Safety Data Sheet Page 1 of 11

Transcription

1 Safety Data Sheet Page 1 of 11 BONDERITE M-CR 1200S AERO - AU SDS No. : V001.1 Date of issue: Section 1. Identification of the substance/preparation and of the company/undertaking Product name: Intended use: BONDERITE M-CR 1200S AERO - AU Conversion coating Supplier: Henkel Australia Pty Ltd Canterbury Road Kilsyth, Victoria, 3137 Australia Phone: +61 (3) Emergency information: 24 HOUR EMERGENCY CONTACT NUMBER: Classification of the substance or mixture Hazardous according to the criteria of Safe Work Australia. GHS Classification: Section 2. Hazards identification Hazard Class Hazard Category Route of Exposure Target organ Oxidizing solids Category 1 Acute toxicity Category 3 Oral Acute toxicity Category 2 Inhalation Acute toxicity Category 2 Dermal Skin corrosion Category 1A Serious eye damage/eye irritation Category 1 Respiratory sensitizer Category 1 Skin sensitizer Category 1 Germ cell mutagenicity Category 1B Carcinogenicity Category 1A Toxic to reproduction Category 2 Target Organ Systemic Toxicant - Category 3 respiratory tract irritation Single exposure Target Organ Systemic Toxicant - Category 1 Repeated exposure Acute hazards to the aquatic Category 1 environment Chronic hazards to the aquatic environment Category 1 Hazard pictogram: Signal word: Danger

2 Page 2 of 11 Hazard statement(s): Precautionary Statement(s): Prevention: Response: Storage: Disposal: H271 May cause fire or explosion; strong oxidizer. H301 Toxic if swallowed. H310+H330 Fatal in contact with skin or if inhaled. H314 Causes severe skin burns and eye damage. H350 May cause cancer. H340 May cause genetic defects. H317 May cause an allergic skin reaction. H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 May cause respiratory irritation. H361 Suspected of damaging fertility or the unborn child. H372 Causes damage to organs through prolonged or repeated exposure. H410 Very toxic to aquatic life with long lasting effects. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P280 Wear protective gloves/protective clothing/eye protection/face protection. P220 Keep/Store away from clothing/combustible materials. P201 Obtain special instructions before use. P210 Keep away from heat. P221 Take any precaution to avoid mixing with combustibles. P262 Do not get in eyes, on skin, or on clothing. P264 Wash hands thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of the workplace. P273 Avoid release to the environment. P283 Wear fire/flame resistant/retardant clothing. P284 [In case of inadequate ventilation] wear respiratory protection. P301+P310+P330 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. Rinse mouth. P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304+P340+P310 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician. P305+P351+P338+P315 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. P308+P313 IF exposed or concerned: Get medical advice/attention. P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P306+P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. P363 Wash contaminated clothing before reuse. P370+P378 In case of fire: Use water for extinction. P371+P380+P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P391 Collect spillage. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations. Classification of material T+ - Very toxic C - Corrosive O - Oxidizing N - Dangerous for the environment

3 Page 3 of 11 Risk phrases: R24/25 Toxic in contact with skin and if swallowed. R26 Very toxic by inhalation. R32 Contact with acids liberates very toxic gas. R35 Causes severe burns. R41 Risk of serious damage to eyes. R42/43 May cause sensitization by inhalation and skin contact. R45 May cause cancer. R46 May cause heritable genetic damage. R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R62 Possible risk of impaired fertility. Safety phrases: S22 Do not breathe dust. S24/25 Avoid contact with skin and eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S27 Take off immediately all contaminated clothing. S28 After contact with skin, wash immediately with plenty of water. S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S46 If swallowed, seek medical advice immediately and show this container or label. S53 Avoid exposure - obtain special instructions before use. S60 This material and its container must be disposed of as hazardous waste. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. Dangerous Goods information: Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). Signal word: HAZARDOUS Section 3. Composition / information on ingredients General chemical description: Mixture inorganic salts inorganic acids Identity of ingredients: Chemical ingredients Proportion % Tripotassium hexacyanoferrate % < 10 % Dipotassium hexafluorozirconate < 10 % non hazardous ingredients~ % Section 4. First aid measures

