT UNITED TECHNOLOGIES AEROSPACE SYSTEMS. THIS DOCUMENT IS THE PROPERTY OF UNITED TECHNOLOGIES AEROSPACE SYSTEMS (UTAS). YOU MAY NOT POSSESS, USE, COPY OR DISCLOSE THIS DOCUMENT OR ANY INFORMATION IN IT, FOR ANY PURPOSE, INCLUDING WITHOUT LIMITATION, TO DESIGN, MANUFACTURE OR REPAIR PARTS, OR OBTAIN ANY GOVERNMENT APPROVAL TO DO SO, WITHOUT UTAS EXPRESS WRITTEN PERMISSION. NEITHER RECEIPT NOR POSSESSION OF THIS DOCUMENT ALONE, FROM ANY SOURCE, CONSTITUTES SUCH PERMISSION. POSSESSION, USE, COPYING OR DISCLOSURE BY ANYONE WITHOUT UTAS EXPRESS WRITTEN PERMISSION IS NOT AUTHORIZED AND MAY RESULT IN CRIMINAL AND/OR CONTR NO: P/C: USED ON: This document or file contains no EAR technology or ITAR technical data. DRWN: Peter Anderson 14/05/ CHECK: Sherwood Joyner 14/05/28 Kidde Technologies, Inc Airport Dr. NW Wilson, NC ENG: Brett Standifer 14/05/28 MSDS Anti-Freeze & Water SHIPPING: Edwin Sepulveda 14/05/28 Mixture (EU) SIMILAR TO NEXT ASSY SIZE CAGE CODE DWG NO REV A A SCALE -- REL DATE SHEET 6 of 6 Page 6 of 6 Print Date: 7/18/2014