Update'on'the'Kemper'IGCC'with' PreGCombusIon,'and'Petra'Nova' PostGCombusIon'Capture'Projects'
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1 Update'on'the'Kemper'IGCC'with' PreGCombusIon,'and'Petra'Nova' PostGCombusIon'Capture'Projects' Thomas'A.'Sarkus' Division'Director,'Major'Projects'Division' May'13,'2015' Na#onal'Energy' Technology'Laboratory'
2 Summit TX Clean Energy' Commercial'Demo'of'Adv.'IGCC'w/' Full'Carbon'Capture;'EOR'in'Permian' Basin' ~$3.5B' 'Total;'$450M' 'DOE' EOR' '~1.84'MMTPY;'late'2018'start' Major'CCS'Demonstra#on'Projects' Project(Loca+ons(&(Cost(Share' CCPI' ICCS'Area'1' Archer Daniels Midland CO 2 'Capture'from'Ethanol'Plant' CO 2 'Stored'in'Saline'Reservoir' $208M' 'Total;'$141M' 'DOE' SALINE '~0.9'MM'TPY;'Sept.'2015'start' HECA' Commercial'Demo'of'Advanced' IGCC'w/'Full'Carbon'Capture' ~$5B' 'Total;'$408M' 'DOE' EOR' ''~2.6'MM'TPY;'midU2020'start' Southern Company' Kemper County IGCC Project Transport'Gasifier'w/'Carbon'Capture' ~$6.4'B' 'Total;'$270M' 'DOE' EOR' '~3.0'MM'TPY;'midU2016'start' Petra Nova W.A. Parish Generating Station Post'Combus#on'CO 2 'Capture' $1B' 'Total;'$167M' 'DOE' EOR' ''~1.4'MM'TPY;'early'2017'start' Air Products & Chemicals, Inc. CO 2 'Capture'from'Steam'Methane'Reformers' EOR'in'Eastern'TX'Oilfields' $431M' 'Total;'$284M' 'DOE' EOR' ''~0.93'MM'TPY;'started'December'2012;'1.9' MMT'stored'as'of'April'2015'
3 Por]olio'of'Capture'and'Storage'Approaches( Plant'Type' Sequestra#on' Power' Industrial' Saline' EOR' Rate*' Feedstock' PreUcombus#on'' HECA'(IGCCUPolygen)' X' X' X' 2.57' NM'SubUbituminous' Coal/Petcoke'Blend' SouthernUKemper'Co.'(IGCC)' X' X' 3.0' MS'Lignite' Summit'Texas'(IGCCUPolygen)' X' X' X' 1.84' Air'Products'and'Chemicals,'Inc.' (SMR)' 'WY'SubUbituminous' Coal' X' X' 0.925' Natural'Gas' ADM'(Ethanol'Produc#on)' X' X' 0.900' Corn'Fermenta#on' PostUcombus#on'' Petra'Nova' X' X' 1.4' WY'SubUbituminous' Coal' Clean'Coal'Power'Ini#a#ve'(CCPI)'''''''''''''''''''''''''''''''''''''''''Industrial'Carbon'Capture'&'Storage'(ICCS,'Area'1)''''''''''''' ' ' *Rate'in'million'metric'tons'per'year'
4 Southern'Company'Services,'Inc.! Advanced(IGCC(with(CO 2 (Capture(' Kemper'County,'MS' 582'MWe'(net)'with'duct'firing;'2'TRIG TM ' gasifiers,'2'siemens'combus#on'turbines,''' 1'Toshiba'steam'turbine' Fuel:'Mississippi'lignite' 67+%'CO 2 'capture'(selexol ' process);'''''''''' 3,000,000'tons'CO 2 /year'' EOR:'Denbury'Onshore'LLC,'Treetop' Midstream'Services'LLC'' Total'DOE'CCPI'Project:'$2.01'B;'DOE' Share:'$270'MM'(13%)' Total'es#mated'project'cost:'~$'6.4B' Key'Dates'! Project'Awarded:'January'30,'2006'! Project'moved'to'MS:'December'5,'2008'! NEPA'Record'of'Decision:'August'19,'2010'! Ini#ate'excava#on'work:'September'27,'2010'! Opera#ons:'midU2016' Status'! Plant'construc#on'>98%'complete;'''''''''''''''''' Peak'construc#on'labor'6,121'! CO 2 'offutake'agreements'signed'! Lignite'mine'in'commercial'opera#on:'June' 2013'! Subsystems'commissioning'in'progress'! Combined'cycle'commercial''opera#on'on' natural'gas:'august'2014'! Gasifier' First'Fire :'March'2015''