4 Page 4 of 11 Ingestion: Skin: Eyes: Inhalation: First Aid facilities: First Aid facilities: Medical attention and special treatment: Do not induce vomiting. Have victim rinse mouth thoroughly with water. Immediate medical treatment necessary. In case of contact, immediately remove contaminated clothing and flush skin with copious amounts of water. Immediate medical treatment necessary. Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Immediate medical treatment necessary. If inhaled, immediately remove the affected person to fresh air. Keep warm and in a quiet place. Immediate medical treatment necessary. Eye wash and safety shower Normal washroom facilities Eye wash and safety shower Treat symptomatically. Treatment of hypocalcemia associated with corrosive fluoride compounds exposure may be corrected by intravenous calcium gluconate or calcium chloride. Treatment of hypomagnesemia may be corrected by intravenous magnesium sulfate. Section 5. Fire fighting measures Suitable extinguishing media: Improper extinguishing media: Decomposition products in case of fire:: Particular danger in case of fire:: Special protective equipment for fire-fighters: Additional fire fighting advice: Hazchem code: Water Carbon dioxide. foam Dry powder. Irritating and toxic gases or fumes may be released during a fire. Oxides of nitrogen. Carbon monoxide. Carbon dioxide. Chromium oxide. Fluorine. Oxidizing agent, may cause spontaneous ignition of combustible materials. Violent reactions may occur with organic materials or reducing agents. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Fire fighters should wear positive pressure self-contained breathing apparatus (SCBA). In case of fire, keep containers cool with water spray. Collect contaminated fire fighting water separately. It must not enter drains. 1W Section 6. Accidental release measures Personal precautions: Environmental precautions: Clean-up methods: Avoid dust formation. Keep unprotected persons away. Avoid contact with skin and eyes. Wear protective equipment. Ensure adequate ventilation. Use personal protective equipment as described in Section 8. Do not empty into drains / surface water / ground water. Wear appropriate protective equipment and clothing during clean-up. Remove mechanically. Spills should be cleaned immediately to prevent dispersion of airborne dusts.

5 Page 5 of 11 Dispose of contaminated material as waste according to Section 13. Section 7. Handling and storage Precautions for safe handling: Conditions for safe storage: Suitable materials with product: Unsuitable materials with product: Avoid contact with eyes, skin and clothing. Fire hazard if organic material (e.g.wood,wood wool, paper) is impregnated with this product and dried up. Wear suitable protective clothing, safety glasses and gloves. Avoid breathing dust. Ensure that workrooms are adequately ventilated. For industrial use only. Store only in the original container. Store in a cool, well-ventilated place. Isolate from incompatible substances. Keep container tightly sealed. Must be stored in the facility for the dangerous goods Do not store near sources of heat or ignition, or reactive materials. Do not store together with organic substances. Do not store together with flammable substances/solutions. Do not store together with strong bases or very alkaline substances. Plastic corroding metal Section 8. Exposure controls / personal protection National exposure standards: Ingredient [Regulated substance] CHROMIUM (VI) COMPOUNDS (AS CR), WATER SOLUBLE FLUORIDES (AS F) ZIRCONIUM COMPOUNDS (AS ZR) ZIRCONIUM COMPOUNDS (AS ZR) FLUORIDES (AS F) form of exposure TWA (ppm) TWA (mg/m3) Peak Limit. (ppm) Peak Limit. (mg/m3) STEL (ppm) STEL (mg/m3)

