Test report No. MAIC Testing and evaluating of a digital printed paper material according to AgBB/DIBt-scheme.

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Cory James
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1 Fraunhofer Institute for Wood Research Wilhelm-Klauditz-Institut WKI Fraunhofer WKI Bienroder Weg 54 E 3818 Braunschweig Germany HP Espanola, S.L. Attn: Mr. Adrian Liga Cami de Can Graells, Sant Cugat del Valles Spain Director Prof. Dr. Bohumil Kasal Bienroder Weg 54 E 3818 Braunschweig Germany Alexander Omelan Material Analysis & Indoor Chemistry Phone Fax sample_info@wki.fraunhofer.de Braunschweig, Customer: Object of the test: HP Espanola, S.L., Spain. Testing and evaluating of a digital printed paper material according to AgBB/DIBt-scheme. Contents: 1. Sample description Page 2 2. Experimental Page Fehler! Textmarke nicht definiert. 3. Results Page 2 This report comprises 5 pages. The test report may be forwarded or duplicated only in its unchanged entirety. A publication in extracts is subject to the written consent of the Fraunhofer-Institut für Holzforschung Wilhelm-Klauditz-Institut (WKI). The test results exclusively relate to the objects tested. The tested material was used up. Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.v., München Executive Board Univ.-Prof. Dr.-Ing. habil. Prof. e.h. mult. Dr. h.c. mult. Hans-Jörg Bullinger, President Prof. Dr. rer. nat. Ulrich Buller Dr. rer. pol. Alfred Gossner Cheques and transfers payable to: Deutsche Bank, München Account BLZ IBAN DE BIC (SWIFT-Code) DEUTDEMM V.A.T. Ident No. DE Tax Number 143/215/2392

Bohumil Kasal Bienroder Weg 54 E 3818 Braunschweig Germany Alexander Omelan Material Analysis & Indoor Chemistry Phone + 49 531 2155-36 Fax + 49 531 2155-95 sample_info@wki.fraunhofer.

2 Sample description: WKI no. Date of reception Sample Name (this information is provided by the customer) Product No. Manufacturer- Code Date- Stamp P HP PVC free wall paper printed CH98B, CH3B HP n.a. (Sample P19883: aluminum foil/wrapped separately, wrapping ok) Notice: Sample material will be stored for 2 months after test report date. Please contact us if an extended storage time is required or if sample material needs to be returned. Sample material for emission tests cannot be retained for repeated tests, it will only be stored for identification and documentation purposes. Sample preparation: After unwrapping three pieces of.33 m² of the sample material were mounted and fixed with low emitting aluminum tape on glass plates. Chamber emission test: For the test the sample material was positioned in the test chamber. The experiment was carried out under the conditions described in the results part. Sampling on TENAX-adsorption tubes was carried out after 3, 7 and 28 days according to the AgBB. Sampling volume was 5 6 liters. The adsorption tubes were analyzed in a thermal desorption GC/MS system. After separation the trapped compounds were identified mass-spectrometrically. The LCI-compounds were quantified with pure reference compounds, non-lci substances were quantified with toluene. The volatile aldehydes were trapped on DNPH-coated cartridges and analyzed after elution with acetonitrile by HPLC-UV. Results: The quantitative test results can be found on the next page. Page 2 of 5

Please contact us if an extended storage time is required or if sample material needs to be returned.

3 Results of the chamber emission test of sample P19883 (HP PVC free wall paper printed) RT CAS-No. Substance Concentration in µg/m³ after Info 3d 7d 28d ,2-Propanediol b Methyl-1,3,-propandiol (Toluene) Ethyldiglycol b Pyrrolidinon (Toluene) Sum of all measured compounds as VVOC value (< C6): < 1 < 1 < 1 Sum of all measured compounds als TVOC* original response value: Sum of all measured compounds as TVOC Toluen value: Sum of all measured compounds as SVOC value (> C16): < 1 < 1 < 1 *TVOC original response : The NIK-substances were quantified with the original response and the non-nik substances were quantified with toluene. Parameters of the emission chamber test: Chamber type: 1m³-glass chamber Q Climatic conditions: 23 C, 5 % r.h. Air exchange:.5 h -1 Loading factor: 1 m²/m³ Test started: :39:32 Sampling: Tenax TA, DNPH Analysis: Thermal desorption GC/MS, HPLC/UV Lower aldehyde results of sample P19883 (HP PVC free wall paper printed) CAS-No. Substance Concentration in µg/m³ Limit of detection 3d 7d 28d [µg/m³] 5-- Formaldehyde Acetaldehyde 2 2 < Propanal < 1 < 1 < Butanal < 2 < 2 < 2 2 Page 3 of 5

68 616-45-5 2-Pyrrolidinon (Toluene) 118 112 82 Sum of all measured compounds as VVOC value (< C6): < 1 < 1 < 1 Sum of all measured compounds als TVOC* original response value: 989 822 364 Sum of all

4 Chromatograms of the chamber emission test of sample P19883 (HP PVC free wall paper printed) TIC: [BSB1]m11499.d day TIC: [BSB1]M1152.D day TIC: [BSB1]M1158.D day Page 4 of 5

4. 45. TIC: [BSB1]M1152.D 1 14 1 1 8 7 day 4 5. 1. 15. 2. 25. 3. 35. 4. 45. TIC: [BSB1]M1158.

5 Remarks: The sample material was a moderate source of volatile organic compounds. Carcinogenic compounds and semi volatile organic compounds could not be detected (detection limit = 1 µg/m³). The sample P19883 fulfills the requirements of the AgBB/DIBt-scheme Health-related evaluation for Volatile Organic Compound Emissions (VOC and SVOC) from Building Products (AgBB-Scheme 21, LCI-List 21). Officer in Charge For the department A. Omelan Dr. E. Uhde Page 5 of 5

The sample P19883 fulfills the requirements of the AgBB/DIBt-scheme Health-related evaluation for Volatile Organic

Indoor Air Comfort Test Report

Knauf Insulation SPRL Rue de Maestricht, 95 B-4600 Vise Belgium Indoor Air Comfort Test Report 1 Sample Information Eurofins Product Testing A/S Smedeskovvej 38 8464 Galten Denmark voc@eurofins.com www.eurofins.com/voc-testing