5 Development of the TRIG for Power & Chemical Production Late 30's ' Orthoflow A Design 1942 Orthoflow C Design Resid FCCs Orthoflow F Design 1951 Early 1960's 's China 2011 USA 2014 Design Based on FCC Technology Pilot Plant Tech Center Grand Forks, ND 2,600 Hours Test Run PSDF at Wilsonville, AL. >14,600 hrs in gasification >2,200 hrs on Mississippi Lignite thru Dec 09 TRIG TM In Kemper County, MS, USA & Dong Guan, China
6
7 Liberty'Mine'' Treated'Effluent'Reservoir' Water'Treatment'Area' Gasifica#on'Area' Lignite'Storage'Dome' Combined'Cycle'Area' Gas'Cleanup'Area' Ash'Management'Area'
8 Inside'the'Boxcut'
9 Commissioning'Ac#vi#es' 'Steam'Blow'
10 Gas'Cleanup'Area'
11 Syngas'Scrubber'and'Water'Gas'ShiO'Reactors'
12 Sulfuric'Acid'Tanks'
13 Crystallizers'in'Water'Treatment'Plant'
14 Combined'Cycle'Plant'
15 Petra'Nova' 'NRG'W.A.'Parish'CCPIU3'' Advanced(Post(Combus+on(CO 2 (Capture(' Thompsons,'TX'(near'Houston)' 240'MWe'slipstream'at'NRG'Energy s'w.a.' Parish'power'plant'(originally'60'MWe)' Fuel:'PRB'subUbituminous'coal' 90%'CO 2 'capture'(km'cdr'process )'1,400,000' tonnes'co 2 /year'' EOR:'Hilcorp'West'Ranch'oil'field'' Total'Project'Cost:'~$1'billion''''''''''''''''''''''''''''''''''' DOE'Share:'$167'million' Key'Dates'! Project'Awarded:'May'2010'! Air'Permit:'December'2012'! NEPA'Record'of'Decision:'May'2013'! Financial'Close:'July'2014'! Construc#on:'''March'2014'(LNTP);'' July'2014'(NTP)'! Opera#on:'January'2017' Status'! Founda#ons'completed'for'quencher,'absorber,' regenerator,'compressor'&'hrsg'! Construc#on'in'progress'on'quencher,'absorber,' HRSG,'cooling'tower'&'pipeline'! Regenerator'being'shop'fabricated'&'compressor' being'manufactured'! Start'absorber/quencher'founda#on'Feb.'2015'! Overall'EPC'effort:'52%'complete'! Construc#on:'13%'complete'
16 Petra'Nova' 'NRG'W.A.'Parish'CCPIU3' 'Overview(! The'project'will'capture'CO 2 'and'send'it'to'nearby'oil'fields'for'carbon'dioxide'enhanced'oil'recovery' (CO 2 ' 'EOR),'which'is'a'longGproven'method'of'producing'stranded'oil.'! DOE s'goals'are'to'demonstrate'integraion'of'carbon'capture'at'an'exising'plant,'protocols'for'co 2' monitoring'to'ensure'permanence'of'sequestraion,'idenify'areas'for'cost'reducion'! Design'will'uIlize'a'standGalone'technology'natural'gas'cogen'to'simplify'retrofit,'provide'flexibility'in' matching'parasiic'energy'demands,'without'disrupt'exising'plant'performance.' h#p://nrgcarbon360.com!!