6 Page 6 of 11 Engineering controls: Eye protection: Skin protection: Ensure good ventilation/suction at the workplace. Ventilation should effectively remove and prevent buildup of any dust generated from the handling of this product. Tightly fitting safety goggles Wear face shield. Use of impervious apron and boots are recommended. Suitable protective gloves. Protective clothing that covers arms and legs. Please note that in practice the working life of chemical resistant gloves may be considerably reduced as a result of many influencing factors (e.g. temperature). Suitable risk assessment should be carried out by the end user. If signs of wear and tear are noticed then the gloves should be replaced. PVC Coated Gloves. Butyl rubber gloves. Respiratory protection: General protection measures: If inhalation risk exists, wear a respirator or air supplied mask complying with the requirements of AS/NZS 1715 and AS/NZS Use only in well-ventilated areas. Appearance: orange powder Odor: mild ph:(concentration: 1 % product) Flash point: Not applicable Solubility in water: Soluble VOC content (2004/42/EC) 0 % (2010/75/EU) Section 9. Physical and chemical properties Section 10. Stability and reactivity Stability: Conditions to avoid: Stable under normal conditions of temperature and pressure. Keep away from heat, ignition sources and incompatible materials. Oxidizing agent, may cause spontaneous ignition of combustible materials.

7 Page 7 of 11 Incompatible materials: Reacts with flammable substances: Fire danger! Can attack glass and vitreous materials. Reacts with alkalis: Heat generated. Reaction with reducing agents. Hazardous decomposition products: Hazardous polymerization: Thermal decomposition can lead to release of irritating gases and vapors. Carbon monoxide. Carbon dioxide. Oxides of nitrogen. Chromium oxide. Fluorine. Will not occur. Section 11. Toxicological information Health Effects: Ingestion: Skin: Eyes: Inhalation: Chronic effects: : Carcinogenicity: Toxicity for reproduction: Mutagenicity: Toxic if swallowed. Ingestion causes burns of the upper digestive and respiratory tracts. If ingested, severe burns of the mouth and throat may occur, as well as perforation of the esophagus and the stomach. Also very toxic in contact with skin. Causes skin burns. Symptoms may include redness, burning, drying, cracking and skin burns. May cause allergic skin reaction. Because of the chromium, may cause cancer. Massive overexposures may lead to kidney failure and death. Causes serious eye damage. Contact with the eyes may cause moderate to severe eye injury. Eye contact may result in corneal injury. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Very toxic if inhaled. This product is irritating to the respiratory system. Can cause severe irritation and burns to the respiratory tract. May cause allergic respiratory reaction. Contains fluorides. Exposure to fluorides over years may cause fluorosis. Damage to the skin and the mucosae, particularly in the nose and throat region; allergic skin diseases; can cause nausea, vomiting, diarrhea, spasms and hemorrhagic nephritis; carcinogenic potential (lung cancer). Category 1A (Carcinogen), May cause cancer. Toxic to reproduction, category 2, Suspected of damaging fertility or the unborn child. Category 1B (Mutagen), This product contains an ingredient which has been associated with mutagenicity effects. Acute toxicity: Value type LD50 Acute toxicity estimate (ATE) LC50 LD50 LD50 LD50 Value mg/kg 0.31 mg/l > 0.31 mg/l 57 mg/kg mg/kg > 2,000 mg/kg Route of application oral inhalation inhalation dermal oral dermal Exposure time 4 h rat rat rabbit rat rat Expert judgement OECD Guideline 402 (Acute Dermal Toxicity) EPA OPPTS (Acute Oral Toxicity) EPA OPPTS (Acute Dermal Toxicity)

8 Page 8 of 11 Skin corrosion/irritation: Tripotassium hexacyanoferrate Result Exposure time corrosive 24 h rabbit irritating Serious eye damage/irritation: Tripotassium hexacyanoferrate Dipotassium hexafluorozirconate corrosive irritating Result Exposure time rabbit Category 1 (irreversible effects on the eye) rabbit OECD Guideline 405 (Acute Eye Irritation / Corrosion) Germ cell mutagenicity: Result Type of study / Route of administration positive bacterial reverse mutation assay (e.g Ames test) Metabolic activation / Exposure time with and without Repeated dose toxicity: Result NOAEL= mg/l Route of application Exposure time / Frequency of treatment inhalation 90 daystaeglich 20 Stunden rat Section 12. Ecological information

