2 Material Safety Data Sheet NFPA HMIS Personal Protective Equipment 0 Health Hazard Fire Hazard 0 See Section 5. Section. Chemical Product and Company Identification Page Number: Common Name/ Trade Name Sodium ascorbate Catalog Number(s). S37, SO08, S349 CAS# Manufacturer SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA RTECS TSCA CI TSCA 8(b) inventory: Sodium ascorbate Commercial Name(s) Synonym Chemical Name Chemical Family Chemical Formula Supplier Ascorbicin, Ascorbin, Cebitate, Natrascorb Sodium L-Ascorbate; Vitamin C Sodium; L-Ascorbic acid sodium salt; Ascorbic acid sodium salt; Monosodium L-Ascorbate L-Ascorbic Acid, monsodium salt C6H7NaO6 SPECTRUM LABORATORY PRODUCTS INC S. SAN PEDRO STREET GARDENA, CA CI# CALL (30) IN CASE OF EMERGENCY CHEMTREC (24hr) Section 2.Composition and Information on Ingredients Name CAS # Exposure Limits TWA (mg/m 3 ) STEL (mg/m 3 ) CEIL (mg/m 3 ) % by Weight ) Sodium ascorbate Toxicological Data on Ingredients Sodium ascorbate: ORAL (LD50): Acute: 753 mg/kg [Mouse] mg/kg [Rat]. Section 3. Hazards Identification Potential Acute Health Effects Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Potential Chronic Health Effects CARCINOGENIC EFFECTS: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. TERATOGENIC EFFECTS: DEVELOPMENTAL TOXICITY: The substance may be toxic to kidneys, bladder. Repeated or prolonged exposure to the substance can produce target organs damage.
3 Sodium ascorbate Page Number: 2 Section 4. First Aid Measures Eye Contact Skin Contact Serious Skin Contact Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 5 minutes. Cold water may be used. Get medical attention if irritation occurs. Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold water may be used. Inhalation Serious Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion Serious Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Section 5. Fire and Explosion Data Flammability of the Product Auto-Ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances May be combustible at high temperature. These products are carbon oxides (CO, CO2). Some metallic oxides. Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks. Explosion Hazards in Presence of Various Substances Slightly explosive in presence of open flames and sparks. Non-explosive in presence of shocks. Fire Fighting Media and Instructions Fire Hazards Explosion Hazards SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. As with most organic solids, fire is possible at elevated temperatures. When heated to decomposition it emits toxic fumes of sodium oxide Fine dust dispersed in air in sufficient concentrations, and in the presences of an ignition source is a potential dust explosion hazard. Section 6. Accidental Release Measures Small Spill Large Spill Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Section 7. Handling and Storage Precautions Storage Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizing agents, reducing agents, acids, alkalis. Keep container tightly closed. Keep container in a cool, well-ventilated area. Sensitive to light. Store in light-resistant containers.
4 Sodium ascorbate Page Number: 3 Section 8. Exposure Controls/Personal Protection Engineering Controls Personal Protection Personal Protection in Case of a Large Spill Exposure Limits Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Section 9. Physical and Chemical Properties Physical state and appearance Molecular Weight ph (% soln/water) Sol i d. ( Gr anul ar s ol i d. Cr ys t al s s ol i d. Crystalline powder. Granular powder) 98. g/mole Odor Taste Color Odorless. White. White to yellowish. Boiling Point Melting Point Critical Temperature Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Water/Oil Dist. Coeff. Ionicity (in Water) Dispersion Properties Solubility Decomposition temperature: 200 C (392 F) - 28 C.66 (Water = ) See solubility in water. Easily soluble in cold water. Insoluble in diethyl ether. Insoluble in chloroform and alcohol. Solubility in water: 62 g/00 25 deg. C and 78 g/00 75 deg. C Section 0. Stability and Data Stability Instability Temperature Conditions of Instability Incompatibility with various substances Corrosivity The product is stable. Excess heat, light, incompatible materials Reactive with oxidizing agents, reducing agents, acids, alkalis. Non-corrosive in presence of glass. Corrosivity Polymerization Sensitive to light. It gradually darkens on exposure to light. On prolonged strorage, a yellow discoloration may occur through slow decompostion. Incompatible with compounds rich in oxygen, copper, metal salts Will not occur.
5 Sodium ascorbate Page Number: 4 Section. Toxicological Information Routes of Entry Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Toxicity to Animals Chronic Effects on Humans other Toxic Effects on Humans Inhalation. Ingestion. Acute oral toxicity (LD50): 6300 mg/kg [Rat]. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: kidneys, bladder. Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation. May affect genetic material (mutagenic) based on animal test data. No human data found. (Registry of Toxic Effects of Chemicals) Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: May cause upper respiratory tract and mucous membrane irritation. Ingestion: May cause gastrointestinal tract effects. Symptoms may include nausea, vomiting, diarrhea, constipation, cramps, heartburn, loss of appetite. Other symptoms may include headache, insomnia, sleepiness, fatigue, flushing Chronic Potential Health Effects: Ingestion: May cause kidney or bladder stones which are caused by acidification of urine and precipitation of cystine or oxalate. Conditions aggravated by exposure: Hemachromatosis, thalassemia, sideroblastic or sickle cell anemial. Section 2. Ecological Information Ecotoxicity BOD5 and COD Products of Biodegradation Toxicity of the Products of Biodegradation the Products of Biodegradation Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. The products of degradation are more toxic. Section 3. Disposal Considerations Waste Disposal Waste must be disposed of in accordance with federal, state and local environmental control regulations. Section 4. Transport Information DOT Classification Identification Not a DOT controlled material (United States). Special Provisions for Transport DOT
6 Sodium ascorbate Page Number: 5 Section 5. Other Regulatory Information and Pictograms Federal and State Regulations California Proposition 65 Warnings Other Regulations TSCA 8(b) inventory: Sodium ascorbate California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer which would require a warning under the statute: No products were found. California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: No products were found. EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances (EINECS No ). Canada: Listed on Canadian Domestic Substance List (DSL). China: Listed on National Inventory. Japan: Not listed on National Inventory (ENCS). Korea: Listed on National Inventory (KECI). Philippines: Listed on National Inventory (PICCS). Australia: Listed on AICS. Other Classifications WHMIS (Canada) CLASS D-2B: Material causing other toxic effects (TOXIC) (for mutagenicity in mammalian somatic cells). DSCL (EEC) HMIS (U.S.A.) Health Hazard Fire Hazard Personal Protection 0 E National Fire Protection Association (U.S.A.) Health 0 Flammability Specific hazard WHMIS (Canada) DSCL (Europe) TDG (Canada) ADR (Europe) Protective Equipment Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
7 Sodium ascorbate Page Number: 6 Safety glasses. Section 6. Other Information MSDS Code References Other Special Considerations S360 -Manufacturer's Material Safety Data Sheet. Registry of Toxic Effects of Chemicals (RTECS) Major Uses: Antioxidant in foods; Chemical preservative in foods Validated by Sonia Owen on /0/204. Verified by Sonia Owen. Printed /0/204. CALL (30) Notice to Reader All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Spectrum Quality Products, Inc. assumes no responsibility for the completeness or accuracy of the information contained herein. Contact Distributor
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