17 Petra'Nova' 'NRG'W.A.'Parish'CCPIU3'' Partners(and(Transac+on(Structure' Project'Ownership'Structure' Partner'Summary'! One'of'the'largest'privatelyGheld'oil'and'natural' gas'e&p'companies'in'the'us'! Strong'track'record'of'implemenIng'new' producion'techniques'into'mature'reservoirs'! Specialized'team'that'has'extensive'experience' implemening'co 2 'floods'! Currently'conducIng'oil'and'natural'gas' business'in'14'countries'! Parent'company,'JX'Holdings,'is'a'leading' integrated'energy,'resources,'and'materials' company'! PolicyGbased'financial'insItuIon'! WhollyGowned'by'the'Japanese'' government'! Over'25,000'loan'and'equity'commitments' valued'at'over'$479'billion'! Awarded'$167'MM'grant'! Funded'through'Clean'Coal'Power'IniIaIve' h#p://nrgcarbon360.com!!
18 Petra'Nova' 'NRG'W.A.'Parish'CCPIU3'' MHI(KMCCDR(Process '! Kansai'Mitsubishi'Carbon'Dioxide'Recovery'Process'(KM'CDR'Process TM' comes' from'one'of'the'world s'most'advanced'industrial'r&d'programs'(commenced' in'1990'and'ongoing).'! Commercially'applied'since'1999:'11'plants'under'operaIon.'! The' Complete'SoluIon 'G'hindered'amine'solvent' KSG1 TM ' 'with' accompanying'proprietary'equipment.' h#ps://
19 US'500'Metric'TPD'Coal'Fired'CCS'Demo'Project' Successful'demonstra#on'of'the'SoCo'500'Metric'TPD'Integrated'CCS'Demo' Project'has'lead'to'MHI'being'able'to'provide'guarantees'for'coal'flue'gas'CDR' plants' h#ps://
20 CO 2 'U'EOR'Fundamentals'! Large'scale'CO 2 GEOR'has'been'proven'successfully'since'the'early'1970s'to'produce'otherwise' unrecoverable'oil'from'mature'fields'(teriary'recovery).'! Its'a'closedGloop'' system'where'' the'co 2' produced'' with'the'oil'is'' separated'and' reginjected.'! 1'ton'of'CO 2 'can'' produce'up'to'4'bbls'' of'oil.''! 60MM'bbls'are' esimated'to'be'' recoverable'at'west'ranch'' ( h#p://
21 CO 2 'Monitoring'Plan' (! Monitoring'responds'to'the'goals'of'the'DOE'CooperaIve'Agreement.'! Industrial'experience'indicates'that'CO 2 'retenion'during'eor'is'good,'however'addiional' monitoring'is'needed'to'demonstrate'this'value'as'part'of'a'capture'and'storage'project'! The'monitoring'approach'is'linked'to'the'siteGspecific'condiIons,'including'geology'and'past'and' planned'operaions.''! Monitoring'needed'for'opImizaIon'of'' operaion'and'surveillance'of'oil'recovery,'' and'for'class'ii'protecion'of'underground'' Sources'of'Drinking'Water'(USDWs)'is'' enhanced'to'document'isolaion'from'' atmosphere.'! Executed'under'a'phased'approach:''! Phase'1' 'Field'CharacterizaIon'and' ''''monitoring'approach'! Phase'2' 'Baseline'Monitoring'&'plan' '''''''''''''''''''implementaion.''! Phase'3' 'CO 2 'monitoring'(3'years)' h#p://nrgcarbon360.com!!
22 Petra'Nova'Construc#on' CCS(Island(
23 Petra'Nova'Construc#on' Heat(Recovery(Steam(Generator((HRSG)(
24 For'Addi#onal'Informa#on' Office(of(Fossil(Energy( NETL(
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