9 Page 9 of 11 General ecological information: Ecotoxicity: Do not empty into drains / surface water / ground water., Because of the low ph of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic organisms and aquatic systems. Very toxic to aquatic life with long lasting effects. Toxicity: Tripotassium hexacyanoferrate Tripotassium hexacyanoferrate Dipotassium hexafluorozirconate Dipotassium hexafluorozirconate Value type Value Acute Toxicity Study Exposure time LC50 52 mg/l Fish 96 h Carassius auratus OECD Guideline 203 (Fish, Acute Toxicity Test) NOEC mg/l Fish 60 d Salvelinus namaycush OECD 210 Guideline (fish early lite stage toxicity test) EC mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC0 1 mg/l Bacteria OECD Guideline 201 (Alga, Growth Inhibition Test) LC50 1,590 mg/l Fish OECD Guideline 203 (Fish, Acute Toxicity Test) EC0 > 1,000 mg/l Bacteria LC mg/l Fish 48 h Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation EC mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC mg/l Algae 72 h Scenedesmus subspicatus (new name: Desmodesmus subspicatus) EC0 231 mg/l Bacteria 16 h Test) DIN DIN LC50 > 200 mg/l Fish 96 h Leuciscus idus OECD Guideline 203 (Fish, Acute Toxicity Test) EC mg/l Daphnia 48 h Daphnia magna OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test) Section 13. Disposal considerations Waste disposal of product: Recommended cleanser: Disposal for uncleaned package: This material can be converted to a less hazardous material by weak reducing agents followed by neutralization. Dispose of as hazardous waste in compliance with local and national regulations. Do not allow product to enter sewer or waterways. Clean the packaging with water. Packaging that cannot be cleaned are to be disposed of in the same manner as the product. Disposal must be made according to official regulations.

10 Page 10 of 11 Section 14. Transport information Road and Rail Transport: Dangerous Goods information: Classified as Dangerous Goods according to the criteria of the Australian Code for the Transport of Dangerous Goods by Road and Rail (ADG Code). UN no.: 1463 Proper shipping name: CHROMIUM TRIOXIDE, ANHYDROUS (mixture) Class or division: 5.1 (6.1, 8) Packing group: II Hazchem code: Emergency information: 1W Refer to the Dangerous Goods - Initial Emergency Response Guide HB 76. Marine transport IMDG: UN no.: 1463 Proper shipping name: CHROMIUM TRIOXIDE, ANHYDROUS (mixture) Class or division: 5.1 (6.1, 8) Packing group: II EmS: F-A,S-Q Seawater pollutant: Marine pollutant Air transport IATA: UN no.: 1463 Proper shipping name:, anhydrous (mixture) Class or division: 5.1 (6.1, 8) Packing group: II Packing instructions (passenger) 558 Packing instructions (cargo) 562 SUSMP Poisons Schedule 6 Section 15. Regulatory information AICS: All components are listed or are exempt from listing on the Australian Inventory of Chemical Substances (AICS). Section 16. Other information Abbreviations/acronyms: STEL - Short term exposure limit TWA - Time weighted average IMDG: International Maritime Dangerous Goods code IATA-DGR: International Air Transport Association Dangerous Goods Regulations ADGC - Australian Dangerous Goods Code Reason for issue: Reviewed SDS. Reissued with new date. involved chapters: 1-16 Date of previous issue: Disclaimer:

11 Page 11 of 11 The percentage weight (% w/w) of ingredients is not to be taken as a specification guaranteed by Henkel Australia Pty. Limited, but only as an approximate guide to the content of hazardous ingredients in the material. The information contained herein does not constitute a guarantee by Henkel Australia Pty. Limited concerning the properties of the material. The information contained in the Safety Data Sheet is offered in good faith and has been developed from what is believed to be accurate and reliable sources. The information is offered without warranty, representation, inducement or licence and Henkel Australia Pty. Limited assumes no legal responsibility for reliance upon same. Henkel Australia Pty. Limited disclaims any liability for loss, injury or damage incurred in connection with the use of the material or its associated Safety Data Sheet. This information is not to be construed as a representation that the material is suitable for any particular purpose or use except those conditions and warranties implied by either Commonwealth or State statutes. Customers are encouraged to make their own enquiries as to the material s characteristics and, where appropriate, to conduct their own tests in the specific context of the material s intended use.